Hot-dip galvanized steel sheet

Patent metadata

Field	Value
Publication number	US-10822684-B2
Application number	US-201515522243-A
Country	US
Kind code	B2
Filing date	Nov 5, 2015
Priority date	Nov 5, 2014
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

A hot-dip galvanized steel sheet includes a base steel sheet and a hot-dip galvanized layer formed on at least one surface of the base steel sheet, in which the hot-dip galvanized layer includes Fe in a content of more than 0% to 5% or less, Al in a content of more than 0% to 1.0% or less, and columnar grains formed by a ζ phase on the surface of the steel sheet, further, 20% or more of the entire interface between the hot-dip galvanized layer and the base steel sheet is coated with the ζ phase, and a ratio of an interface formed between ζ grains in which coarse oxides are present among ζ grains and the base steel sheet with respect to the entire interface between the ζ phase and the base steel sheet in the hot-dip galvanized layer is 50% or less, the base steel sheet has predetermined chemical components and a refined layer in direct contact with the interface between the base steel sheet and the hot-dip galvanized layer, an average thickness of the refined layer is 0.1 to 5.0 μm, an average grain size of ferrite in the refined layer is 0.1 to 3.0 μm, one or two or more of oxides of Si and Mn are contained in the refined layer, and a maximum size of the oxide is 0.01 to 0.4 μm.

First claim

The invention claimed is:

1. A hot-dip galvanized steel sheet comprising:
a base steel sheet; and
a hot-dip galvanized layer formed on at least one surface of the base steel sheet, wherein:
the hot-dip galvanized layer includes, % by mass, Fe in a content of more than 0% to 5% or less, Al in a content of more than 0% to 1.0% or less, and columnar grains formed by a ζ phase on a surface of the steel sheet, further, 20% or more of an entire interface between the hot-dip galvanized layer and the base steel sheet is coated with the ζ phase, and a ratio of an interface between coarse oxide-containing ζ grains and the base steel sheet is 50% or less with respect to an entire interface between the ζ phase and the base steel sheet in the hot-dip galvanized layer,
a ratio of an interface between a δ1 phase and the base steel sheet is 20% or less with respect to the entire interface between the hot-dip galvanized layer and the base steel sheet;
the base steel sheet includes a chemical composition which comprises, % by mass,
C: 0.040% to 0.400%,
Si: 0.05% to 2.50%,
Mn: 0.50% to 3.50%,
P: 0.0001% to 0.1000%,
S: 0.0001% to 0.0100%,
Al: 0.001% to 1.500%,
N: 0.0001% to 0.0100%,
O: 0.0001% to 0.0100%, and
a remainder of Fe and unavoidable impurities;
the base steel sheet has a refined layer in direct contact with the interface between the base steel sheet and the hot-dip galvanized layer, an average thickness of the refined layer is 0.1 to 5.0 μm, an average grain size of ferrite in the refined layer is 0.1 to 3.0 μm, one or two or more of oxides of Si and Mn are contained in the refined layer, and a maximum size of the one or two or more of oxides of Si and Mn is 0.01 to 0.4 μm,
a plating of the hot-dip galvanized steel sheet is not peeled off under a plating adhesion evaluation with DuPont impact test,
wherein the plating adhesion evaluation is performed by
performing DuPont impact test to the hot-dip galvanized steel sheet to which 5% uniaxial tension strain was applied,
attaching an adhesive tape to the hot-dip galvanized steel sheet after the impact test,
peeling off the adhesive tape from the hot-dip galvanized steel sheet after attaching the adhesive tape,
confirming whether or not the plating of the hot-dip galvanized steel sheet is peeled off,
wherein DuPont impact test was performed by dropping a weight of 3 kg onto the hot-dip galvanized steel sheet from a height of 1 m using a punching die having a radius of curvature of a front end of ½ inch.

2. The hot-dip galvanized steel sheet according to claim 1 ,
wherein a plated amount of the hot-dip galvanized layer on one surface of the base steel sheet in the hot-dip galvanized layer is 10 g/m 2 or more and 100 g/m 2 or less.

3. The hot-dip galvanized steel sheet according to claim 1 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from
Ti: 0.001% to 0.150%,
Nb: 0.001% to 0.100%, and
V: 0.001% to 0.300%.

4. The hot-dip galvanized steel sheet according to claim 2 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from
Ti: 0.001% to 0.150%,
Nb: 0.001% to 0.100%, and
V: 0.001% to 0.300%.

5. The hot-dip galvanized steel sheet according to claim 1 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from
Cr: 0.01% to 2.00%,
Ni: 0.01% to 2.00%,
Cu: 0.01% to 2.00%,
Mo: 0.01% to 2.00%,
B: 0.0001% to 0.0100%, and
W: 0.01% to 2.00%.

6. The hot-dip galvanized steel sheet according to claim 2 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from
Cr: 0.01% to 2.00%,
Ni: 0.01% to 2.00%,
Cu: 0.01% to 2.00%,
Mo: 0.01% to 2.00%,
B: 0.0001% to 0.0100%, and
W: 0.01% to 2.00%.

7. The hot-dip galvanized steel sheet according to claim 3 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from
Cr: 0.01% to 2.00%,
Ni: 0.01% to 2.00%,
Cu: 0.01% to 2.00%,
Mo: 0.01% to 2.00%,
B: 0.0001% to 0.0100%, and
W: 0.01% to 2.00%.

8. The hot-dip galvanized steel sheet according to claim 4 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from
Cr: 0.01% to 2.00%,
Ni: 0.01% to 2.00%,
Cu: 0.01% to 2.00%,
Mo: 0.01% to 2.00%,
B: 0.0001% to 0.0100%, and
W: 0.01% to 2.00%.

9. The hot-dip galvanized steel sheet according to claim 1 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

10. The hot-dip galvanized steel sheet according to claim 2 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

11. The hot-dip galvanized steel sheet according to claim 3 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

12. The hot-dip galvanized steel sheet according to claim 4 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

13. The hot-dip galvanized steel sheet according to claim 5 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

14. The hot-dip galvanized steel sheet according to claim 6 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

15. The hot-dip galvanized steel sheet according to claim 7 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

16. The hot-dip galvanized steel sheet according to claim 8 ,
wherein the base steel sheet further contains, % by mass, one or two or more selected from Ca, Ce, Mg, Zr, La, and REM in a total amount of 0.0001% to 0.0100%.

Assignees

• Nippon Steel Corp

Inventors

• Kawata Hiroyuki
• Yasui Takeshi
• Ueda Kohei
• Maruyama Naoki
• Yamaguchi Yuji
• Uchida Satoshi
• KOMAMI Ryosuke
• Arai Hayato
• Nakamura Toyomitsu

Classifications

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• C23C2/28

  Thermal after-treatment, e.g. treatment in oil bath · CPC title

• C21D8/0257

  with diffusion of elements, e.g. decarburising, nitriding · CPC title

• C22C38/58

  with more than 1.5% by weight of manganese · CPC title

• C22C38/00

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title