Removal of dust in urea finishing

Patent metadata

Field	Value
Publication number	US-10828593-B2
Application number	US-201816236097-A
Country	US
Kind code	B2
Filing date	Dec 28, 2018
Priority date	Jul 5, 2013
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

Disclosed is a method for the removal of urea dust from the off-gas of a finishing section of a urea production plant. the method comprises subjecting the off-gas to quenching with water so as to produce quenched off-gas, and subjecting the quenched off-gas to scrubbing using at least one venturi scrubber. As a result, a lower pressure drop over the scrubber is attained, and a more efficient growth of urea particles, facilitating the removal thereof.

First claim

The invention claimed is:

1. A finishing equipment for a urea plant, said finishing equipment comprising a quenching system, one or more venturi scrubbers and a urea finishing device,
wherein the urea finishing device comprises an inlet for liquid urea, an inlet for cooling gas, a collector for solid urea, and an outlet for off-gas,
wherein said quenching system comprises an inlet that is connected with said outlet for off-gas of the urea finishing device and comprises an outlet for quenched off-gas, and
wherein the one or more venturi scrubbers comprise(s) an inlet which is connected with said outlet for quenched off-gas.

2. A finishing equipment according to claim 1 , wherein the urea finishing device is a fluid bed granulation unit.

3. A finishing equipment according to claim 1 , wherein said venturi scrubber comprises a plurality of venturi tubes which are arranged in parallel.

4. A finishing equipment according to claim 1 , further comprising an acid scrubber for the removal of ammonia, which is arranged downstream of the one or more venturi scrubbers.

5. A finishing equipment according to claim 1 , wherein the one or more venturi scrubbers are of the micro mist venturi (MMV) type.

6. The finishing equipment according to claim 1 ,
wherein the at least one venturi scrubber is configured for subjecting the quenched off-gas to scrubbing to give scrubbed gas,
wherein said venturi scrubber comprises a throat, a converging section, and an entrance to said converging section,
wherein said venturi scrubber is furthermore configured for adding a scrubbing liquid to the venturi scrubber at said throat or at said entrance such that said added scrubbing liquid enters the quenched off-gas
wherein said quenching system is configured for subjecting the off-gas to quenching with water optionally in the form of an aqueous solution so as to produce quenched off-gas,
wherein the quenching system is arranged upstream of the venturi scrubber such that the quenching takes place before the off-gas enters the venturi scrubber, and
wherein the finishing equipment further comprises a washing section comprising an inlet for a washing liquid and configured for percolation of the washing liquid down through said washing section thereby collecting particles from said quenched off-gas stream.

7. A urea plant comprising a synthesis and recovery section, an evaporation section, a condensation section, a finishing section, a dust scrubbing section, and a quenching system,
wherein said synthesis and recovery section is in fluid communication with said evaporation section,
wherein said evaporation section is in fluid communication with said finishing section and has a gas flow line to the condensation section; and
wherein said finishing section has a gas flow line to said dust scrubbing section, wherein the dust scrubbing section comprises at least one venturi scrubber,
wherein said finishing section comprises a urea finishing device comprising an inlet for liquid urea, an inlet for cooling gas, a collector for solid urea, and an outlet for off-gas,
wherein said quenching system comprises an inlet that is connected with said outlet for off-gas of the urea finishing device and comprises an outlet for quenched off-gas, and
wherein the at least venturi scrubber comprises an inlet which is connected with said outlet for quenched off-gas.

8. The urea plant according to claim 7 ,
wherein the at least one venturi scrubber is configured for subjecting the quenched off-gas to scrubbing to give scrubbed gas,
wherein said venturi scrubber comprises a throat, a converging section, and an entrance to said converging section,
wherein said venturi scrubber is furthermore configured for adding a scrubbing liquid to the venturi scrubber at said throat or at said entrance such that said added scrubbing liquid enters the quenched off-gas
wherein said quenching system is configured for subjecting the off-gas to quenching with water optionally in the form of an aqueous solution so as to produce quenched off-gas,
wherein the quenching system is arranged upstream of the venturi scrubber such that the quenching takes place before the off-gas enters the venturi scrubber, and
wherein the finishing equipment further comprises a washing section comprising an inlet for a washing liquid and configured for percolation of the washing liquid down through said washing section thereby collecting particles from said quenched off-gas stream.

9. A method of modifying an existing urea plant, said plant comprising a synthesis and recovery section (A), an evaporation section (B), a finishing section (C), a dust scrubbing section (D) and a condensation section (E),
wherein said synthesis and recovery section (A) is in fluid communication with said evaporation section (B),
wherein said evaporation section (B) is in fluid communication with said finishing section (C) and has a gas flow line to a condensation section (E);
wherein said finishing section (C) has a gas flow line to a dust scrubbing section (D), wherein the dust scrubbing section (D) comprises at least one venturi scrubber (F), wherein the method comprises installing a quenching system (G) between the finishing section (C) and the at least one venturi scrubber (F), wherein said quenching system is in fluid communication with a gas flow line from the finishing section (C) and with a gas flow line to venturi scrubber (F) comprised in the dust scrubbing section (D).

10. A method according to claim 9 , wherein the method comprises installing one or more venturi scrubbers in parallel to the already present venturi scrubber.

11. The method of modifying an existing urea plant according to claim 10 ,
wherein the at least one venturi scrubber is configured for subjecting the quenched off-gas to scrubbing to give scrubbed gas,
wherein said venturi scrubber comprises a throat, a converging section, and an entrance to said converging section,
wherein said venturi scrubber is furthermore configured for adding a scrubbing liquid to the venturi scrubber at said throat or at said entrance such that said added scrubbing liquid enters the quenched off-gas
wherein said quenching system is configured for subjecting the off-gas to quenching with water optionally in the form of an aqueous solution so as to produce quenched off-gas,
wherein the quenching system is arranged upstream of the venturi scrubber such that the quenching takes place before the off-gas enters the venturi scrubber, and
wherein the finishing equipment further comprises a washing section comprising an inlet for a washing liquid and configured for percolation of the washing liquid down through said washing section thereby collecting particles from said quenched off-gas stream.

12. A method according to claim 9 , wherein the plant further comprises an acid scrubber for the removal of ammonia downstream of the dust scrubbing section.

13. A method according to claim 9 , wherein the venturi scrubber is of the micro mist venturi (MMV) type.

Assignees

• Stamicarbon

Inventors

• Soons Petrus Catharina Gerlach
• Dirkx Wilfried Marc Renaat

Classifications

• C07C273/02

  of urea, its salts, complexes or addition compounds · CPC title

• B01D53/58

  Ammonia · CPC title

• C07C273/16

  Separation; Purification · CPC title

• B01J2/16

  by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain · CPC title

• B01D47/10 Primary

  Venturi scrubbers · CPC title