Invert emulsion containing vegetable oil

Patent metadata

Field	Value
Publication number	US-10815417-B2
Application number	US-201616317372-A
Country	US
Kind code	B2
Filing date	Sep 6, 2016
Priority date	Sep 6, 2016
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

An invert emulsion composition which includes a base fluid having an oleaginous phase and a non-oleaginous phase, an emulsifier, and wherein the oleaginous phase includes a mixture of vegetable oil and an oil other than vegetable oil. The composition may also include particles such as proppants or gravel, which may be coated prior to introduction to the composition to assist in stabilization the emulsion. The invert emulsion composition can be employed in fracturing, gravel packing, and diversion operations, and the like.

First claim

The invention claimed is:

1. An invert emulsion composition comprising:
a base fluid having an oleaginous phase and a non-oleaginous phase, wherein the oleaginous phase comprises a mixture of a vegetable oil and an additional oil other than the vegetable oil;
an emulsifier; and
a proppant coated with at least a portion of the mixture of the vegetable oil and the additional oil creating an oil coated proppant, wherein the oil coated proppant is prepared prior to introduction to the base fluid and emulsifier.

2. The invert emulsion composition of claim 1 , wherein the vegetable oil or the additional oil of the oil coated proppant forming a portion of the oleaginous phase after introduction.

3. The invert emulsion composition of claim 1 , wherein the ratio of oleaginous phase to non-oleaginous phase ranges from about 1:19 to about 19:1 oleaginous phase to non-oleaginous phase.

4. The invert emulsion composition of claim 1 , wherein the oleaginous phase is present in the composition in a range of 30% or less by volume.

5. The invert emulsion composition of claim 1 , wherein the oleaginous phase is present in the composition in a range of from about 5% to less than 30% by volume.

6. The invert emulsion composition of claim 1 , wherein the oleaginous phase is present in the composition in a range of about 10% or less by volume.

7. The invert emulsion composition of claim 1 , wherein the vegetable oil is present in a range of at least 5% of the oleaginous phase.

8. The invert emulsion composition of claim 1 , wherein the additional oil is a mineral oil.

9. The invert emulsion composition of claim 1 , wherein the vegetable oil is selected from the group consisting of custard seed oil, almond oil, babassu oil, castor oil, clark A oil, coconut oil, corn oil, cotton seed oil, jojoba oil, linseed oil, mustard seed oil, olive oil, palm oil, peanut oil, safflower oil, sesame oil, soybean oil, sunflower-seed oil, wheat germ oil, and mixtures thereof.

10. The invert emulsion composition of claim 1 , wherein the vegetable oil is extracted from plant seed.

11. The invert emulsion composition of claim 1 , wherein the vegetable oil comprises glyceride.

12. The invert emulsion composition of claim 1 , wherein the proppant has an average particle size of about 2 mesh or larger.

13. The invert emulsion composition of claim 1 , further comprising suspension agents.

14. A method for creating an invert emulsion, the method comprising:
coating a proppant with a portion of a mixture including a vegetable oil and an additional oil other than a vegetable oil to create an oil coated proppant;
adding an emulsifier to a non-oleaginous phase;
combining the non-oleaginous phase and a oleaginous phase to form a base fluid, the oleaginous phase comprising the vegetable oil and the additional oil; and
adding the oil coated proppant to the base fluid to create the invert emulsion.

15. The method of claim 14 , wherein the additional oil is mineral oil.

16. The method of claim 14 , wherein the ratio of oleaginous phase to non-oleaginous phase ranges from about 1:19 to about 19:1 oleaginous phase to non-oleaginous phase.

17. The method of claim 14 , wherein the oleaginous phase is present in the composition in a range of about 10% or less by volume.

18. The method of claim 14 , wherein the vegetable oil is selected from the group consisting of custard seed oil, almond oil, babassu oil, castor oil, clark A oil, coconut oil, corn oil, cotton seed oil, jojoba oil, linseed oil, mustard seed oil, olive oil, palm oil, peanut oil, safflower oil, sesame oil, soybean oil, sunflower-seed oil and wheat germ oil.

19. The method of claim 14 , wherein the vegetable oil is present in a range of at least 30% of the oleaginous phase.

20. The method of claim 14 , wherein the proppant has an average particle size of about 2 mesh or larger.

21. The method of claim 14 , further comprising mixing the invert emulsion composition using mixing equipment.

22. The method of claim 14 , wherein the invert emulsion composition is introduced into a wellbore drilled in a subterranean formation using one or more pumps.

Assignees

• Halliburton Energy Services Inc

Inventors

• Eluru Sairam
• Prakash Chetan
• Nehete Umesh Namdeo

Classifications

• E21B43/267

  reinforcing fractures by propping · CPC title

• C09K8/36

  Water-in-oil emulsions · CPC title

• C09K8/34 Primary

  Organic liquids · CPC title

• C09K8/64 Primary

  Oil-based compositions · CPC title

• C09K8/80

  Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open · CPC title