Sealing gels, process for production thereof and use thereof in sealing compounds for self-sealing tyres

Patent metadata

Field	Value
Publication number	US-10815364-B2
Application number	US-201615745886-A
Country	US
Kind code	B2
Filing date	Jul 26, 2016
Priority date	Jul 27, 2015
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

The present invention relates to:
a sealing gel having a Mooney viscosity (ML1+4 @ 100° C.) in the range from 100 MU to 170 MU, a sealing compound comprising inventive sealing gel, a process for producing this sealing compound, the use of sealing gels for improving viscoelastic properties in sealing compounds, and the use of sealing gel-containing sealing compounds for improving rolling resistance properties in tyres having sealing layers.

First claim

What is claimed is:

1. A sealing gel having a Mooney viscosity ML1+4 at 100° C. of 100 MU to 170 MU as determined by ASTM D1646 published in 1999, wherein the gel comprises a mixture comprising:
a first diene rubber gel (A) having a Mooney viscosity ML1+4 at 100° C. of 170 MU to 195 MU as determined by ASTM D1646 published in 1999 obtained by emulsion polymerization of at least one conjugated diene in the presence of at least one first crosslinker (I); and
a) a second diene rubber gel (B) having a Mooney viscosity ML1+4 at 100° C. of 75 MU to 110 MU as determined by ASTM D1646 published in 1999 obtained by emulsion polymerization of at least one conjugated diene in the presence of at least one second crosslinker (II); or
b) a third diene rubber gel (H) obtained by emulsion polymerization of at least one conjugated diene in the presence of at least one second crosslinker (I) and in the presence of at least one second crosslinker (II),

where:
the at least one first crosslinker (I) comprises an acrylate of a polyhydric C 2 -C 20 alcohol, a methacrylate of a polyhydric C 2 -C 20 alcohol, or a mixture thereof; and
the at least one second crosslinker (II) comprises a compounds having two or more vinyl groups, two or more allyl groups, two or more isopropenyl groups, one maleimide unit, or a mixtures thereof; and
the at least one conjugated diene is at least one of 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, isoprene, or chloroprene.

2. The sealing gel according to claim 1 , wherein the emulsion polymerization of the at least one conjugated diene comprises polymerization with further monomers selected from the group consisting of vinylaromatics, acrylonitrile, esters of acrylic acid and methacrylic acid, tetrafluoroethylene, vinylidene fluoride, hexafluoropropene, 2-chlorobutadiene, 2,3-dichlorobutadiene, carboxylic acids containing double bonds, hydroxyl compounds containing double bonds, amine-functionalized (meth)acrylates, glycidyl methacrylate, acrolein, N-vinyl-2-pyrrolidone, N-allylurea, N-allyithiourea, secondary amino (meth)acrylates, and vinylic heteroaromatics.

3. The sealing gel according to claim 2 , wherein:
the at least one conjugated diene is 1,3-butadiene,
the further monomer is styrene;
the at least one first crosslinker (I) is trimethylolpropane trimethacrylate;
the at least one second crosslinker (II) is divinylbenzene; and
the emulsion polymerization is performed at 5° C. to 20° C.

4. The sealing gel according to claim 1 , wherein the at least one conjugated diene is 1,3-butadiene, and the first diene rubber gel (A) and the second diene rubber gel (B) and the third diene rubber gel (H) have a proportion of cis-1,4-butadiene units of 8% by weight to 17% by weight, a proportion of trans-1,4-butadiene units of 59% by weight to 75% by weight, and a proportion of 1,2-vinylbutadiene units of 17% by weight to 21% by weight, wherein each proportion is based on the 1,3-butadiene incorporated.

5. The sealing gel according to claim 1 , wherein the amount of the at least one first crosslinker (I) is 1 phm to 6 phm, based on the total amount of diene monomer, further monomer and crosslinker.

6. The sealing gel according to claim 1 , wherein the amount of the at least one second crosslinker (II) is 0.2 phm to 4 phm, based on the total amount of diene monomer, further monomer and crosslinker.

7. The sealing gel according to claim 2 , wherein:
the amount of further monomers in the diene rubber gel is 1 phm to 20 phm, based on the total amount of monomers and crosslinkers, and
the amount of diene monomer in the diene rubber gel is typically 79.8 phm to 98.8 phm, based on the total amount of diene monomer, further monomer and crosslinker.

