Production equipment and production method of liquefied hydrogen and liquefied natural gas

Patent metadata

Field	Value
Publication number	US-10816262-B2
Application number	US-201616077484-A
Country	US
Kind code	B2
Filing date	Mar 10, 2016
Priority date	Mar 10, 2016
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

Provided is a production facility for liquefied hydrogen and a liquefied natural gas from a natural gas, including: a first heat exchanger configured to cool a hydrogen gas through heat exchange between the hydrogen gas and a mixed refrigerant for liquefying a natural gas containing a plurality of kinds of refrigerants selected from the group consisting of methane, ethane, propane, and nitrogen; a second heat exchanger configured to cool the mixed refrigerant through heat exchange between the mixed refrigerant and propane; and a third heat exchanger configured to cool the hydrogen gas through heat exchange between the hydrogen gas and a refrigerant containing hydrogen or helium, wherein the first heat exchanger has a precooling temperature of from −100° C. to −160° C.

First claim

The invention claimed is:

1. A production facility for liquefied hydrogen and a liquefied natural gas from a natural gas, comprising:
a first heat exchanger configured to cool a hydrogen gas through heat exchange between the hydrogen gas and a mixed refrigerant used for liquefying a natural gas containing a plurality of kinds of refrigerants selected from the group consisting of methane, ethane, propane, and nitrogen;
a second heat exchanger configured to cool the mixed refrigerant through heat exchange between the mixed refrigerant and propane; and
a third heat exchanger configured to cool the hydrogen gas through heat exchange between the hydrogen gas and a refrigerant containing hydrogen or helium,
wherein the first heat exchanger provides precooling at a precooling temperature of from −100° C. to −160° C.;

the production facility further comprises:
a liquefied hydrogen production line comprising at least one acid gas removal unit;
a liquefied natural gas production line comprising an acid gas removal unit; and
a single acid gas stripping unit shared between the liquefied hydrogen production line and the liquefied natural gas production line, and configured to collectively strip an acid gas absorbed in the acid gas removal units of the liquefied hydrogen production line and the liquefied natural gas production line,
wherein the liquefied natural gas production line is used for producing the liquefied natural gas and the liquefied hydrogen production line is used for producing a raw material hydrogen that is supplied as the hydrogen gas to the first heat exchanger.

2. The production facility for liquefied hydrogen and a liquefied natural gas according to claim 1 ,
wherein the liquefied hydrogen production line and the liquefied natural gas production line further comprises at least one natural gas pretreatment unit selected from the group consisting of a condensate separation unit, and a mercury removal unit,

so that a natural gas having been subjected to the pretreatment unit is divided into the liquefied hydrogen production line for producing the raw material hydrogen and the liquefied natural gas production line for producing the liquefied natural gas.

3. The production facility for liquefied hydrogen and a liquefied natural gas according to claim 1 ,
wherein the production facility comprises a plurality of the acid gas removal units in the liquefied hydrogen production line, and
wherein the single acid gas stripping unit is configured to collectively strip the acid gas absorbed in the acid gas removal unit in the liquefied natural gas production line and acid gases absorbed in the plurality of the acid gas removal units in the liquefied hydrogen production line.

4. A production method for liquefied hydrogen and a liquefied natural gas from a natural gas, comprising:
dividing a natural gas into a liquefied hydrogen production line for producing a hydrogen gas and a liquefied natural gas production line for producing a liquefied natural gas;
removing an acid gas from the natural gas in the liquefied natural gas production line and an acid gas from the natural gas in the liquefied hydrogen production line;
collectively stripping the acid gas removed from the natural gas in the liquefied natural gas production line and the acid gas removed from the natural gas in the liquefied hydrogen production line;
using a refrigerant for producing the liquefied natural gas in a precooling step for producing liquefied hydrogen,
the precooling step for producing liquefied hydrogen having a precooling temperature of from −100° C. to −160° C.,
the refrigerant for liquefying the natural gas comprising a mixed refrigerant containing a plurality of kinds of refrigerants selected from the group consisting of methane, ethane, propane, and nitrogen;

precooling the mixed refrigerant through heat exchange between the mixed refrigerant and propane; and
cooling the hydrogen gas supplied from the liquefied hydrogen production line through heat exchange between the hydrogen gas and a refrigerant containing hydrogen or helium.

5. The production method for liquefied hydrogen and a liquefied natural gas according to claim 4 , wherein the production method further comprises subjecting the natural gas in each of the liquefied hydrogen production line and the liquefied natural gas production line to at least one pretreatment selected from the group consisting of condensate separation treatment and mercury removal treatment.

6. The production method for liquefied hydrogen and a liquefied natural gas according to claim 4 , wherein the production method further comprises:
removing another acid gas from a process gas which is produced after a shift reaction of a reformed gas containing hydrogen as a main component in the liquefied hydrogen production line; and
collectively stripping the another acid gas produced after the shift reaction together with the acid gas removed from the natural gas in the liquefied natural gas production line and the acid gas removed from the natural gas in the liquefied hydrogen production line.

Assignees

• Jgc Corp

Inventors

• Watanabe Yoshiyuki
• Omori Hidefumi
• Matsuhara Toru
• Watanabe Shintaro
• Nakayama Toru

Classifications

• F25J1/0229

  Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock · CPC title

• C01B3/38

  using catalysts · CPC title

• F25J1/0087

  Propane; Propylene · CPC title

• F25J1/004

  by flash gas recovery (F25J1/0267 takes precedence) · CPC title

• F25J1/0217

  as at least a three level refrigeration cascade with at least one MCR cycle · CPC title