Non-catalytic hydrogen generation process for delivery to a hydrodesulfurization unit and a solid oxide fuel cell system combination for auxiliary power unit application

Patent metadata

Field	Value
Publication number	US-10833341-B2
Application number	US-201816039040-A
Country	US
Kind code	B2
Filing date	Jul 18, 2018
Priority date	Oct 14, 2011
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

A non-catalytic hydrogen generation process is provided that supplies hydrogen to a hydrodesulfurization unit and a solid oxide fuel cell system combination, suitable for auxiliary power unit application. The non-catalytic nature of the process enables use of sulfur containing feedstock for generating hydrogen which is needed to process the sulfur containing feed to specifications suitable for the solid oxide fuel cell. Also, the non-catalytic nature of the process with fast dynamic characteristics is specifically applicable for startup and shutdown purposes that are typically needed for mobile applications.

First claim

That which is claimed is:

1. A method for producing electricity from a sulfur containing hydrocarbon fuel stream, the method comprising the steps of:
supplying at least a diverted portion of the sulfur containing hydrocarbon fuel stream to a non-catalytic reformer to generate a hydrogen containing product stream;
supplying the hydrogen containing product stream from the reformer and at least a portion of the hydrocarbon fuel stream to a hydrodesulfurization unit, where the diverted portion of the sulfur containing hydrocarbon fuel stream supplied to the non-catalytic reformer is controlled by a control valve, wherein the control valve is configured to receive a signal from the hydrodesulfurization unit, said signal relating to an amount of hydrogen needed by the hydrodesulfurization unit, and wherein the control valve is configured to adjust flow rate of the diverted portion in accordance with said signal;
desulfurizing the sulfur containing hydrocarbon fuel stream in the hydrodesulfurization unit to produce a hydrogen sulfide containing hydrocarbon fuel stream;
supplying the hydrogen sulfide containing hydrocarbon fuel stream from the hydrodesulfurization unit to an adsorber, wherein said adsorber is operable to remove hydrogen sulfide from the hydrocarbon fuel stream to produce a desulfurized hydrocarbon fuel stream; and
supplying the desulfurized hydrocarbon fuel stream to a solid oxide fuel cell, wherein said solid oxide fuel cell is configured to produce electricity from said desulfurized hydrocarbon fuel stream.

2. The method of claim 1 , further comprising supplying water and oxygen to the non-catalytic reformer, wherein a reaction of the sulfur containing hydrocarbon fuel stream, water and oxygen is operable to produce the product stream comprising hydrogen.

3. The method of claim 1 , wherein the product stream comprises between about 50% and 53.6% hydrogen gas by volume.

4. The method of claim 1 , wherein the adsorber comprises an adsorbent bed comprising zinc oxide.

5. The method of claim 1 , wherein the desulfurized hydrocarbon fuel stream comprises less than about 1 ppm sulfur.

6. The method of claim 1 , wherein the desulfurized hydrocarbon fuel stream comprises less than about 0.5 ppm sulfur.

7. The method of claim 1 , wherein during continuous operation, between about 5% and about 22% of the sulfur containing hydrocarbon fuel stream by volume is supplied to the reformer.

8. The method of claim 1 , wherein during continuous operation, between about 10.4% and about 14.8% of the sulfur containing hydrocarbon fuel stream by volume is supplied to the reformer.

9. The method of claim 1 , wherein the ratio of hydrogen to sulfur containing hydrocarbon fuel stream supplied to the hydrodesulfurization unit is between about 100:1 and 500:1.

10. The method of claim 1 , wherein upon start up, all of the hydrocarbon fuel stream is supplied to the reformer for the production of the hydrogen containing product stream.

11. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons selected from the group consisting of: natural gas; liquefied petroleum gas; naphtha; kerosene; jet fuel; diesel; fuel oil; and mixtures thereof.

12. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons having a boiling point in the range of between about 30° C. and about 360° C.

13. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons having between about 1 and 25 carbon atoms per molecule.

14. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons having between about 1 and 8 carbon atoms per molecule.

15. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons having between about 6 and 12 carbon atoms per molecule.

16. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons having between about 6 and 16 carbon atoms per molecule.

17. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons having between about 8 and 15 carbon atoms per molecule.

18. The method of claim 1 , wherein the sulfur containing hydrocarbon fuel stream comprises hydrocarbons having between about 15 and 25 carbon atoms per molecule.

Assignees

• Saudi Arabian Oil Co

Inventors

• Pham Thang Viet
• Imran Hasan
• Daoudi Mohamed

Classifications

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D53/04

  with stationary adsorbents {(B01D53/025 takes precedence)} · CPC title

• H01M8/0612

  from carbon-containing material · CPC title

• Y02P30/20

  using bio-feedstock · CPC title

• C10G25/003

  Specific sorbent material, not covered by C10G25/02 or C10G25/03 · CPC title