Splash screen

Patent metadata

Field	Value
Publication number	US-10822268-B2
Application number	US-201615569110-A
Country	US
Kind code	B2
Filing date	Apr 26, 2016
Priority date	Apr 29, 2015
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

A splash screen, and a process for making a splash screen, comprising a glass sheet, the glass sheet comprising, a substrate of soda lime silica glass having a coating deposited on at least at least a first surface, the coating comprising a corrosion-protection layer deposited directly on the first surface of the substrate, the corrosion-protection layer having a thickness in the range 24 nm to 125 nm and comprising pyrolytically deposited silica with intentional doping of 7 atom % or lower. The splash screen provides reduced moisture induced corrosion of the glass surface.

First claim

The invention claimed is:

1. A splash screen comprising a glass sheet, the glass sheet comprising:
a substrate of soda lime silica glass having a coating deposited on at least a first surface,
the coating comprising a corrosion-protection layer deposited directly on the first surface of the substrate, the corrosion-protection layer having a thickness in the range 24 nm to 125 nm and comprising pyrolytically deposited silica with intentional doping of 7 atom % or lower,
further comprising a second corrosion-protection layer deposited on the second surface of the substrate, the second corrosion-protection layer comprising silica deposited from a liquid coating composition comprising a polysilazane; and
wherein the splash screen is a bath screen and/or a shower screen and wherein the glass substrate with corrosion-protection layer passes standard EN1096.

2. The splash screen as claimed in claim 1 , wherein the pyrolytically deposited silica has intentional doping of 5 atom % or lower.

3. The splash screen as claimed in claim 1 , wherein the pyrolytically deposited silica has intentional doping of 3 atom % or lower.

4. The splash screen as claimed in claim 1 , wherein the corrosion-protection layer comprises 93 mol % to 100 mol % silicon dioxide.

5. The splash screen as claimed in claim 1 , wherein the corrosion-protection layer has a thickness in the range 30 nm to 120 nm.

6. The splash screen as claimed in claim 1 , wherein the corrosion-protection layer has a thickness in the range 50 nm to 110 nm.

7. The splash screen as claimed in claim 1 , wherein the outer layer of the coating comprises pyrolytically deposited silica with intentional doping of 7 atom % or lower.

8. The splash screen as claimed in claim 1 , wherein the outer layer of the coating comprises the corrosion-protection layer.

9. The splash screen as claimed in claim 1 , wherein the corrosion-protection layer is the only layer of the coating on the first surface.

10. The splash screen as claimed in claim 1 , further comprising a further layer deposited on the corrosion-protection layer, the further layer comprising silica deposited from a liquid coating composition comprising a polysilazane.

11. The splash screen as claimed in claim 1 , wherein the substrate is adapted to hold fixings to fix the splash screen in position for use.

12. The splash screen as claimed in claim 11 , wherein the substrate is adapted to hold fixings by having at least one hole drilled through the substrate.

13. The splash screen as claimed in claim 1 , wherein the substrate is toughened.

14. The splash screen as claimed in claim 1 , further comprising fixings to fix the splash screen in position for use, and wherein the fixings comprise adhesive portions or mechanical attachment portions to attach the fixings to the splash screen.

15. A process for manufacturing a splash screen comprising a glass sheet, the process comprising:
providing a substrate of soda lime silica glass, pyrolytically depositing a corrosion-protection layer directly on a first surface of the substrate, the corrosion-protection layer comprising silica with intentional doping of 7 atom % or lower and being deposited to a thickness in the range 24 nm to 125 nm,
further providing a liquid coating composition comprising a polysilazane, contacting the second surface of the substrate with the coating composition, and
curing the coating composition at a predetermined curing temperature thereby forming a further layer comprising silica on the second surface, and
wherein the splash screen is a bath screen and/or a shower screen and wherein the glass substrate with corrosion-protection layer passes standard EN1096.

16. The process as claimed in claim 15 , wherein pyrolytically depositing the corrosion-protection layer comprises contacting the surface of the substrate with a precursor mixture comprising a source of silicon, a source of oxygen and, optionally, a radical scavenger.

17. The process as claimed in claim 15 , wherein the source of silicon comprises a silane.

18. The process as claimed in claim 15 , wherein the radical scavenger comprises an alkene and wherein pyrolytically depositing the corrosion-protection layer is conducted when the substrate is at a temperature in the range 550° C. to 750° C.

19. The process as claimed in claim 15 , wherein pyrolytically depositing the corrosion-protection layer is by online chemical vapour deposition conducted during the float glass production process.

20. The process as claimed in claim 15 , wherein the liquid coating composition comprises a solvent and wherein the polysilazane is a compound of formula [R 1 R 2 Si—NR 3 ] n , wherein one of R 1 , R 2 , and R 3 are each independently selected from H or C 1 to C 4 alkyl, and n is an integer.

21. The process as claimed in claim 15 , wherein the polysilazane comprises perhydropolysilazane.

22. The process as claimed in claim 15 , wherein contacting the second surface with the coating composition comprises a method selected from dip coating, spin coating, roller coating, spray coating, air atomisation spraying, ultrasonic spraying, and/or slot-die coating.

23. The process as claimed in claim 22 , further comprising cleaning the first and/or second surface before contacting the surface with the coating composition, and wherein cleaning the second surface comprises one or more of: abrasion with ceria, washing with alkaline aqueous solution, deionised water rinse and/or plasma treatment.

24. The process as claimed in claim 15 , wherein the predetermined curing temperature is a temperature of 130° C., and wherein curing the coating composition on the surface of the substrate comprises irradiating with ultraviolet (UV) radiation.

25. The process as claimed in claim 15 , wherein the polysilazane is at a concentration in the range 0.5% to 80% by weight in the coating composition.

26. The process as claimed in claim 15 , wherein the further silica layer is deposited to a thickness of 15 nm or higher.

27. The process as claimed in claim 15 , wherein the further layer of silica layer has a refractive index in the range 1.42 to 1.55.

28. The process for manufacturing a splash screen, the process comprising,
providing a soda lime silica glass substrate having a first and second surface, and a coating deposited on at least a first surface, the coating comprising a corrosion-protection layer deposited directly on the first surface of the substrate, the corrosion-protection layer having a thickness in the range 24 nm to 125 nm and comprising pyrolytically deposited silica with intentional doping of 7 atom % or lower,
providing a liquid coating composition comprising a polysilazane,
contacting the second surface of the substrate with the coating composition, and
curing the coating composition at a predetermined curing temperature, thereby forming a further layer comprising silica on the second surface, wherein the splash screen is a bath screen and/or a shower screen and wherein the glass substrate with corrosion-protection layer passes standard EN1096.

Assignees

• Pilkington Group Ltd

Inventors

• Hurst Simon James
• Colley Anna Louise
• Harris Peter Michael
• Cheetham Kieran James

Classifications

• C03C17/02 Primary

  with glass (C03C17/34, C03C17/44 take precedence) · CPC title

• C03C17/34

  with at least two coatings having different compositions (C03C17/44 takes precedence) · CPC title

• C03C17/42

  at least one coating of an organic material and at least one non-metal coating · CPC title

• C03B18/14

  Changing the surface of the glass ribbon, e.g. roughening (by chemical methods C03C) · CPC title

• C03C2218/11

  from solutions or suspensions · CPC title