8. The sealing gel according to claim 1 , wherein:
the sealing gel comprises a mixture comprising the first diene rubber gel (A) and the second diene rubber gel (B); and
the ratio of the first diene rubber gel (A) to the second diene rubber gel (B) is from 1:9 to 9:1.

9. The sealing gel according to claim 1 , wherein the sealing gel comprises a mixture of the first diene rubber gel (A), the second diene rubber gel (B), and the third diene rubber gel (H).

10. A sealing compound comprising:
at least one sealing gel according to claim 1 in an amount of 45 phr to 100 phr, and
resin (C) in an amount of 10 phr to 60 phr, and
optionally a natural rubber or synthetic rubber (E) in an amount of 0 phr to 55 phr, wherein the phr values are based in each case on the total amount of sealing gel and optionally natural rubber or synthetic rubber (E) in the sealing compound.

11. The sealing compound according to claim 10 , further comprising an ageing stabilizer (D) in an amount of 1 phr to 10 phr.

12. The sealing compound according to claim 10 , further comprising a plasticizer (F) in an amount of 10 phr to 50 phr.

13. The sealing compound according to claim 10 , further comprising at least one filler (G) in an amount of 1 phr to 50 phr.

14. A process for producing sealing compounds according to claim 10 , the process comprising mixing in solid or liquid form the rubber gel, the resin (C), and the optional natural or synthetic rubber (E).

15. A process for producing sealing compounds according to claim 10 , the process comprising mixing the rubber components in the form of their latexes and co-processing and mixing further components.

16. A method for improving an adhesion property and a cohesion property of a sealing compound, the method comprising incorporating the sealing gel according to claim 1 into the sealing compounds to improve an adhesion property and a cohesion property.

17. A method of sealing punctures in a tire, the method comprising incorporating a sealing layer comprising sealing compounds according to claim 10 in a tire.

18. A pneumatic motor vehicle tire having a sealing compound comprising a sealing gel according to claim 1 .

19. The sealing gel according to claim 1 , wherein the sealing gel comprises a mixture comprising the first diene rubber gel (A) and the second diene rubber gel (B) and wherein:
the emulsion polymerization of the at least one conjugated diene in the presence of the at least one first crosslinker (I), the emulsion polymerization of the at least one conjugated diene in the presence of the at least one second crosslinker (II), and the emulsion polymerization of the at least one conjugated diene in the presence of both the at least one first crosslinker (I) and the at least one second crosslinker (II), are each done at a temperature of 5° C. to 20° C.;
the at least one conjugated diene is at least one of 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, isoprene, or chloroprene;
the at least one first crosslinker (I) is selected from acrylates and methacrylates of ethylene glycol, propane-1,2-diol, butane-1,4-diol, hexanediol, polyethylene glycol having 2 to 4 oxyethylene units, neopentyl glycol, bisphenol A, glycerol, trimethylolpropane, pentaerythritol, sorbitol with unsaturated polyesters of aliphatic di- and polyols and mixtures thereof;
the at least one second crosslinker (II) is selected from the group consisting of diisopropenylbenzene, divinylbenzene (DVB), divinyl ether, divinyl sulphone, diallyl phthalate, trivinylbenzene, triallyl cyanurate, triallylisocyanurate, 1,2-polybutadiene, N,N′-m-phenylenemaleimide, tolylene-2,4-bis(maleimide), triallyl trimellitate, and mixtures thereof;
the emulsion polymerization of the at least one conjugated diene further comprises polymerization with further monomers selected from the group consisting of styrene,

Assignees

• Arlanxeo Deutschland Gmbh

Inventors

• Kohl Christopher
• Schmidt Udo
• Zhou Jiawen
• Frueh Thomas
• Lucassen Alex

Classifications

• C08F236/06

  Butadiene · CPC title

• C08F236/04

  conjugated · CPC title

• C08F212/36

  Divinylbenzene · CPC title

• B60C5/00

  Inflatable pneumatic tyres or inner tubes (B60C1/00, B60C9/00 - B60C17/00 take precedence) · CPC title

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title