Process for purification of a synthesis gas containing hydrogen and impurities

Patent metadata

Field	Value
Publication number	US-10816264-B2
Application number	US-201414899355-A
Country	US
Kind code	B2
Filing date	Jun 25, 2014
Priority date	Jun 26, 2013
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

A process for purification of a current of hydrogen synthesis gas ( 100 ), particularly in the front-end of an ammonia plant, wherein said gas contains hydrogen and minor amounts of carbon monoxide, carbon dioxide, water and impurities, said process including steps of methanation ( 13 ) of said current ( 100 ), converting residual amounts of carbon monoxide and carbon dioxide to methane and water, dehydration ( 14 ) of the gas to remove water, and then a cryogenic purification ( 15 ) such as liquid nitrogen wash, to remove methane and Argon; a corresponding plant and method for revamping an ammonia plant are also disclosed.

First claim

The invention claimed is:

1. A process for purification of a current of hydrogen synthesis gas f or obtaining a make-up synthesis gas for the synthesis of ammonia, said current of hydrogen synthesis gas to be purified being composed of hydrogen and minor amounts of carbon monoxide, carbon dioxide, water and impurities and containing at least 90% (mol) hydrogen, said process including a step of cryogenic purification, and dehydration of syngas through molecular sieves prior to said cryogenic purification, the process comprising a step of methanation of said current of hydrogen synthesis gas to be purified, wherein carbon monoxide and carbon dioxide are converted into methane and water, prior to said steps of dehydration and cryogenic purification, said step of cryogenic purification comprising a liquid nitrogen wash;
wherein hydrogen synthesis gas is washed with liquid nitrogen in a column and wherein said molecular sieves being regenerated by using tail gas discharged from said liquid nitrogen wash.

2. The process according to claim 1 , wherein said current of hydrogen synthesis gas to be purified is obtained by reforming of a hydrocarbon source with oxygen, shift conversion of carbon monoxide to carbon dioxide, and removal of carbon dioxide.

3. The process according to claim 1 , wherein a portion of the hydrogen synthesis gas, after said step of methanation and dehydration, bypasses said cryogenic purification.

Assignees

• Casale Sa

Inventors

• Filippi Ermanno
• Ostuni Raffaele
• Chiesa Damiano Marzari

Classifications

• C01B3/58

  including a catalytic reaction · CPC title

• C01B3/02 Primary

  Production of hydrogen; Production of gaseous mixtures containing hydrogen · CPC title

• C01B3/025 Primary

  Preparation or purification of gas mixtures for ammonia synthesis · CPC title

• C01B2203/147

  Three or more purification steps in series · CPC title

• C01B3/506

  at low temperatures · CPC title