Process and apparatus for in-line blending of polymers

Patent metadata

Field	Value
Publication number	US-10829610-B2
Application number	US-201616065066-A
Country	US
Kind code	B2
Filing date	Dec 21, 2016
Priority date	Dec 21, 2015
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

The present invention deals with a process for polymerising olefins in a solution and withdrawing a stream of the solution from the polymerisation reactor and passing it to a sequence of heating steps. The heated solution is passed to a separation step, which is conducted at a pressure of no more than 15 bar and in which separation step a liquid phase comprising the polymer and a vapour phase coexist. A vapour stream and a concentrated solution stream comprising the polymer are withdrawn from the separation step. At least a part of the vapour stream is passed to the first polymerisation reactor, to the second polymerisation reactor or to both.

First claim

The invention claimed is:

1. A process for producing a polymer comprising the following steps of:
(A) polymerising, in a first polymerisation reactor in a first solvent,
a first olefin monomer having two or more carbon atoms and
optionally a first alpha-olefin comonomer containing from 3 to 10 carbon atoms,
in the presence of a first polymerisation catalyst and optionally a chain transfer agent and for producing a first solution comprising a first polymer of the first olefin monomer and the optional first alpha-olefin comonomer and the first solvent;

(B) polymerising, in a second polymerisation reactor in a second solvent,
a second olefin monomer having two or more carbon atoms and
optionally a second alpha-olefin comonomer containing from 3 to 10 carbon atoms,
in the presence of a second polymerisation catalyst and optionally a chain transfer agent and producing a second solution comprising a second polymer of the second olefin monomer and the optional second alpha-olefin comonomer and the second solvent;

(C) withdrawing a first stream of the first solution from the first polymerisation reactor;
(D) withdrawing a second stream of the second solution from the second polymerisation reactor;
(E) combining the second stream of the second solution with the first stream of the first solution to produce a combined stream of the first and second solution;
(F) passing the combined stream of the first and second solution to a first heating step and a second heating step;
(G) passing the combined stream of the first and second solution into a separation step, which separation step is conducted at a pressure of no more than 15 bar and in which separation step a liquid phase comprising the polymer and a vapour phase coexist;
(H) withdrawing a vapour stream and a concentrated solution stream comprising the polymer from the separation step;
(I) passing at least a part of the vapour stream to the first polymerisation reactor, to the second polymerisation reactor or to both.

2. The process according to claim 1 comprising an additional step of passing the first combined solution stream through a static mixer downstream of the second heating step.

3. The process according to claim 1 comprising steps of passing the vapour stream to a condensing step and withdrawing a partially condensed vapour stream from the condensing step.

4. The process according to claim 3 comprising steps of: passing at least a part of the vapour stream to the first heating step for heating the combined stream; and recovering the at least part of the vapour stream from the first heating step as the partially condensed vapour stream.

5. The process according to claim 4 comprising steps of: dividing the vapour stream into a first vapour stream and a second vapour stream; passing the first vapour stream to the first heating step for heating the combined solution stream and recovering the first vapour stream from the first heating step.

6. The process according to claim 5 comprising a step of dividing the partially condensed vapour stream into a condensed vapour stream and an uncondensed vapour stream.

7. The process according to claim 6 comprising a step of passing the condensed vapour stream to the first polymerisation reactor, to the second polymerisation reactor or to both the first polymerisation reactor and the second polymerisation reactor.

8. The process according to claim 7 comprising a step of passing at least a part of the uncondensed vapour stream to the first polymerisation reactor or to the second polymerisation reactor.

9. Process according to claim 1 wherein the first solvent and the second solvent are the same.

10. Process according to claim 1 wherein the first olefin monomer and the second olefin monomer are ethylene or propylene.

11. The process according to claim 1 wherein the second alpha-olefin comonomer is the same as the first alpha-olefin comonomer.

12. The process according to claim 1 wherein the first co-monomer has a boiling point that is less than the boiling point of the first solvent and the second co-monomer has a boiling point which is greater than the boiling point of the second solvent.

13. The process according to claim 1 wherein the polymer content in the concentrated solution stream withdrawn from the separation step is from 40 to 90% by weight, based on the total weight content of the solution stream.

14. A process for producing a polymer comprising the following steps of:
(A′) polymerising, in a first polymerisation reactor in a first solvent,
a first olefin monomer having two or more carbon atoms and optionally a first alpha-olefin comonomer containing from 3 to 10 carbon atoms,
in the presence of a first polymerisation catalyst and optionally a chain transfer agent and producing a first solution comprising a first polymer of the first olefin monomer and the optional first alpha-olefin comonomer and the first solvent;

(B′) polymerising, in a second polymerisation reactor in a second solvent,
a second olefin monomer having two or more carbon atoms and
optionally a second alpha-olefin comonomer containing from 3 to 10 carbon atoms
in the presence of a second polymerisation catalyst and optionally a chain transfer agent and producing a second solution comprising a second copolymer polymer of the second olefin monomer and the optional second alpha-olefin comonomer and the second solvent;

(C′) withdrawing a first stream of the first solution from the first polymerisation reactor and passing the first stream to a first heating step and a second heating step;
(D′) withdrawing a second stream of the second solution from the second polymerisation reactor and passing the second stream to a third heating step and a fourth heating step;
(E′) combining a heated second stream of the second solution with a heated first stream of the first solution to produce a combined stream of the first and second solution;
(F′) passing the combined stream of the first and second solution into a separation step, which separation step is conducted at a pressure of no more than 15 bar and in which separation step a liquid phase comprising the polymer and a vapour phase coexist;
(G′) withdrawing a vapour stream and a concentrated solution stream comprising the polymer from the separation step;
(H′) passing at least a part of the vapour stream to the first polymerisation reactor, to the second polymerisation reactor or to both.

15. The process according to claim 14 comprising an additional step of passing the first stream of the first solution through a static mixer downstream of the second heating step.

16. The process according to claim 14 comprising steps of passing the vapour stream to a condensing step and withdrawing a partially condensed vapour stream from the condensing step.

17. The process according to claim 16 comprising steps of: passing at least a part of the vapour stream to the first heating step for heating the first stream of the first solution; and recovering the at least part of the vapour stream from the first heating step as the partially condensed vapour stream.

18. The process according to claim 17 comprising steps of:
dividing the vapour stream into a first vapour stream and a second vapour stream;
passing the first vapour stream to the first heating step for heating the first stream of the first solution and recovering the first vapour stream from the first heating step;
passing the second vapour stream to the third heating step for heating the second stream of the second solution and recovering the second vapour stream fr

Assignees

• Borealis Ag

Inventors

• Al-Haj Ali Mohammad
• Bergstra Michiel
• Eriksson Erik
• Mathivanan Guhan
• Räsänen Jukka
• Sleijster Henry
• Vijay Sameer
• Wurnitsch Christof
• Zitting Samuli
• Kanellopoulos Vasileios
• Aho Jani

Classifications

• C08F2/001 Primary

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title

• C08F6/12

  Separation of polymers from solutions · CPC title

• C08F2/06

  Organic solvent · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title