Polypropylene composition with improved heat resistance

Patent metadata

Field	Value
Publication number	US-10829624-B2
Application number	US-201716303341-A
Country	US
Kind code	B2
Filing date	Jun 2, 2017
Priority date	Jun 6, 2016
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

The present invention is directed to a polypropylene composition, said polypropylene composition comprising two different polypropylene fractions (PP1) and (PP2), wherein the first polypropylene (PP1) has a weight molecular weight Mw in the range of above 45 kg/mol to below 65 kg/mol and a melting temperature of at least 140° C.

First claim

The invention claimed is:

1. A polypropylene composition comprising:
a) a first polypropylene having a weight average molecular weight Mw in the range of above 45 kg/mol to below 65 kg/mol, a molecular weight distribution (Mw/Mn) in the range of 4.0 to 10.0, and a melting temperature of at least 140 ° C., and
b) a second polypropylene having a higher weight average molecular weight Mw than the first polypropylene.

2. The polypropylene composition according to claim 1 , wherein the first polypropylene has a xylene cold soluble (XCS) fraction in the range of 1.0 to 20.0 wt.-%.

3. The polypropylene composition according to claim 1 , wherein the mixture consisting of the first polypropylene and the second polypropylene has a melting temperature of at least 150 ° C.

4. The polypropylene composition according to claim 1 , wherein the second polypropylene is a propylene homopolymer.

5. The polypropylene composition according to claim 1 , wherein the amount of the first polypropylene and the second polypropylene together makes up at least 80 wt.-% of the polypropylene composition (PC).

6. The polypropylene composition according to claim 1 , wherein the polypropylene composition comprises at least 66 wt.-% of the second polypropylene and at least 5 wt.-% of the first polypropylene.

7. The polypropylene composition according to claim 1 , wherein the weight ratio between the first polypropylene and the second polypropylene is in the range of 0.02 to 0.60.

8. The polypropylene composition according to claim 1 , wherein the first polypropylene has been polymerized in the presence of:
a) a Ziegler-Natta catalyst comprising compounds of a transition metal of Group 4 to 6 of IUPAC, a Group 2 metal compound and an internal donor, wherein said internal donor is a non-phthalic compound, preferably is a non-phthalic acid ester;
b) optionally a co-catalyst, and
c) optionally an external donor.

9. The polypropylene composition according to claim 1 , wherein the mixture (M) consisting of the first polypropylene and the second polypropylene has:
a) a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 in the range of 2.0 to 50 g/10 min and/or
b) a weight average molecular weight Mw in the range of 200 to 560 kg/mol, and wherein the weight average molecular weight Mw of the second polypropylene is in the range of 210 to 950 kg/mol.

10. The polypropylene composition according to claim 1 , wherein the mixture consisting of the first polypropylene and the second polypropylene has:
a) a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 in the range of 500 to 5000 g/10 min and/or
b) a weight average molecular weight Mw in the range of 65 to 100 kg/mol, and wherein the weight average molecular weight Mw of the second polypropylene is in the range of 70 to 125 kg/mol.

11. A molded article, comprising a polypropylene composition comprising:
a) a first polypropylene having a weight average molecular weight in the range of above 45 kg/mol to below 65 kg/mol, a molecular weight distribution (Mw/Mn) in the range of 4.0 to 10.0, and a melting temperature of at least 140 ° C., and
b) a second polypropylene having a higher weight average molecular weight Mw than the first polypropylene.

12. A film or melt blown fiber, comprising a polypropylene composition comprising:
a) a first polypropylene having a weight average molecular weight in the range of above 45 kg/mol to below 65 kg/mol, a molecular weight distribution (Mw/Mn) in the range of 4.0 to 10.0, and a melting temperature of at least 140 ° C., and b) a second polypropylene having a higher weight average molecular weight Mw than the first polypropylene.

13. The melt blown fiber according to claim 12 , wherein the amount of the polypropylene composition makes up at least 80 wt.-% of the melt blown fiber.

14. The melt blown fiber according to claim 12 , wherein the melt blown fiber is incorporated into a melt-blown web.

15. The melt blown fiber according to claim 14 , wherein the melt-blown web has a weight per unit area of at most 120 g/m 2 .

16. The melt blown fiber according to claim 14 , wherein the melt-blown web is incorporated into an article that is selected from the group consisting of filtration medium, diaper, sanitary napkin, panty liner, incontinence product for adults, protective clothing, surgical drape, surgical gown, and surgical wear.

Assignees

• Borealis Ag

Inventors

• Wang Jingbo
• Gahleitner Markus
• Doshev Petar
• Grestenberger Georg

Classifications

• C08L2207/02

  Heterophasic composition · CPC title

• C08F4/651

  Pretreating with non-metals or metal-free compounds · CPC title

• C08F110/06

  Propene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/12 Primary

  Polypropene · CPC title