Noncovalent soft elastomer and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-10829580-B2
Application number	US-201615573116-A
Country	US
Kind code	B2
Filing date	Apr 27, 2016
Priority date	May 11, 2015
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

A noncovalent soft elastomer includes a binary block copolymer composed of an A block and a B block and a solvent, wherein the B block has a noncovalent-bonding functional group, and the solvent is a nonvolatile liquid which has a property of dissolving the B block but not dissolving the A block and which forms a functional group capable of noncovalent-bonding of the B block.

First claim

The invention claimed is:

1. A noncovalent elastomer composition comprising:
a block copolymer having:
an A block that is a polymer having a glass transition temperature (Tg) of 35° C. or higher and comprises at least one selected from the group consisting of polystyrenes, polyacrylic acid esters, polymethacrylic acid esters, and polyolefins;
a B block comprising:
(i) at least one selected from the group consisting of polyvinylpyridines, poly(meth)acrylic acids, polyacrylamides, and polyhydroxyalkyl (meth)acrylates, or
(ii) at least one selected from the group consisting of polystyrene derivatives, polydiene derivatives, and polyolefin derivatives, into which a functional group has been introduced, the functional group being capable of non-covalent bonding selected from hydrogen bonding, coordination bonding, and ionic bonding; and

a solvent having a vapor pressure of 1 mmHg or less and having a property of dissolving the B block but not dissolving the A block, wherein the solvent is an alcohol-based solvent selected from the group consisting of (i) glycol-based solvents selected from trimers to tricontamers of alkylene glycol, and (ii) non-glycol-based solvents selected from monoalcohol-based solvents, diol-based solvents, and polyol-based solvents,

wherein a strip specimen formed of the noncovalent elastomer composition, and having a thickness of 0.6 mm and a width of 4 mm, has a stress at 300% elongation in the range of from 0.044 MPa to 1.42 MPa.

2. The noncovalent elastomer composition according to claim 1 , wherein the alcohol-based solvent is selected from the group consisting of dipropylene glycol; a trimer to tricontamer of alkylene glycol; a monoalcohol-based solvent; diol-based solvents selected from 1,3-propanediol, 1,4-butanediol, 1,2-butanediol, 2,3-butanediol, 1,3-butanediol, 1,5-pentanediol, 1,2-pentanediol, 1,3-pentanediol, 1,4-pentanediol, 2,3-pentanediol, 1,6-hexanediol, 1,2-hexanediol, 1,3-hexanediol, 1,4-hexanediol, 1,5-hexanediol, 2,3-hexanediol, 2,4-hexanediol, 2,5-hexanediol, 1,7-heptanediol, 1,2-heptanediol, 1,3-heptanediol, 1,4-heptanediol, 1,5-heptanediol, 1,6-heptanediol, 2,3-heptanediol, 2,4-heptanediol, 2,5-heptanediol, 2,6-heptanediol, 3,4-heptanediol, and 3,5-heptanediol; and polyol-based solvents selected from 1,2,3-propanetriol (glycerin), 1,2,3-butanetriol, and 1,2,4-butanetriol.

3. The noncovalent elastomer composition according to claim 1 ,
wherein the block copolymer is a binary block copolymer composed of the A block and the B block.

4. The noncovalent elastomer composition according to claim 1 ,
wherein the block copolymer is an AB block copolymer or an ABA block copolymer.

5. The noncovalent elastomer composition according to claim 1 , wherein:
the A block is at least one selected from the group consisting of polystyrenes, polyacrylic acid esters, polymethacrylic acid esters, and polyolefins,
the B block is at least one selected from the group consisting of polyvinylpyridines, poly(meth)acrylic acids, and polyacrylamides, and
the solvent is an ethylene glycol-based solvent having 2 to 30 oxyethylene groups.

6. The noncovalent elastomer composition according to claim 1 ,
wherein the noncovalent bond is a hydrogen bond, an ionic bond, or a coordination bond.

7. The noncovalent elastomer composition according to claim 1 ,
wherein the functional group is at least one selected from the group consisting of a nitrogen-containing heterocyclic group, a carboxylic acid group, an amide group, and a hydroxy group.

8. The noncovalent elastomer composition according to claim 1 , wherein a weight concentration of the block copolymer in the noncovalent elastomer composition is from 49 percent by weight to 80 percent by weight.

9. The noncovalent elastomer composition according to claim 1 ,
further comprising a metal salt.

10. A method for manufacturing the noncovalent elastomer composition of claim 1 , comprising the steps of:
(a) synthesizing the block copolymer, and
(b) producing the noncovalent elastomer composition by mixing the solvent and the block copolymer.

Assignees

• National Univ Corporation Tokai National Higher Education And Research System

Inventors

• Noro Atsushi
• Ohno Maho

Classifications

• C08K5/3445

  Five-membered rings · CPC title

• C08L101/14

  the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F293/005 Primary

  using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent · CPC title

• C08F20/56

  Acrylamide; Methacrylamide · CPC title