Accelerated CVI densification of CMC through infiltration

Patent metadata

Field	Value
Publication number	US-10822281-B2
Application number	US-201816185203-A
Country	US
Kind code	B2
Filing date	Nov 9, 2018
Priority date	Nov 9, 2018
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

A process for densification of a ceramic matrix composite comprises forming a reinforcing ceramic continuous fiber stack having a central zone bounded by an outer zone adjacent; locating first particles within the central zone; coating the first particles and the ceramic fibers with silicon carbide through chemical vapor infiltration; locating second particles within the outer zone; coating the second particles and the ceramic fibers with silicon carbide through chemical vapor infiltration; forming the stack into a predetermined three dimensional shape; and densifying the stack.

First claim

What is claimed is:

1. A process for densification of a ceramic matrix composite comprising:
forming a reinforcing ceramic continuous fiber stack having a central zone bounded by a middle zone and an outer zone adjacent said middle zone opposite said central zone;
locating small particles within said central zone;
coating said small particles and ceramic fibers with silicon carbide through chemical vapor infiltration;
locating medium particles within said middle zone;
coating said medium particles and said ceramic fibers with silicon carbide through chemical vapor infiltration;
locating large particles within said outer zone; and
coating said large particles and said ceramic fibers with silicon carbide through chemical vapor infiltration;
forming a preform into a predetermined three dimensional shape; and
densifying said reinforcing ceramic continuous fiber stack.

2. The process of claim 1 , wherein said reinforcing ceramic continuous fiber stack comprises fiber tows aligned into a plies, each fiber tow having a surface having pores.

3. The process of claim 2 , wherein said step of locating small particles within said central zone further comprises coating said surface of the fiber tow proximate said central zone with a slurry containing said small particles.

4. The process of claim 2 , wherein said step of locating medium particles within said middle zone further comprises coating said surface of the fiber tow proximate said middle zone with a slurry containing said medium particles.

5. The process of claim 2 , wherein said step of locating large particles within said outer zone further comprises coating said surface of the fiber tow proximate said outer zone with a slurry containing said large particles.

6. The process of claim 2 , wherein said step of densifying said stack comprises utilizing said chemical vapor infiltration to coat surfaces of said small, medium and large particles and coat surfaces of said fiber tows; and
heating said stack.

7. The process of claim 2 , further comprising:
prior to locating said small, medium and large particles, pre-coating said tows aligned into said stack of plies by employing an interface fiber coating; and
rigidizing said stack.

8. The process of claim 7 , further comprising:
infiltrating said small particles into said pores of said tow in said central zone, said middle zone and said outer zone by using a binder including said small particles;
removing said binder having said small particles from said middle zone and said outer zone.

9. The process of claim 8 , further comprising:
infiltrating said medium particles into said pores of said tow in said middle zone and said outer zone by using a binder including said medium particles;
removing said medium particles from said outer zone.

10. The process of claim 9 , further comprising:
infiltrating said large particles into said pores of said tow in said outer zone by using a binder including said large particles.

11. The process of claim 9 , wherein removing said small particles and said medium particles comprises soaking said stack in a solvent for a predetermined time to dissolve said binder from said middle and outer zones respectively.

12. The process of claim 1 , wherein said step of forming said stack into a predetermined three dimensional shape comprises placing said stack into a tool having a predetermined shape mold.

13. The process of claim 12 , wherein said step of forming said stack into a predetermined three dimensional shape comprises pressing said stack in said tool into said predetermined shape.

14. A process for densification of a ceramic matrix composite comprising:
forming a reinforcing ceramic continuous fiber stack having a central zone bounded by an outer zone;
locating first particles within said central zone;
coating said first particles and ceramic fibers with silicon carbide through chemical vapor infiltration;
locating second particles within said outer zone;
coating said second particles and said ceramic fibers with silicon carbide through chemical vapor infiltration;
forming said reinforcing ceramic continuous fiber stack into a predetermined three dimensional shape; and
densifying said reinforcing ceramic continuous fiber stack.

15. The process of claim 14 , further comprising:
coating a first slurry containing said first particles onto a surface of first plies that form said stack, such that a portion of said first particles infiltrate into pores of said first plies and a portion remain on the surface of said first plies;
coating a second slurry containing said second particles onto a surface of second plies that form said stack, such that a portion of said second particles infiltrate into pores of said second plies and a portion remain on the surface of said second plies; and
stacking said first plies in said central zone and said second plies into said outer zone to form the stack in said predetermined three dimensional shape.

16. The process of claim 15 , further comprising:
drying said slurry.

17. The process of claim 15 , further comprising:
pre-coating said first plies and said second plies that form said stack with an interface coating prior to applying said first slurry and second slurry.

18. The process of claim 17 , further comprising:
pre-coating comprises a chemical vapor infiltration process to build up at least one deposition layer onto the ceramic fibers.

19. A process for densification of a ceramic matrix composite comprising:
forming a reinforcing ceramic continuous fiber stack comprising fiber tows aligned into a plies, each fiber tow having a surface having pores, said reinforcing ceramic continuous fiber stack having a central zone bounded by a middle zone and an outer zone adjacent said middle zone opposite said central zone;
pre-coating said tows by employing an interface fiber coating;
rigidizing said reinforcing ceramic continuous fiber stack;
locating small particles within said central zone by infiltrating said small particles into said pores of said tow in said central zone, said middle zone and said outer zone by using a binder including said small particles;
removing said binder having said small particles from said middle zone and said outer zone;
coating said small particles and ceramic fibers with silicon carbide through chemical vapor infiltration;
locating medium particles within said middle zone;
coating said medium particles and said ceramic fibers with silicon carbide through chemical vapor infiltration;
locating large particles within said outer zone; and
coating said large particles and said ceramic fibers with silicon carbide through chemical vapor infiltration;
forming a preform into a predetermined three dimensional shape; and
densifying said reinforcing ceramic continuous fiber stack.

Assignees

• United Technologies Corp
• Raytheon Tech Corp

Inventors

• She Ying
• Beals James T
• Tang Xia
• Jackson Richard Wesley

Classifications

• C04B35/515 Primary

  based on non-oxide ceramics · CPC title

• C04B35/62863

  Silicon carbide · CPC title

• C04B2235/3826

  Silicon carbides · CPC title

• C04B2235/5463

  Particle size distributions · CPC title

• C04B2235/5436

  micrometer sized, i.e. from 1 to 100 micron · CPC title