System and method for catalyst preparation

Patent metadata

Field	Value
Publication number	US-10828613-B2
Application number	US-201916248960-A
Country	US
Kind code	B2
Filing date	Jan 16, 2019
Priority date	Oct 18, 2012
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

Techniques are provided for catalyst preparation. A system for catalyst preparation may include an agitator disposed inside a polymerization catalyst tank and configured to mix a polymerization catalyst and a solvent to generate a polymerization catalyst solution. The system may also include a heating system coupled to the polymerization catalyst tank and configured to maintain a temperature of the polymerization catalyst solution above a threshold. The system may also include a precontactor configured to receive feed streams comprising an activator and the polymerization catalyst solution from the polymerization catalyst tank to generate a catalyst complex. The system may also include a transfer line configured to transfer the catalyst complex from an outlet of the precontactor to a reactor.

First claim

What is claimed is:

1. A polymer manufacturing system comprising:
(A) a catalyst solution tank configured to contain a metallocene catalyst solution and to supply a precontactor with at least a portion of the metallocene catalyst solution;
(B) a precontactor configured to contact the metallocene catalyst solution, an activator, and a co-catalyst to form a catalyst complex;
(C) a polymerization reactor system configured to contact the catalyst complex with an olefin monomer and an optional olefin comonomer to produce a polyolefin;
(D) an ultraviolet-visible analyzer configured to determine a first concentration of a metallocene catalyst in the metallocene catalyst solution; and
(E) a control system configured to control the first concentration of the metallocene catalyst in the metallocene catalyst solution.

2. The polymer manufacturing system of claim 1 , wherein the catalyst solution tank contains an agitator configured to mix the metallocene catalyst and a solvent to form the metallocene catalyst solution.

3. The polymer manufacturing system of claim 1 , further comprising a heating system coupled to the catalyst solution tank and configured to maintain a temperature of the metallocene catalyst solution.

4. The polymer manufacturing system of claim 1 , further comprising a transfer line configured to transfer the catalyst complex from an outlet of the precontactor to the polymerization reactor system.

5. The polymer manufacturing system of claim 1 , wherein the polymerization reactor system comprises one or more polymerization reactors selected independently from a fluidized bed reactor, a gas-phase reactor, a loop slurry reactor, or any combination thereof.

6. The polymer manufacturing system of claim 1 , wherein the polymerization reactor system comprises a loop slurry reactor.

7. The polymer manufacturing system of claim 1 , wherein the metallocene catalyst solution contains a first metallocene catalyst and a second metallocene catalyst.

8. The polymer manufacturing system of claim 1 , wherein the polymerization reactor system is configured to contact the catalyst complex with ethylene and an olefin comonomer comprising 1-butene, 1-hexene, 1-octene, or a mixture thereof.

9. The polymer manufacturing system of claim 1 , wherein the ultraviolet-visible analyzer further comprises a filter for filtering a sample of the metallocene catalyst solution containing the metallocene catalyst prior to analysis.

10. The polymer manufacturing system of claim 1 , wherein the ultraviolet-visible analyzer is further configured to determine the first concentration of the metallocene catalyst in the metallocene catalyst solution at a selected wavelength using a calibration curve.

11. A polymer manufacturing system comprising:
(A) a catalyst solution tank configured to contain a metallocene catalyst solution and to supply a precontactor with at least a portion of the metallocene catalyst solution;
(B) a precontactor configured to contact the metallocene catalyst solution, an activator, and a co-catalyst to form a catalyst complex;
(C) a polymerization reactor system configured to contact the catalyst complex with an olefin monomer and an optional olefin comonomer to produce a polyolefin;
(D) an ultraviolet-visible analyzer (i) configured to determine a first concentration of a metallocene catalyst in the metallocene catalyst solution, and (ii) configured to determine a second concentration of the metallocene catalyst in the catalyst complex in the precontactor; and
(E) a control system (i) configured to control the first concentration of the metallocene catalyst in the metallocene catalyst solution, and (ii) configured to control the second concentration of the metallocene catalyst in the catalyst complex in the precontactor.

12. The polymer manufacturing system of claim 11 , further comprising a first transfer line configured to transfer the catalyst complex from an outlet of the precontactor to the polymerization reactor system.

13. The polymer manufacturing system of claim 11 , further comprising a second transfer line configured to transfer the metallocene catalyst solution from the catalyst solution tank to the precontactor.

14. The polymer manufacturing system of claim 11 , wherein the polymerization reactor system comprises one or more polymerization reactors selected independently from a fluidized bed reactor, a gas-phase reactor, a loop slurry reactor, or any combination thereof.

15. The polymer manufacturing system of claim 11 , wherein the polymerization reactor system comprises a loop slurry reactor.

16. The polymer manufacturing system of claim 11 , wherein the ultraviolet-visible analyzer is further configured to determine the first concentration and the second concentration at a selected wavelength using a calibration curve.

17. The polymer manufacturing system of claim 11 , wherein:
the activator comprises a chemically-treated solid oxide; and
the co-catalyst comprises an alkyl aluminum compound.

18. The polymer manufacturing system of claim 11 , wherein the polymerization reactor system is configured to contact the catalyst complex with ethylene and an olefin comonomer comprising 1-butene, 1-hexene, 1-octene, or a mixture thereof.

19. The polymer manufacturing system of claim 11 , wherein the catalyst solution tank contains an agitator configured to mix the metallocene catalyst and a solvent to form the metallocene catalyst solution.

20. The polymer manufacturing system of claim 11 , further comprising a heating system coupled to the catalyst solution tank and configured to maintain a temperature of the metallocene catalyst solution.

21. The polymer manufacturing system of claim 11 , wherein the ultraviolet-visible analyzer further comprises a filter for filtering a sample of the metallocene catalyst solution containing the metallocene catalyst prior to analysis.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Benham Elizabeth A
• Masino Albert P
• Yang Qing
• Muninger Randy S
• Gonzales Rebecca A

Classifications

• B01J19/1837 Primary

  Loop-type reactors · CPC title

• B01J2219/00094

  Jackets · CPC title

• B01J2219/00186

  controlling the composition of the reactive mixture · CPC title

• C08F2500/05

  Bimodal or multimodal molecular weight distribution · CPC title

• C08F2500/07

  High density, i.e. > 0.95 g/cm3 · CPC title