Carbon dioxide trapping device and method capable of producing electricity

Patent metadata

Field	Value
Publication number	US-10818953-B2
Application number	US-201515115980-A
Country	US
Kind code	B2
Filing date	Feb 3, 2015
Priority date	Feb 3, 2014
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

An apparatus and process are provided for electricity production and high-efficiency trapping of carbon dioxide, using carbon dioxide within combustion exhaust gas and converging technologies associated with a carbon dioxide absorption tower and a generating device using ions which uses a difference in concentration of salinity between seawater and freshwater. It is expected that enhanced electrical energy production efficiency, an effect of reducing costs for the operation of a carbon dioxide trapping process, and electricity production from carbon dioxide, which is a greenhouse gas, can be simultaneously achieved by increasing the difference in concentration using an absorbent for absorbing carbon dioxide.

First claim

The invention claimed is:

1. A carbon dioxide capturing apparatus capable of producing electricity, comprising:
an absorption tower in which a gas including carbon dioxide comes in contact with an absorbent and is absorbed by the absorbent, the absorption tower comprising a flow path for discharging an absorption solution that has absorbed carbon dioxide;
an electricity-generating device including:
a space formed between a cation electrode and an anion electrode the space including a fluid solution flow path through which a fluid solution moves comprising a first flow path formed by a cation exchange membrane spaced apart from the cation electrode and a second flow path formed by an anion exchange membrane spaced apart from the anion electrode, and an absorption solution flow path connected to the flow path of the absorption tower between the first flow path and the second flow path to be supplied with the absorption solution that has absorbed carbon dioxide discharged from the absorption tower,
a heat exchanger in which the absorption solution that has absorbed carbon dioxide discharged from the absorption tower and a regenerated absorption solution passing through the electricity-generating device are heat-exchanged;
a first liquid transfer pump for supplying the absorption solution that has absorbed carbon dioxide discharged from the absorption tower through the heat exchanger to the absorption solution flow path; and
a second liquid transfer pump for supplying the regenerated absorption solution passing through the electricity-generating device through the heat exchanger to the absorption tower;
wherein the cation exchange membrane is a membrane that allows only cations to selectively pass through, and the anion exchange membrane is a membrane that allows only anions to selectively pass through, and
wherein when the absorption solution has a relatively higher concentration than the fluid solution or the absorption solution has a relatively lower concentration than the fluid solution, the absorption solution is supplied from the absorption tower to the absorption solution flow path of the electricity-generating device and the fluid solution is supplied to the fluid solution flow path, such that a cation passes through the cation exchange membrane and an anion passes through the anion exchange membrane due to the difference in concentration between the fluid solution and the absorption solution having absorbed carbon dioxide, so that electricity is generated by a potential difference by moving cations and anions at the electricity-generating device.

2. The carbon dioxide capturing apparatus capable of producing electricity according to claim 1 , wherein the absorbent includes, as a solute, one or more selected from an aqueous electrolyte group consisting of amines, alkali metal bicarbonates, alkali carbonates, carbonates, hydroxides, borates, phosphates, nitrates, acids, and sodium chloride and an organic electrolyte group consisting of propylene carbonate (PC), diethyl carbonate (DEC), and tetrahydrofuran (THF).

3. The carbon dioxide capturing apparatus capable of producing electricity according to claim 1 , wherein the absorbent further includes, as an additive, a corrosion inhibitor, a coagulant aid, an antioxidant, an oxygen scavenger, an antifoaming agent, or a combination thereof.

4. The carbon dioxide capturing apparatus capable of producing electricity according to claim 1 ,
wherein the absorbent includes, as a solvent, one or more materials selected from the group consisting of an aqueous solvent group and an organic solvent group,
wherein the aqueous solvent group includes a solvent selected from the group consisting of pure water, freshwater, brackish water, saline water, and a mixed solvent of an alcohol and water, and
wherein the organic solvent group includes an aliphatic hydrocarbon group consisting of hexane; an aromatic hydrocarbon group consisting of benzene, toluene, xylene, and methylnaphthalene; a heterocyclic compound group consisting of quinoline and pyridine; a ketone group consisting of acetone, methyl ethyl ketone, and cyclohexanone; an ester group consisting of methyl acetate and methyl acrylate; an amine group consisting of diethylenetriamine and N,N-dimethylaminopropylamine; an ether group consisting of diethyl ether, propylene oxide, and tetrahydrofuran (THF); an amide group consisting of N-methylpyrrolidone (NMP), dimethylformamide, and dimethylacetamide; and a polar aprotic solvent group consisting of hexamethylphosphoramide and dimethyl sulfoxide.

5. The carbon dioxide capturing apparatus capable of producing electricity according to claim 1 , wherein the absorption solution that has absorbed carbon dioxide, which is supplied to the absorption solution flow path, and the fluid solution supplied to the first flow path and the second flow path are supplied alternately.

6. The carbon dioxide capturing apparatus capable of producing electricity according to claim 1 , wherein the absorption solution that has absorbed carbon dioxide and the fluid solution are supplied in parallel.

Assignees

• Korea Inst Energy Res

Inventors

• Yoon Yeo Il
• Kim Han Ki
• Nam Sung Chan
• Kim Chan Soo
• Park Sung Youl
• Jeong Nam Jo
• Kim Young Eun

Classifications

• B01D53/965

  including an electrochemical process step · CPC title

• B01D53/62

  Carbon oxides · CPC title

• H01M8/227 Primary

  Dialytic cells or batteries; Reverse electrodialysis cells or batteries · CPC title

• B01D2252/204

  Amines · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title