Method for making ceramic matrix composite articles with progressive melt infiltration

Patent metadata

Field	Value
Publication number	US-10834790-B2
Application number	US-201514974895-A
Country	US
Kind code	B2
Filing date	Dec 18, 2015
Priority date	Dec 22, 2014
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

A method of melt infiltrating a green ceramic matrix composite (CMC) article, wherein the green CMC article includes a ceramic reinforcing structure. The method includes heating a localized region of the green CMC article; melting a metal alloy infiltrant to form a molten metal alloy; and introducing the molten metal alloy into the localized region to infiltrate the reinforcing structure of the green CMC article with the metal alloy infiltrant and form the CMC article.

First claim

The invention claimed is:

1. A method of repairing a defect in a localized region of a green ceramic matrix composite (CMC) article, the localized region comprising a portion of the CMC article, and wherein the green CMC article comprises a woven, fabric ceramic reinforcing structure, the method comprising:
moving a heat source above a surface of the localized region of the green CMC article to heat only the localized region of the green CMC article to a temperature to 1400° C. to 1600° C., wherein the localized region of the green CMC article is heated by the heat source for 2 seconds to 30 seconds;
melting a metal alloy infiltrant to form a molten metal alloy; and
introducing the molten metal alloy into the localized region to infiltrate the woven, fabric ceramic reinforcing structure of the green CMC article with the metal alloy infiltrant and densify the localized region of the green CMC article and repair the defect.

2. The method of claim 1 , wherein the metal alloy infiltrant comprises a metalloid chosen from Si, B, and oxides thereof metals chosen from Al, Y, Ti, Zr, oxides thereof; and mixtures and combinations thereof.

3. The method of claim 1 , wherein the ceramic reinforcing structure comprises a ceramic material selected from the group consisting of aluminum oxide (Al 2 O 3 ), mullite (Al 6 Si 2 O 13 ), zirconium oxide (ZrO 2 ), Boron Carbide (B 4 C), carbon (C), graphite, silicon carbide (SiC), silicon carbon nitride, silicon nitride, and mixtures and combinations thereof.

4. The method of claim 3 , wherein the ceramic material comprises fibers.

5. The method of claim 1 , wherein the localized region and the metal alloy infiltrant are heated by at least one of a laser, an electric arc, an electron beam, and a microwave generator.

6. The method of claim 1 , wherein the ceramic reinforcing structure comprises SiC fibers.

7. The method of claim 1 , wherein the green CMC article is in an inert atmosphere.

8. The method of claim 1 , wherein the green CMC article is at an atmospheric pressure.

9. The method of claim 1 , further comprising pre-heating a bulk of the green CMC article prior to introducing the molten metal alloy into the localized region.

10. A method of repairing a first defect in a first localized region of green ceramic matrix composite (CMC) article, and a second defect in a second localized region of the green CMC article, wherein the first localized region is different from the second localized region, and the first defect is different from the second defect, and wherein the first and the second localized regions comprise respective first and second portions of the CMC article wherein the green CMC article comprises a ceramic reinforcing structure, the method comprising:
moving a heat source above a surface of the first localized region of the green CMC article to heat only the first localized region of the green CMC article to a temperature to 1400° C. to 1600° C., wherein the first localized region of the green CMC article is heated for 2 seconds to 5 minutes;
melting a first metal alloy infiltrant to form a first molten metal alloy;
introducing the first molten metal alloy into the first localized region to infiltrate the ceramic reinforcing structure therein and repair the first defect;
moving a heat source above a surface of the second localized region of the green CMC article to heat only the second localized region of the green CMC article, wherein the second localized region of the green CMC article is heated for 2 seconds to 5 minutes;
melting a second metal alloy infiltrant to form a second molten metal alloy, wherein the second metal alloy is different from the first metal alloy; and
introducing the second molten metal alloy into the second localized region to infiltrate the ceramic reinforcing structure therein and repair the second defect.

Assignees

• Rolls Royce High Temperature Composites Inc

Inventors

• Harris Stephen Isaiah

Classifications

• C04B35/80 Primary

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• H05B6/80 Primary

  Apparatus for specific applications (stoves or ranges F24C7/02) · CPC title

• C04B2235/66

  Specific sintering techniques, e.g. centrifugal sintering · CPC title

• C04B35/584

  based on silicon nitride · CPC title

• C04B35/52

  based on carbon, e.g. graphite · CPC title