Thermolatently catalysed two-component system

Patent metadata

Field	Value
Publication number	US-10815330-B2
Application number	US-201716093819-A
Country	US
Kind code	B2
Filing date	Apr 18, 2017
Priority date	Apr 22, 2016
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

The invention relates to a two-component system containing a component A) comprising at least one NCO-reactive connection, and a component B) comprising at least one polyisocyanate, characterised in that the component A) contains ≥400 to ≤9500 wt. ppm water, in relation to the total weight of the component A), and the component A) and/or the component B) contains at least one thermolatent, inorganic, tin-containing catalyst. The invention also relates to a method for producing a coating on a substrate, coatings that can be obtained with the method, the use of the component A) or B) in the two-component system, and substrates coated with the coating, in particular coated vehicle bodies or vehicle parts.

First claim

The invention claimed is:

1. A two-component coatings system containing a component A) comprising at least one NCO-reactive compound and a component B) comprising at least one polyisocyanate, characterized in that the component A) contains ≥400 to ≤9500 ppmw of water based on the total weight of the component A) and the component A) and/or the component B) contains at least one thermolatent inorganic tin-containing catalyst.

2. The two-component coatings system as claimed in claim 1 , characterized in that the component A) contains ≥501 to ≤6500 ppmw of water based on the total weight of the component A).

3. The two-component coatings system as claimed in claim 1 , characterized in that the NCO-reactive compound is a polyhydroxyl compound.

4. The two-component coatings system as claimed in claim 1 , characterized in that the polyisocyanate is an aliphatic or cycloaliphatic polyisocyanate.

5. The two-component coatings system as claimed in claim 1 , characterized in that the polyisocyanate is a derivative of hexamethylene diisocyanate or of pentamethylene diisocyanate.

6. The two-component coatings system as claimed in claim 1 , characterized in that the thermolatent inorganic tin-containing catalyst comprises cyclic tin compounds of formula I, II or III or mixtures thereof:

where:
D represents —O—, —S— or —N(R1)—
wherein R1 represents a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic radical or an optionally substituted aromatic or araliphatic radical which has up to 20 carbon atoms and may optionally contain heteroatoms from the group of oxygen, sulfur, nitrogen, or is hydrogen or the radical

or R1 and L3 together represent —Z—L5—;

D* represents —O— or —S—;
X, Y and Z represent identical or different radicals selected from alkylene radicals having the formulae —C(R2)(R3)—, —C(R2)(R3)—C(R4)(R5)— or —C(R2)(R3)—C(R4)(R5)—C(R6)(R7)— or ortho-arylene radicals having the formulae

wherein R2 to R11 independently represent saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or optionally substituted aromatic or araliphatic radicals which have up to 20 carbon atoms and may optionally contain heteroatoms from selected from the group consisting of oxygen, sulfur, nitrogen, or are hydrogen;

L1, L2 and L5 independently represent —O—, —S—, —OC(═O)—, —OC(═S) —SC(═O)—, —SC(═S)—, —OS(═O) 2 O—, —OS(═O) 2 — or —N(R12)—,
wherein R12 represents a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic radical or an optionally substituted aromatic or araliphatic radical which has up to 20 carbon atoms and may optionally contain heteroatoms selected from the group consisting of oxygen, sulfur, nitrogen, or is hydrogen;

L3 and L4 independently represent —OH, —SH, —OR13, —Hal, —OC(═O)R14, —SR15, —OC(═S)R16, —OS(═O) 2 OR17, —OS(═O) 2 R18 or —NR19R20, or L3 and L4 together represent —L1—X—D—Y—L2—,
wherein R13 to R20 independently represent saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or optionally substituted aromatic or araliphatic radicals which have up to 20 carbon atoms and may optionally contain heteroatoms selected from the group consisting of oxygen, sulfur, nitrogen, or are hydrogen.

7. A process for producing a coating on a substrate, comprising the steps of:
a1) providing a substrate;
b1) applying at least one two-component coatings system according to claim 1 ; and
c1) curing the coating by heating.

8. A process for producing a coating on a substrate, comprising the steps of:
a2) providing a substrate;
b2) applying at least one two-component coatings system containing a component A) comprising at least one NCO-reactive compound and a component B) comprising at least one polyisocyanate, wherein component A) and/or component B) contain at least one thermolatent inorganic tin-containing catalyst;
c2) curing the coating by heating,
characterized in that the two-component coatings system during application in step b2) absorbs from the application atmosphere ≥400 to ≤9500 ppmw of water based on the total weight of the component A).

9. The process as claimed in claim 8 , characterized in that the two-component coatings system during application in step b2) absorbs ≥501 to ≤6500 ppmw of water based on the total weight of the component A).

10. The process as claimed in claim 7 , characterized in that the substrate has a surface made completely or partially of plastic and/or metal.

11. A component A) for use in a two-component coatings system as claimed in claim 1 .

12. A component B) for use in a two-component coatings system as claimed in claim 1 .

13. A coating produced or producible by the process according to claim 7 .

14. A substrate coated with a coating as claimed in claim 13 , wherein the substrate may be a chassis or parts thereof.

15. The substrate as claimed in claim 14 , characterized in that the chassis or parts thereof comprise(s) one or more of the materials selected from metal, plastic or mixtures thereof.

16. The two-component coatings system as claimed in claim 1 , characterized in that the component A) contains ≥700 to ≤5000 ppmw of water based on the total weight of the component A).

17. The two-component coatings system as claimed in claim 1 , characterized in that the component A) contains ≥1001 to ≤4000 ppmw of water based on the total weight of the component A).

18. The two-component coatings system as claimed in claim 1 , characterized in that the component A) contains ≥1400 to ≤2400 ppmw of water based on the total weight of the component A).

19. The two-component coatings system as claimed in claim 1 , characterized in that the polyisocyanate is a hexamethylene diisocyanate trimer or a pentamethylene diisocyanate trimer.

Assignees

• Covestro Deutschland Ag

Inventors

• Grahl Michael
• Klippert Uwe
• Richter Frank
• Siegemund Sven
• Weikard Jan

Classifications

• C08G18/6225

  Polymers of esters of acrylic or methacrylic acid · CPC title

• C08G18/246 Primary

  containing also tin-carbon bonds · CPC title

• B05D7/14

  to metal, e.g. car bodies (involving a chemical reaction between the metal and the coating C23) · CPC title

• C09D175/04 Primary

  Polyurethanes · CPC title

• C08G18/792

  formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates · CPC title