Apparatus and process for synthesizing natural gas using carbon dioxide and water in air

Patent metadata

Field	Value
Publication number	US-10815442-B2
Application number	US-201916460071-A
Country	US
Kind code	B2
Filing date	Jul 2, 2019
Priority date	Jul 2, 2018
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

An apparatus for producing a natural gas using carbon dioxide and water in air that includes an air-compressing member, a water collecting member, a water storing member, a carbon dioxide collecting member, a water electrolysis member, and a methanation reaction member. The water electrolysis member electrolyzes water separated from compressed air. The methanation reaction member generates a natural gas by reacting hydrogen from the electrolysis and carbon dioxide from the carbon dioxide collecting member. A method of producing a natural gas using carbon dioxide and water in air includes supplying hydrogen electrolyzed from water separated from air and carbon dioxide collected from the dry air to a methanation reaction member to generate a natural gas. A natural gas-synthesizing equipment system includes an apparatus for producing a natural gas using carbon dioxide and water in air.

First claim

I claim:

1. An apparatus for producing a natural gas using carbon dioxide and water in air, comprising:
an air-compressing member;
a water collecting member for collecting and separating water from the compressed air supplied from the air-compressing member;
a water storing member connected to the water collecting member and for storing the collected water;
a carbon dioxide collecting member connected to the water collecting member and for collecting carbon dioxide from dry air supplied after the water collecting member collects water;
a water electrolysis member for electrolyzing water supplied from the water storing member to generate oxygen and hydrogen;
a methanation reaction member for generating a natural gas by methanation reaction of hydrogen supplied from a hydrogen storing member connected to the water electrolysis member and carbon dioxide supplied from a carbon dioxide storing member connected to the carbon dioxide collecting member;
a separation member having a means for separating the natural gas, carbon dioxide and water contained in a methanation reaction product supplied from the methanation reaction member, respectively;
a product storing member for storing the natural gas supplied from the separation member, from which water and carbon dioxide are removed; and
an oxygen storing member for storing oxygen gas supplied from the water electrolysis member,
wherein an electrical energy required for operating the apparatus is supplied by at least one of a solar cell, regenerated electricity, and idle electricity.

2. The apparatus for producing natural gas using carbon dioxide and water in air of claim 1 , further comprising:
a means for measuring a flow rate of the hydrogen gas supplied to the methanation reaction member, a means for measuring a flow rate of the carbon dioxide gas, and a flow rate adjusting means for determining/controlling the flow rate of the carbon dioxide as a function of the measured hydrogen flow rate.

3. The apparatus for producing natural gas using carbon dioxide and water in air of claim 1 , wherein the water collecting member includes at least one of a cooling means, an adsorption means and a membrane separation means for collecting water from the compressed air.

4. The apparatus for producing natural gas using carbon dioxide and water in air of claim 1 , wherein the carbon dioxide collecting member includes at least one of an adsorption means and a membrane separation means for collecting carbon dioxide from the dry air.

5. The apparatus for producing natural gas using carbon dioxide and water in air of claim 1 , wherein the water electrolysis member includes a proton exchange membrane (PEM) electrolysis means, a solid electrolyte water electrolysis means, or an alkaline electrolysis means.

6. The apparatus for producing natural gas using carbon dioxide and water in air of claim 1 , wherein the methanation reaction member includes a thermal reaction means or a plasma reaction means for the methanation reaction.

7. The apparatus for producing natural gas using carbon dioxide and water in air of claim 1 , wherein the separation member includes:
at least one of a distillating separation means, a cooling separation means, a freezing separation means, and a membrane separating means for separating the natural gas, carbon dioxide and water contained in the natural gas product, respectively;
a carbon dioxide re-feeding line for re-cycling the separated carbon dioxide to the carbon dioxide collecting member; and
a water supplying line for supplying the separated water to the water storing member.

8. The apparatus for producing natural gas using carbon dioxide and water in air of claim 7 , wherein the natural gas contained in the natural gas product is separated by cooling the natural gas in a temperature range of from −5° C. to 60° C.

9. A method for producing a natural gas using carbon dioxide and water in air using the apparatus of claim 1 , comprising:
compressing air using the air-compressing member;
collecting water from the compressed air supplied from the air-compressing member to the water collecting member, supplying the water to the water storing member, and supplying dry air from which water has been removed to the carbon dioxide collecting member;
collecting carbon dioxide from the dry air in the carbon dioxide collecting member and storing carbon dioxide in the carbon dioxide storing member;
supplying water from the water storing member to the water electrolysis member to generate oxygen and hydrogen by electrolysis and storing the generated oxygen and hydrogen in the oxygen storing member and the hydrogen storing member, respectively; and
supplying carbon dioxide and hydrogen from each of the carbon dioxide storing member and the hydrogen storing member to the methanation reaction member to generate the natural gas by the methanation reaction,
wherein an electric energy required for each of the above steps is supplied by the at least one of the solar cell, the regenerated electricity, and the idle electricity.

10. The method for producing natural gas using carbon dioxide and water in air of claim 9 , further comprising:
separating carbon dioxide and water contained in the natural gas product supplied from the methanation reaction member so as to separate the natural gas from which the carbon dioxide and water have been removed, and supplying the separated natural gas to the product storing member.

11. The method for producing natural gas using carbon dioxide and water in air of claim 10 , further comprising:
recycling the carbon dioxide separated from the natural gas product to the carbon dioxide collecting member or the carbon dioxide storing member.

12. A natural gas-synthesizing equipment system, comprising:
the apparatus for producing a natural gas of claim 1 and a container comprising the apparatus.

13. The natural gas-synthesizing equipment system of claim 12 , further comprising:
at least one of the containers, wherein each member of the apparatus for producing the natural gas is separately contained in each of the at least one container, and the members of the apparatus for producing the natural gas contained in the each container are connected for using the apparatus.

14. The natural gas synthesis equipment system of claim 12 , wherein each member of the apparatus for producing the natural gas is miniaturized and may be used for residential use.

Assignees

• Univ Sogang Res & Business Development Found

Inventors

• Yoon Kyung Byung

Classifications

• C25B9/23

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title

• F25J3/04018

  of main feed air · CPC title

• C10L2290/46

  Compressors or pumps · CPC title

• C10L2290/42

  Fischer-Tropsch steps · CPC title