Glasses having improved hydrolytic and alkali resistance

Patent metadata

Field	Value
Publication number	US-10822265-B2
Application number	US-201815892029-A
Country	US
Kind code	B2
Filing date	Feb 8, 2018
Priority date	Feb 8, 2017
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

A glass having a good hydrolytic resistance and alkali resistance is defined by a targeted combination of stoichiometric glasses, including glasses also existing as crystals in the same stoichiometry and whose properties can be assumed as being very similar due to the identical topology of the structural units for glass and crystal, respectively. A process of producing the glasses is also provided.

First claim

What is claimed is:

1. A glass having a composition of constituent phases, said constituent phases comprising:
reedmergnerite, from 9 to 80 mol %;
albite, from 1 to 40 mol %;
potassium reedmergnerite, from 0 to 60 mol %;
danburite, from 0 to 30%;
cordierite, from 0 to 20%;
willemite, from 0 to 20%;
silicon dioxide, from 0 to 65%;
diboron trioxide, from 0 to 20%;
pekovite, from 0 to 20%; and
maleevite, from 0 to 25%,
wherein the glass comprises surface glass and bulk glass and the total content of boron in the surface glass is at least 60% of the content of boron in the bulk glass and the content of boron in the surface glass is reduced in relation to the bulk glass by at least 1 mol %, wherein the surface glass is present in a depth of about 6 nm.

2. The glass according to claim 1 , wherein the sum of proportions of reedmergnerite, potassium reedmergnerite and albite is at least 50 mol %, and wherein said constituent phases comprise:
reedmergnerite, from 20 to 50 mol %;
albite, from 15 to 40 mol %;
potassium reedmergnerite, from 0 to 20 mol %;
danburite, from 0 to 15%;
cordierite, from 0 to 15%;
willemite, from 0 to 15%;
silicon dioxide, from 25 to 50%;
diboron trioxide, from 1 to 10%;
pekovite, from 0 to 10%; and
maleevite, from 0 to 10%.

3. The glass according to claim 1 , wherein said constituent phases comprise:
reedmergnerite, from 9 to 50 mol %;
albite, from 1 to 15 mol %;
potassium reedmergnerite, from 0 to 20 mol %;
danburite, from 0 to 30%;
cordierite, from 0 to 20%;
willemite, from 0 to 20%;
silicon dioxide, from 25 to 65%;
diboron trioxide, from 0 to 10%;
pekovite, from 0 to 20%; and
maleevite, from 0 to 25%.

4. The glass according to claim 1 , wherein a proportion of silicon dioxide is at most 50 mol %.

5. The glass according to claim 1 , wherein a proportion of diboron trioxide is at most 15 mol %.

6. The glass according to claim 1 , wherein a proportion of reedmergnerite in the glass is higher than a proportion of albite.

7. The glass according to claim 1 , wherein a proportion of reedmergnerite in the glass is higher than a proportion of potassium reedmergnerite.

8. The glass according to claim 1 , wherein the total content of boron in the surface glass is at least 80% of the content of boron in the bulk glass.

9. The glass according to claim 1 , comprising a number of angular degrees of freedom of up to 0.339.

10. The glass according to claim 1 , comprising a number of angular degrees of freedom of up to 0.328.

11. The glass according to claim 1 , comprising a number of angular degrees of freedom of up to 0.304.

12. The glass according to claim 1 , comprising a number of angular degrees of freedom less than 0.29.

13. The glass according to claim 1 , comprising a thermal expansion of from 3 ppm/K to 7 ppm/K.

14. The glass according to claim 1 , comprising a thermal expansion of from 4.5 ppm/K to 5.5 ppm/K.

15. The glass according to claim 1 , wherein a pH-value of <8.99 results from dissolution of 50 μmol glass in neutral water.

16. The glass according to claim 1 , wherein a pH-value of <8.79 results from dissolution of 50 μmol glass in neutral water.

17. The glass according to claim 1 , wherein the glass has an ablation rate of at most 135 mg/(dm 2 3 h).

18. The glass according to claim 1 , wherein the glass has an ablation rate of at most 125 mg/(dm 2 3 h).

19. The glass according to claim 1 , wherein the glass has an average potential well depth of from 1515 kJ/mol to 1715 kJ/mol.

20. A glass having a composition of constituent phases, said constituent phases comprising:
reedmergnerite, from 10 to 80 mol %;
albite, from 1 to 40 mol %;
potassium reedmergnerite, from 0 to 60 mol %;
danburite, from 0 to 30%;
cordierite, from 0 to 20%;
willemite, from 0 to 20%;
silicon dioxide, from 0 to 65%;
diboron trioxide, from 0 to 20%;
pekovite, from 0 to 20%; and
maleevite, from 0 to 25%,
wherein a number of angular degrees of freedom per atom in a bulk of the glass is less than 0.25, and wherein the glass has an average potential well depth of from 1515 kJ/mol to 1634 kJ/mol.

21. A process for producing a glass, comprising:
melting a plurality of glass raw materials to form a glass melt, the plurality of glass raw materials including
reedmergnerite, from 10 to 80 mol %,
albite, from 1 to 40 mol %,
potassium reedmergnerite, from 0 to 60 mol %,
danburite, from 0 to 30%,
cordierite, from 0 to 20%,
willemite, from 0 to 20%,
silicon dioxide, from 0 to 65%,
diboron trioxide, from 0 to 20%,
pekovite, from 0 to 20%, and
maleevite, from 0 to 25%; and
cooling of the glass melt.

22. The process according to claim 21 , further comprising:
after melting the plurality of glass raw materials to form the glass melt, forming a glass article from the glass melt.

23. The process according to claim 22 , wherein the glass article is a glass tube.

24. The process according to claim 22 , the process further comprising:
applying a water vapor containing gas to the glass during at least one of the forming and melting.

25. The process according to claim 21 , the process further comprising applying a water vapor containing gas to the glass during the melting.

Assignees

• Schott Ag

Inventors

• Fotheringham Ulrich
• Schwall Michael
• Ritter Simone
• Nass Peter
• Kass Christof
• Berndhäuser Christoph
• Gross Christoph

Classifications

• C03C4/20

  for chemical resistant glass · CPC title

• C03C2203/50

  After-treatment · CPC title

• C03C3/091 Primary

  containing aluminium · CPC title

• C03C3/093 Primary

  containing zinc or zirconium · CPC title

• C03C2203/10

  Melting processes · CPC title