Catalyst containing 2-acetylbutyrolactone and/or the hydrolysis products thereof, and use thereof in a hydrotreatment and/or hydrocracking process

Patent metadata

Field	Value
Publication number	US-10828627-B2
Application number	US-201716320558-A
Country	US
Kind code	B2
Filing date	Jun 22, 2017
Priority date	Jul 28, 2016
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

The invention has as its object a catalyst that comprises a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and at least one additive that is selected from among 2-acetylbutyrolactone and/or its hydrolysis products, 2-(2-hydroxyethyl)-3-oxobutanoic acid, and 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid. The invention also relates to the method for preparation of said catalyst and its use in a method for hydrotreatment and/or hydrocracking.

First claim

The invention claimed is:

1. A catalyst comprising a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and an additive that is at least one of 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, or 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid.

2. The catalyst according to claim 1 , in which the content of element from group VIB is 5 to 40% by weight expressed in terms of metal oxide from group VIB in relation to the total weight of the catalyst, and the content of element from group VIII is 1 to 10% by weight that is expressed in terms of metal oxide from group VIII in relation to the total weight of the catalyst.

3. The catalyst according to claim 1 , in which the molar ratio of element from group VIII to element from group VIB in the catalyst is 0.1 to 0.8.

4. The catalyst according to claim 1 , further comprising 0.1 to 20% by weight of phosphorus, expressed in terms of P 2 O 5 in relation to the total weight of the catalyst, and having a molar ratio of phosphorus to the element from group VIB in the catalyst greater than or equal to 0.05.

5. The catalyst according to claim 1 , in which the total content of 2 acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, and 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid additives is 1 to 45% by weight in relation to the total weight of the catalyst.

6. The catalyst according to claim 1 , further comprising an organic compound other than the 2 acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, and 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid additives, with said organic compound containing oxygen, nitrogen, sulfur or a mixture thereof.

7. The catalyst according to claim 6 , in which the organic compound is a compound that comprises one or more carboxylic, alcohol, thiol, thioether, sulfone, sulfoxide, ether, aldehyde, ketone, ester, carbonate, amine, nitrile, imide, oxime, urea, or amide groups.

8. The catalyst according to claim 7 , in which the organic compound is triethylene glycol, diethylene glycol, ethylene glycol, ethylenediaminetetraacetic acid (EDTA), maleic acid, malonic acid, citric acid, dimethylformamide, N-methylpyrrolidone, propylene carbonate, bicine, or tricine.

9. The catalyst according to claim 1 , in which the substrate contains from 0.1 to 50% by weight of zeolite.

10. The catalyst according to claim 1 , that is at least partially sulfurized.

11. A method for preparation of a catalyst according to claim 1 comprising:
a) contacting at least one component of an element from group VIB, at least one component of an element from group VIII, at least one additive that is at least one of 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, or 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid, and optionally phosphorus with a substrate based on alumina or silica or silica-alumina, or contacting a regenerated catalyst that contains a substrate based on alumina or silica or silica-alumina, at least one component of an element from group VIB, at least one component of an element from group VIII, and optionally phosphorus with at least one 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, or 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid additive, in such a way as to obtain a catalyst precursor,
b) said catalyst precursor that is obtained from a) is dried at a temperature that is lower than 200° C., without being calcined subsequently.

12. The method according to claim 11 , in which a) comprises:
a′) impregnating the substrate based on alumina or silica or silica-alumina by at least one solution that contains the at least one element from group VIB, the at least one element from group VIII, the additive that is at least one of 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, or 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid, and optionally phosphorus in such a way as to obtain the catalyst precursor.

13. The method according to claim 11 , in which a) comprises:
a1) impregnating the substrate based on alumina or silica or silica-alumina by at least one solution that contains the at least one element from group VIB, the at least one element from group VIII, and optionally phosphorus to obtain an impregnated substrate,
a2) drying the impregnated substrate that is obtained in a1) at a temperature that is lower than 200° C. to obtain a dried impregnated substrate, and optionally calcining the dried impregnated substrate to obtain a calcined impregnated substrate,
a3) impregnating the dried and optionally calcined impregnated substrate that is obtained in a2) by an impregnation solution that comprises the additive that is at least one of 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid in such a way as to obtain the catalyst precursor,
a4) optionally, maturing the catalyst precursor that is obtained in a3).

14. The method according to claim 11 , in which a) comprises:
a1′) preparing a substrate that comprises the additive that is at least one of 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, or 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid, and optionally at least one part of phosphorus,
a2′) impregnating the substrate that is obtained in a1′) by an impregnation solution that comprises the at least one element from group VIB, the at least one element from group VIII, and optionally phosphorus in such a way as to obtain the catalyst precursor,
a3′) optionally maturing the catalyst precursor that is obtained in a2′).

15. The method according to claim 11 , in which a) comprises:
a1″) contacting by co-impregnating a solution that contains the at least one element from group VIB, the at least one element from group VIII, at least one organic compound that contains oxygen and/or nitrogen and/or sulfur, and optionally phosphorus with the substrate based on alumina or silica or silica-alumina in such a way as to obtain an impregnated substrate,
a2″) drying the impregnated substrate that is obtained from a1″) at a temperature that is lower than 200° C., without being calcined subsequently, to obtain a dried impregnated substrate,
a3″) contacting the dried impregnated substrate that is obtained from a2″) with a solution of at least one organic compound that contains oxygen and/or nitrogen and/or sulfur that is identical to or different from the one that is used in a1″) in such a way as to obtain the catalyst precursor, and
a4″) optionally maturing the catalyst precursor that is obtained in a3″),
wherein at least one of the organic compounds of a1″) or of a3″) is at least one of 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, or 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid.

16. The method according to claim 11 , in which a) comprises:
a1′″) impregnating the regenerated catalyst that contains a substrate based on alumina or silica or silica-alumina, the at least one component of an element from group VIB, the at least one component of an element from group VIII, and optionally phosphorus by an impregnation solution that comprises the additive that is at least one of 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, or 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid in such a way as to obtain the catalyst precursor,
a2′″) optionally maturing the catalyst precursor that is obtained in a1′″).

17. The method according to claim 11 , in which the total molar ratio of the additive(s) 2-acetylbutyrolactone, 2-(2-hydroxyethyl)-3-oxobutanoic acid, and 3-hydroxy-2-(2-hydroxyethyl)-2-butenoic acid to element(s) from grou

Assignees

• Ifp Energies Now

Inventors

• Carrette P-Louis

Classifications

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• B01J23/94

  of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper · CPC title

• B01J37/088

  Decomposition of a metal salt · CPC title

• C10G2400/04

  Diesel oil · CPC title

• B01J31/04

  containing carboxylic acids or their salts {(B01J31/0277 - B01J31/0298 take precedence; multi-metal carboxylate complexes like Pd (II) acetate, i.e. Pd3 (OAc) 6 or Cr(II)acetate, i.e. Cr2(OAc)4 B01J31/2226)} · CPC title