Method of fabricating a ceramic composite

Patent metadata

Field	Value
Publication number	US-10822282-B2
Application number	US-201816192265-A
Country	US
Kind code	B2
Filing date	Nov 15, 2018
Priority date	Nov 15, 2018
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

A method of making a ceramic composite component includes providing a fibrous preform or a plurality of fibers, providing a first plurality of particles, coating the first plurality of particles with a coating to produce a first plurality of coated particles, delivering the first plurality of coated particles to the fibrous preform or to an outer surface of the plurality of fibers, and converting the first plurality of coated particles into refractory compounds. The first plurality of particles or the coating comprises a refractory metal.

First claim

The invention claimed is:

1. A method of making a ceramic composite component, the method comprising:
providing a fibrous preform or a plurality of fibers;
providing a first plurality of particles;
coating the first plurality of particles with a coating to produce a first plurality of coated particles, wherein the first plurality of particles or the coating comprises a refractory metal;
delivering the first plurality of coated particles to the fibrous preform or to an outer surface of the plurality of fibers;
wherein the first plurality of coated particles forms a portion of a matrix and wherein the matrix contains 12 to 80 percent of the first plurality of coated particles by volume; and
converting the first plurality of coated particles into refractory compounds.

2. The method of claim 1 , wherein the first plurality of coated particles is mixed with a preceramic polymer for delivery to the preform or fibers.

3. The method of claim 2 and further comprising processing the preceramic polymer and refractory compounds to produce a ceramic matrix composite containing the refractory compounds.

4. The method of claim 1 , wherein converting the first plurality of coated particles into refractory compounds comprises applying radiative or thermal energy to the first plurality of coated particles.

5. The method of claim 1 , wherein the first plurality of particles are selected from a group consisting of powder, platelets, and chopped fibers.

6. The method of claim 5 , wherein the coating comprises the refractory metal and the first plurality of particles comprise a material selected from the group consisting of carbon and boron.

7. The method of claim 6 , wherein for a first subset of the first plurality of coated particles, each coated particle comprises a stoichiometric ratio of the material forming the first plurality of particles and the refractory metal.

8. The method of claim 6 , wherein for a second subset of the first plurality of coated particles, each coated particle comprises an excess amount of the carbon or boron than needed for a stoichiometric mixture with the refractory metal such that the resulting refractory compounds form around carbon or boron cores.

9. The method of claim 6 , wherein for a third subset of the first plurality of coated particles, each coated particle comprises an excess amount of the refractory metal than needed for a stoichiometric reaction with the carbon or boron.

10. The method of claim 9 , wherein the first subset of the first plurality of coated particles is delivered to an outer surface of the fibrous preform.

11. The method of claim 6 , wherein the first plurality of coated particles comprises:
a first subset of the first plurality of coated particles, wherein each coated particle of the first subset comprises a stoichiometric ratio of the material forming the first plurality of particles and the refractory metal;
a second subset of the first plurality of coated particles, wherein each coated particle of the second subset comprises an excess amount of the carbon or boron than needed for a stoichiometric mixture with the refractory metal such that the resulting refractory compounds form around carbon or boron cores; and
a third subset of the first plurality of coated particles, wherein each coated particle of the third subset comprises an excess amount of the refractory metal than needed for a stoichiometric reaction with the carbon or boron.

12. The method of claim 1 , wherein the first plurality of particles comprise the refractory metal and the coating comprises a material selected from the group consisting of carbon and boron.

13. The method of claim 12 and further comprising:
providing a second plurality particles comprising a material selected from the group consisting of carbon and boron;
coating the second plurality of particles with a refractory metal to produce a second plurality of coated particles; and
converting the second plurality of coated particles into refractory compounds.

14. The method of claim 1 , wherein the refractory metal is selected from the group consisting of hafnium, titanium, tantalum, niobium, zirconium, vanadium, rhenium, and mixtures thereof.

15. The method of claim 1 and further comprising:
densifying the fibrous preform to form a composite structure; and
processing the composite structure to produce a final form of the component.

16. A component for use in ultra-high temperatures, the component comprising:
a ceramic matrix;
a plurality of refractory compounds distributed throughout the ceramic matrix, wherein the plurality of refractory compounds comprises refractory carbides or refractory borides comprising a refractory metal and containing unreacted carbon or boron cores, respectively.

17. The component of claim 16 and further comprising a plurality of refractory oxides distributed on a surface of the component, wherein the refractory oxides comprise a refractory metal.

18. A method of making a ceramic composite component, the method comprising:
providing a fibrous preform or a plurality of fibers;
providing a first plurality of particles comprising a refractory metal;
coating the first plurality of particles with a coating comprising a material selected from the group consisting of carbon and boron to produce a first plurality of coated particles;
delivering the first plurality of coated particles to the fibrous preform or to an outer surface of the plurality of fibers; and
converting the first plurality of coated particles into refractory compounds.

19. The method of claim 17 and further comprising:
providing a second plurality particles comprising a material selected from the group consisting of carbon and boron;
coating the second plurality of particles with a refractory metal to produce a second plurality of coated particles; and
converting the second plurality of coated particles into refractory compounds.

Assignees

• United Technologies Corp

Inventors

• Schmidt Wayde R
• Sheedy Paul

Classifications

• C04B35/515 Primary

  based on non-oxide ceramics · CPC title

• C04B2235/5288

  Carbon nanotubes · CPC title

• C04B2235/427

  Diamond · CPC title

• C04B2235/425

  Graphite · CPC title

• C04B2235/524

  Non-oxidic, e.g. borides, carbides, silicides or nitrides · CPC title