Method of making a fiber preform for ceramic matrix composite (CMC) fabrication utilizing a fugitive binder

Patent metadata

Field	Value
Publication number	US-10822280-B2
Application number	US-201816116173-A
Country	US
Kind code	B2
Filing date	Aug 29, 2018
Priority date	Dec 15, 2017
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

A method of making a fiber preform for ceramic matrix composite (CMC) fabrication comprises laminating an arrangement of fibers between polymer sheets comprising an organic polymer, which may function as a fugitive binder during fabrication, to form a flexible prepreg sheet. A plurality of the flexible prepreg sheets are laid up in a predetermined geometry to form a stack, and the stack is heated to soften the organic polymer and bond together the flexible prepreg sheets into a bonded prepreg structure. Upon cooling of the bonded prepreg structure, a rigid preform is formed. The rigid preform is heated at a sufficient temperature to pyrolyze the organic polymer. Thus, a porous preform that may undergo further processing into a CMC is formed.

First claim

What is claimed is:

1. A method of making a fiber preform for ceramic matrix composite (CMC) fabrication, the method comprising:
laminating an arrangement of fibers between polymer sheets consisting of an organic polymer, thereby forming a flexible prepreg sheet consisting of the polymer sheets and the arrangement of fibers, the lamination comprising feeding the polymer sheets and the arrangement of fibers into opposing rollers and extracting the flexible prepreg sheet from the opposing rollers;
laying up a plurality of the flexible prepreg sheets in a predetermined geometry, thereby forming a stack of the flexible prepreg sheets;
heating the stack to soften the organic polymer and bond together the flexible prepreg sheets, thereby forming a bonded prepreg structure;
cooling the bonded prepreg structure, thereby forming a rigid preform; and
heating the rigid preform at a sufficient temperature to pyrolyze the organic polymer, thereby forming a porous preform for further processing.

2. The method of claim 1 , further comprising:
coating the porous preform with a fiber interphase material to form a coated preform;
rigidizing the coated preform to form a rigidized preform; and
infiltrating the rigidized preform with a slurry comprising a particulate matrix material to form an impregnated preform; and
melt infiltrating the impregnated preform with a molten metal or alloy, thereby fabricating a CMC.

3. The method of claim 1 , wherein the laying-up, the heating of the stack, and the cooling are carried out in a first tool, and
wherein the heating of the rigid preform to pyrolyze the organic polymer is carried out in a second tool.

4. The method of claim 1 , further comprising, prior to the laminating, forming each of the polymer sheets by extrusion from a polymer precursor.

5. The method of claim 4 , wherein the polymer precursor comprises a polymer solution or a polymer melt.

6. The method of claim 4 , wherein the extrusion is carried out at a temperature in a range from about 80° C. to about 200° C.

7. The method of claim 1 , wherein the lamination is carried out at a temperature in a range from about 80° C. to about 200° C.

8. The method of claim 1 , wherein the lamination comprises a pressure in a range from about 50 psi to about 200 psi.

9. The method of claim 1 , wherein the flexible prepreg sheet comprises a thickness in a range from about 0.004 in to about 0.015 in.

10. The method of claim 1 , wherein the arrangement of fibers comprises a woven arrangement or a unidirectional arrangement.

11. The method of claim 1 , wherein the predetermined geometry comprises a planar or curved shape.

12. The method of claim 1 , wherein the heating of the stack is carried out at a softening temperature in a range from about 80° C. to about 200° C.

13. The method of claim 1 , further comprising, during the heating of the stack, compressing the stack at a pressure in a range from about 50 psi to about 100 psi.

14. The method of claim 13 , wherein the compression of the stack comprises vacuum bagging or pressing.

15. The method of claim 1 , wherein the heating of the rigid preform to pyrolyze the organic polymer is carried out at a pyrolysis temperature in a range from about 200° C. to about 1000° C.

16. The method of claim 1 , wherein the organic polymer is selected from the group consisting of polyethylene carbonate, polypropylene carbonate, polyvinyl alcohol, and polyvinyl pyrollidone.

17. The method of claim 1 , wherein a decomposition product of the organic polymer during pyrolysis consists of carbon dioxide and water.

18. The method of claim 1 , wherein the fibers comprise a ceramic selected from the group consisting of silicon carbide and silicon nitride.

19. The method of claim 1 , wherein the fibers are continuous fibers comprising silicon carbide, and the CMC includes a matrix comprising silicon carbide.

20. A method of making a fiber preform for ceramic matrix composite (CMC) fabrication, the method comprising:
laminating an arrangement of fibers between polymer sheets consisting of an organic polymer, thereby forming a flexible prepreg sheet consisting of the polymer sheets and the arrangement of fibers;
laying up a plurality of the flexible prepreg sheets in a predetermined geometry, thereby forming a stack of the flexible prepreg sheets;
heating the stack to soften the organic polymer and bond together the flexible prepreg sheets, thereby forming a bonded prepreg structure;
cooling the bonded prepreg structure, thereby forming a rigid preform; and
heating the rigid preform at a sufficient temperature to pyrolyze the organic polymer, thereby forming a porous preform for further processing.

Assignees

• Rolls Royce High Temperature Composites Inc

Inventors

• Harris Stephen
• Smolenski David

Classifications

• C08J5/241

  using inorganic fibres · CPC title

• B29C70/00

  Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts · CPC title

• B32B5/024 Primary

  Woven fabric · CPC title

• C04B35/80

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B35/573

  obtained by reaction sintering {or recrystallisation} · CPC title