Electrochemical desalination system with coupled electricity storage

Patent metadata

Field	Value
Publication number	US-10822254-B2
Application number	US-201916715252-A
Country	US
Kind code	B2
Filing date	Dec 16, 2019
Priority date	Aug 11, 2017
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

A desalination and energy storage system comprises at least one water reservoir, at least one negative-ion redox electrode, at least one positive-ion redox electrode, a cation-exchange membrane disposed between the at least one negative-ion redox electrode and the water reservoir, and an anion-exchange membrane disposed between the at least one positive-ion redox electrode and the water reservoir. The at least one water reservoir comprises an input and an output, wherein water in the at least one water reservoir is reduced below a threshold concentration during a desalination operation mode. The at least one negative-ion electrode comprises a first solution and is configured to accept, and have, a reversible redox reaction with at least one negative ion in the water, and the at least one positive-ion electrode comprises a second solution and is configured to accept, and have, a reversible redox reaction with at least one positive ion in the water.

First claim

What is claimed is:

1. A reversible desalination and energy storage system, comprising:
at least one reservoir comprising an input and an output, wherein solvent in the at least one reservoir is reduced below a threshold concentration during a desalination operation mode;
at least one negative-ion redox electrode comprising a first solution of a first electrolyte material and configured to accept, and have a reversible redox reaction with, at least one negative ion in the solvent;
at least one positive-ion redox electrode comprising a second solution of a second electrolyte material and configured to accept, and have a reversible redox reaction with, at least one positive ion in the solvent;
a cation-exchange membrane disposed between the at least one negative-ion redox electrode and the reservoir; and
an anion-exchange membrane disposed between the at least one positive-ion redox electrode and the reservoir.

2. The system of claim 1 , wherein the system is configured to remove dissolved ionic species from the solvent in the at least one reservoir having an electrolyte concentration of up to the solubility limit of the ionic species in the solvent.

3. The system of claim 1 , wherein the system is configured to add dissolved ionic species to the solvent in the at least one reservoir to provide an electrolyte concentration in the solvent of up to the solubility limit of the ionic species in the solvent.

4. The system of claim 1 , wherein the first solution, the second solution, and the solvent each has a pH between and including 3-10.

5. The system of claim 1 , wherein the system is configured to operate alternately in a desalination mode and a salination mode, wherein the salination mode comprises driving ions from the at least one negative-ion redox electrode and the at least one positive-ion redox electrode into the at least one reservoir while storing energy in the system, and the desalination mode comprises desalinating solvent while releasing stored energy as output power employing the at least one negative-ion redox electrode as a positive or negative output electrode and the at least one positive-ion redox electrode as a negative or positive output electrode.

6. The system of claim 1 , wherein the system has a standard cell potential of at least 0.8 V.

7. The system of claim 1 , wherein the input solvent comprises an industrial waste stream.

8. The system of claim 1 , wherein the input solvent comprises at least one of wastewater and a geothermal brine.

9. The system of claim 1 , further comprising a second desalination system coupled to the reservoir output, wherein the second desalination system uses a solvent treatment process other than an electrochemical battery.

10. The system of claim 9 , wherein the second desalination system uses reverse osmosis.

11. An apparatus, comprising:
a first system according to claim 1 ; and
a second system according to claim 1 .

12. The apparatus of claim 11 , wherein the first system and the second system are configured to operate in a desalination mode and a salination mode, and the first and second system operate in the same mode at the same time.

13. The apparatus of claim 11 , wherein the first system and the second system are configured to operate in a desalination mode and a salination mode, and the first and second systems operate in different modes at the same time.

14. A method, comprising:
providing an electrochemical desalination battery unit comprising:
at least one reservoir comprising an input and an output, wherein solvent in the at least one reservoir is reduced below a threshold concentration during a desalination operation mode;
at least one negative-ion redox electrode comprising a first solution of a first electrolyte material and configured to accept, and have a reversible redox reaction with, at least one negative ion in the solvent;
at least one positive-ion redox electrode comprising a second solution of a second electrolyte material and configured to accept, and have a reversible redox reaction with, at least one positive ion in the solvent;
a cation-exchange membrane disposed between the at least one negative-ion redox electrode and the reservoir; and
an anion-exchange membrane disposed between the at least one positive-ion redox electrode and the reservoir;

transporting solvent having a first salinity into the reservoir;
discharging the battery unit to provide solvent having a second salinity that is lower than the first salinity; and
removing the solvent having the second salinity from the battery unit.

15. The method of claim 14 , further comprising:
transporting the solvent having the second salinity into a second desalination system; and
desalinating the solvent to provide water having a third salinity that is lower than the second salinity.

16. The method of claim 15 , wherein the third salinity is equal to or less than 0.5 parts per thousand.

17. The method of claim 14 , further comprising:
in response to removing the solvent having the second salinity, transporting solvent having a fourth salinity into the reservoir; and
charging the battery unit to provide solvent having a fifth salinity that is higher than the fourth salinity.

18. The method of claim 17 , wherein the fourth salinity is equal to about the first salinity.

19. A reversible desalination and energy storage system comprising:
a central reservoir comprising a first electrolyte solution, an input and an output, wherein the first electrolyte solution has a first pH;
at least one negative-ion redox electrode comprising a second electrolyte solution and configured to accept, and have a reversible redox reaction with, at least one negative ion in the first electrolyte solution, wherein the second electrolyte solution has a second pH;
at least one positive-ion redox electrode comprising a third electrolyte solution and configured to accept, and have a reversible redox reaction with, at least one positive ion in the first electrolyte solution, wherein the third electrolyte solution has a third pH, and the second pH is less than the first pH and third pH;
a cation-exchange membrane disposed between the at least one negative-ion redox electrode and the central reservoir; and
an anion-exchange membrane disposed between the at least one positive-ion redox electrode and the central reservoir.

20. The system of claim 19 , wherein the system is configured to operate alternately in a desalination mode and a salination mode, wherein the salination mode comprises driving ions from the at least one negative-ion redox electrode and the at least one positive-ion redox electrode into the central reservoir while storing energy in the system, and the desalination mode comprises desalinating solvent while releasing stored energy as output power employing the at least one negative-ion redox electrode as a positive or negative output electrode and the at least one positive-ion redox electrode as a negative or positive output electrode.

Assignees

• Palo Alto Res Ct Inc

Inventors

• Desai Divyaraj
• Beh Eugene S
• Volkel Armin R
• Van Overmeere Quentin L C
• Rivest Jessica Louis Baker

Classifications

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/58

  of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates · CPC title

• H01M4/42

  Alloys based on zinc · CPC title

• H01M4/368

  Liquid depolarisers · CPC title

• C02F2201/4618

  Supplying or removing reactants or electrolyte · CPC title