Ester composition preparation system and ester composition preparation method using same

Patent metadata

Field	Value
Publication number	US-10829430-B2
Application number	US-201816343988-A
Country	US
Kind code	B2
Filing date	Sep 5, 2018
Priority date	Sep 7, 2017
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

Provided are an ester composition preparation system, including an integrated reactor, a gas-liquid separation column, a purification unit, an alcohol storage tank, and a mixed alcohol separation column, which is an efficient, economical, and simplified ester composition preparation system, and an ester composition preparation method using the same. The ester composition preparation system is a simplified system which can reduce facility space, drastically remove reaction equipment, and reduce transfer time through the introduction of the integrated reactor in which the reaction preparing an ester compound and the reaction preparing an ester composition are carried out in one space, the mixed alcohol separation column and the gas-liquid separation column.

First claim

The invention claimed is:

1. A preparation system, comprising:
an integrated reactor having an inner reaction space in which a direct esterification, which is a reaction of a first alcohol and a carboxylic acid-based compound comprising two or more carboxyl groups, and a trans-esterification, which is a reaction of a product of the direct esterification and a second alcohol, are carried out, an upper outlet line connected to a gas phase compartment, and a lower outlet line connected to a liquid phase compartment, provided therewith;
a gas-liquid separation column having a gas-liquid separation space, into which a gasified reaction product and a gas phase low boiling point mixture from the integrated reactor flow through the upper outlet line of the integrated reactor and in which a gas-liquid separation is carried out, a lower recovery line, through which a liquefied reaction product is recovered to the integrated reactor, and an upper outflow line, through which the gas phase low boiling point mixture flows out, provided therewith;
a purification unit having a purification bath, in which an ester composition flowed out through the lower outlet line of the integrated reactor and the second alcohol are separated, a purified product line through which a purified ester composition is discharged, and an alcohol recovery line through which the second alcohol is recovered, provided therewith;
an alcohol storage tank having an inner space, in which the first alcohol and the second alcohol are stored, provided therewith, and connected to the upper outflow line of the gas-liquid separation column and to the alcohol recovery line of the purification unit, so as to store a mixed alcohol of the first alcohol and the second alcohol; and
a mixed alcohol separation column having an alcohol separation space, into which the mixed alcohol flows from the alcohol storage tank and in which the mixed alcohol is separated depending on the number of alkyl carbon atoms of the alcohol, and one or more recirculation lines, through which separated alcohol is recirculated, provided therewith,
wherein the reaction product in the gas-liquid separation column is a product of the direct esterification or a product of the trans-esterification, and the low boiling point mixture includes one or more of the first alcohol and the second alcohol.

2. The preparation system of claim 1 , wherein the preparation system further has a middle outlet line provided with the liquid phase compartment in the integrated reactor, and the middle outlet line is connected to the middle part of the gas-liquid separation column and the middle part of the gas-liquid separation column is positioned at one half or higher in the height direction of the column.

3. The preparation system of claim 2 , wherein through the middle outlet line of the integrated reactor, a liquid phase reaction product of the direct esterification and a low boiling point mixture including an ungasified first alcohol flow out.

4. The preparation system of claim 1 , wherein the one or more recirculation lines of the mixed alcohol separation column comprises a recirculation line for the first alcohol and a recirculation line for the second alcohol.

5. The preparation system of claim 1 , further comprising a product storage tank, wherein the product storage tank is connected to the purified product line of the purification unit.

6. The preparation system of claim 1 , which is a batch reaction system.

7. The preparation system of claim 1 , wherein the carboxylic acid-based compound comprising two or more carboxyl groups is terephthalic acid.

8. The preparation system of claim 1 , wherein the first alcohol and the second alcohol are primary alcohols, and the number of carbon atoms of the first alcohol is larger than that of the second alcohol.

9. The preparation system of claim 1 , wherein the numbers of alkyl carbon atoms of the first alcohol and the second alcohol are 1 to 12.

10. The preparation system of claim 1 , wherein the ester composition is a mixture of three ester compounds.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Ha Na
• Lee Sung Kyu
• Shin Joon Ho
• Jun Hyoung
• Kim Hyun Kyu

Classifications

• C07C67/03

  by reacting an ester group with a hydroxy group · CPC title

• C07C29/80 Primary

  by distillation · CPC title

• C07C69/82

  Terephthalic acid esters · CPC title

• C07C67/08 Primary

  by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title