Gas detector and method of detection

Patent metadata

Field	Value
Publication number	US-10823671-B2
Application number	US-201515761148-A
Country	US
Kind code	B2
Filing date	Dec 22, 2015
Priority date	Oct 17, 2015
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

One or more light sources emit light within first, second, and third wavelength ranges through exhaust gas. The first and second wavelength ranges are characterized by first and second different absorption wavelength ranges of a background gas. The third wavelength range is characterized by an absorption wavelength range of a gas-of-interest. At least some of the light within the first, second, and third wavelength ranges is absorbed by the exhaust gas thereby providing modified light characterized by the first, second, and third absorption wavelength ranges. One or more detectors receive the modified light. A processing subsystem determines a temperature of the exhaust gas based on the modified light characterized by the first and second absorption wavelength ranges and a concentration of the gas-of-interest based on the modified light characterized by the third absorption wavelength range and the temperature of the exhaust gas.

First claim

The invention claimed is:

1. A system comprising:
an exhaust-gas-duct configured to receive an exhaust gas comprising a gas-of-interest and a background gas;
one or more light sources operatively coupled to the exhaust-gas-duct and configured to emit light within first, second, and third wavelength ranges, through the exhaust gas, wherein the first wavelength range is characterized by a first absorption wavelength range of the background gas, wherein the second wavelength range is characterized by a second absorption wavelength range of the background gas, wherein the first and second wavelength ranges are not identical, and wherein the third wavelength range is characterized by an absorption wavelength range of the gas-of-interest;
one or more detectors operatively coupled to the exhaust-gas-duct and configured to receive the light that has traversed through the exhaust gas from the one or more light sources, wherein at least some of the light within the first, second, and third wavelength ranges is absorbed by the exhaust gas thereby providing modified light for detection characterized by the first, second, and third absorption wavelength ranges;
a processing subsystem communicatively coupled to the one or more detectors and configured to determine a temperature of the exhaust gas based on the modified light characterized by the first and second absorption wavelength ranges and to determine a concentration of the gas-of-interest based on the modified light characterized by the third absorption wavelength range and the determined temperature of the exhaust gas; and
an absorption cell located outside the exhaust-gas-duct and configured to receive a portion of the exhaust gas and maintaining the portion of the exhaust gas at a temperature level substantially equal to the determined temperature, wherein the one or more light sources are configured to emit the light within the third wavelength range through the absorption cell.

2. The system of claim 1 , wherein the gas-of-interest comprises nitrogen oxide.

3. The system of claim 1 , wherein the background gas comprises water, water vapor, or a combination thereof.

4. The system of claim 1 , wherein the one or more light sources are configured for emitting the light within the first, second, and third wavelength ranges directly through the exhaust-gas-duct.

5. The system of claim 1 , further comprising a coupling unit coupled to the exhaust-gas-duct and the absorption cell, wherein the coupling unit comprises:
a tube extending from the exhaust-gas-duct to the absorption cell and configured to direct the portion of the exhaust gas from the exhaust-gas-duct to the absorption cell; and
a first temperature control unit communicatively coupled to the tube and configured to maintain the portion of the exhaust gas at the determined temperature within the tube.

6. The system of claim 5 , wherein the absorption cell comprises a second temperature control unit configured to maintain the portion of the exhaust gas at the determined temperature within the absorption cell.

7. The system of claim 1 , further comprising an absorption cell located inside the exhaust-gas-duct, and wherein the absorption cell comprises a multi-pass absorption cell.

8. The system of claim 1 , wherein the light comprises a combined single light beam.

9. The system of claim 8 , wherein the one or more light sources comprise a tunable laser source, a diode laser, a laser, a distributed feedback laser source, or a quantum cascade laser source.

10. The system of claim 1 , wherein a concentration of the background gas is at least 2%, and wherein the gas-of-interest is different from the background gas.

11. The system of claim 1 , wherein the processing subsystem is further configured to determine the temperature of the exhaust gas within the exhaust-gas-duct based on a ratio of an intensity of the modified light characterized by the first absorption wavelength range and an intensity of the modified light characterized by the second absorption wavelength range.

12. A method, comprising:
receiving an exhaust gas comprising a gas-of-interest and a background gas;
emitting light through the exhaust gas, wherein the light is within first, second, and third wavelength ranges, wherein the first wavelength range is characterized by a first absorption wavelength range of the background gas, the second wavelength range is characterized by a second absorption wavelength range of the background gas, wherein the first and second absorption wavelength ranges are not identical, and wherein the third wavelength range is characterized by a third absorption wavelength range of the gas-of-interest;
receiving light that has traversed through the exhaust gas, wherein at least some of the light within the first, second, and third wavelength ranges is absorbed by the exhaust gas thereby providing modified light for detection within the first, second, and third absorption wavelength ranges;
determining a temperature of the exhaust gas based on the modified light characterized by the first and second absorption wavelength ranges and determining a concentration of the gas-of-interest based on the modified light characterized by the third absorption wavelength range and the determined temperature of the exhaust gas; and
receiving a portion of the exhaust gas in an absorption cell and maintaining the portion of the exhaust gas in the absorption cell at a temperature level substantially equal to the determined temperature.

13. The method of claim 12 , wherein the light comprises a single combined light beam.

14. The method of claim 12 , determining the temperature of the exhaust gas within an exhaust-gas-duct based on a ratio of an intensity of the modified light characterized by the first absorption wavelength range and an intensity of the modified light characterized by the second absorption wavelength range.

15. The method of claim 12 , wherein the gas-of-interest comprises nitrogen oxide.

16. The method of claim 12 , wherein the background gas comprises water, water vapor, or a combination thereof.

17. A system comprising:
an exhaust-gas-duct configured to receive an exhaust gas comprising water, water vapor and nitrogen oxide;
one or more light sources operatively coupled to the exhaust-gas-duct and configured to emit light within first, second, and third wavelength ranges, through the exhaust gas, wherein the first wavelength range is characterized by a first absorption wavelength range of the water or water vapor, wherein the second wavelength range is characterized by a second absorption wavelength range of the water or water vapor, wherein the first and second wavelength ranges are not identical, and wherein the third wavelength range is characterized by a third absorption wavelength range of the nitrogen oxide;
one or more detectors operatively coupled to the exhaust-gas-duct and configured to receive the light that has traversed through the exhaust gas from the one or more light sources, wherein at least some of the light within the first, second, and third wavelength ranges is absorbed by the exhaust gas thereby providing modified light for detection characterized by the first, second, and third absorption wavelength ranges;
a processing subsystem communicatively coupled to the one or more detectors and configured to determine a temperature of the exhaust gas based on the modified light characterized by the first and second absorption wavelength ranges and to determine a concentration of the nitrogen oxide based on the modified light characterized by the third absorption wavelength ra

Assignees

• General Electric Comany
• Gen Electric

Inventors

• Sharma Rachit
• Moyeda David Kelly
• Mitra Chayan
• Sridharan Arun Kumar
• Bekal Anish
• Fung Eric Yuhang

Classifications

• G01N21/3504 Primary

  for analysing gases, e.g. multi-gas analysis · CPC title

• F01N2560/026

  for measuring or detecting NOx · CPC title

• F01N2560/06

  the means being a temperature sensor · CPC title

• G01N21/39 Primary

  using tunable lasers · CPC title

• G01N21/0332

  with temperature control (control of temperature G05D23/00; cryostats F17C3/08) · CPC title