Process for removing methane from a gas

Patent metadata

Field	Value
Publication number	US-10828601-B2
Application number	US-201415021630-A
Country	US
Kind code	B2
Filing date	Oct 17, 2014
Priority date	Oct 21, 2013
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

In a method for removing methane from feed gas having a methane concentration of 2 mole % or less, the feed gas is optionally mixed with make-up methane or air and passed through a heat exchanger to heat the gas to an oxidation reactor inlet temperature T1. The heated stream is passed to the reactor where the methane is oxidised. A gas stream including the products of the oxidation reaction are removed with the gas stream being at a reactor outlet temperature T2 higher than the inlet temperature T1. The gas stream is then passed through the heat exchanger against the reactor stream to recover heat from the gas stream removed in the reactor and to heat the reactor stream. The outlet temperature T2 is measured and the inlet temperature T1 is controlled by adjusting the relative amount of make-up methane and/or air added to the feed gas.

First claim

The invention claimed is:

1. A method for removing methane from feed gas having a methane concentration of 2 mole % or less using a system that includes
a feed gas line for supplying the feed gas to a heat exchanger, an oxidation reactor that receives feed gas that has been heated by the heat exchanger, and a make-up methane feed line for supplying make-up methane for mixing with the feed gas in the feed gas line, said method comprising the steps of:
(a) passing the feed gas through the heat exchanger to raise the temperature of the feed gas to a desired inlet temperature of the oxidation reactor;
(b) passing the heated feed gas from step (a) to the oxidation reactor containing an oxidation catalyst, where the methane in the feed gas is oxidised;
(c) removing a gas stream including the products of the oxidation reaction from the reactor, said gas stream being at an outlet temperature which is higher than the inlet temperature;
(d) passing the gas stream removed in step (c) through the heat exchanger against the feed gas from step (a) to allow the heat to be recovered from the gas stream removed in step (c) and utilised to heat the feed gas in step (a);
(e) comparing the outlet temperature with a pre-determined desired temperature, and, when the outlet temperature falls below the desired temperature, adding make-up methane from the make-up methane feed line to the feed gas in order to increase the methane concentration, such that following the temperature rise occasioned by the reaction, the outlet temperature approaches the desired temperature.

2. The method according to claim 1 wherein the catalyst contains at least one of palladium and platinum on a support.

3. The method according to claim 2 wherein the support is an oxidic support.

4. The method according to claim 1 wherein the catalyst support is presented in a honeycomb configuration.

5. The method according to claim 2 wherein the inlet temperature is at least 350° C.

6. The method according to claim 2 wherein the outlet temperature is 650° C. or less.

7. The method according to claim 1 wherein the feed gas has less than 1 mole % methane.

8. The method according to claim 1 wherein the feed gas has less than 0.5 mole % methane.

9. The method according to claim 1 wherein the feed gas has less than about 0.1 mole % methane.

Assignees

• Johnson Matthey Davy Technologies Ltd

Inventors

• Watson David
• Swinney John

Classifications

• B01D2255/1021

  Platinum · CPC title

• B01D53/86 Primary

  Catalytic processes · CPC title

• B01D2258/06

  Polluted air · CPC title

• B01D53/864 Primary

  Removing carbon monoxide or hydrocarbons · CPC title

• B01D2255/1023

  Palladium · CPC title