Hydrophobic finish compositions with extended flow time retention and building products made thereof

Patent metadata

Field	Value
Publication number	US-10815149-B2
Application number	US-201816168107-A
Country	US
Kind code	B2
Filing date	Oct 23, 2018
Priority date	Mar 13, 2015
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

Disclosed are hydrophobic finish compositions and cementitious articles made with the hydrophobic finish compositions. In some embodiments, the article is a waterproof gypsum panel surface reinforced with inorganic mineral fibers that face a flexible and hydrophobic cementitious finish possessing beneficial waterproofing properties. The waterproof gypsum panels of the invention have many uses, such as, tilebacker board in wet or dry areas of buildings, exterior weather barrier panel for use as exterior sheathing, and roof cover board having water durability and low surface absorption. The flexible and hydrophobic cementitious finish can include fly ash, film-forming polymer, silane compound (e.g., alkyl alkoxysilane), an extended flow time retention agent including either one or more carboxylic acids, salts of carboxylic acids, or mixtures thereof, and other optional additives.

First claim

The invention claimed is:

1. A hydrophobic finish composition comprising:
(i) hydraulic component comprising fly ash;
(ii) film-forming polymer;
(iii) at least one silane compound selected from the group consisting of:
(a) silane compounds having a molecular weight of at least about 150,
(b) silane compounds having a general chemical formula (I):
(R 1 O) m Si—X 4-m   (I)

wherein R 1 O is an alkoxy group, X is an organofunctional group, and m ranges from 1 to 3, and
(c) mixtures of silane compounds (a) and (b); and

(iv) an extended flow time retention agent comprising at least one member selected from the group consisting of carboxylic acids, salts of carboxylic acids, and mixtures thereof;
wherein said carboxylic acids have the chemical formula (II):

wherein R is an organofunctional group;
wherein the salts of carboxylic acid have the chemical formula (III)

wherein R is as defined in formula (II) and X + is a cation,
wherein there is an absence of calcium sulfate.

2. The hydrophobic finish composition of claim 1 , wherein the carboxylic acids or salts of carboxylic acids are not a polycarboxylate superplasticizer.

3. The hydrophobic finish composition of claim 1 , having an absence of polycarboxylate ether.

4. The hydrophobic finish composition of claim 1 , wherein the extended flow time retention agent comprises citric acid or a citric acid salt.

5. The hydrophobic finish composition of claim 1 , wherein the extended flow time retention agent is at least one member selected from the group consisting of tricarboxylic acids, dicarboxylic acids, sugar acids, aldonic acids, aldaric acids, uronic acids, aromatic carboxylic acids, amino carboxylic acids, alpha hydroxy acids, beta hydroxy acids, sodium salts of said acids, and potassium salts of said acids.

6. The hydrophobic finish composition of claim 1 , wherein the film-forming polymer comprises at least one member selected from the group consisting of acrylic polymers and copolymers, rubber-based polymers and copolymers, styrene-butadiene rubber, copolymers of styrene and acrylic, copolymers of vinyl acetate and ethylene, copolymers of vinyl chloride and ethylene, copolymers of vinyl acetate and vinyl ester of versatic acid, copolymers of vinyl laurate and ethylene, terpolymers of vinyl acetate, ethylene and methylmethacrylate, terpolymers of vinyl acetate, ethylene and vinyl laurate, terpolymers of vinyl acetate, ethylene and vinyl ester of versatic acid, and any combination thereof.

7. The hydrophobic finish composition of claim 1 , wherein the silane compound is in an amount from about 0.1% to about 5% by weight of the wet finish and the extended flow time retention agent is in an amount from about 0.05% to 1.00% by weight of the hydraulic component, wherein the silane compound has a molecular weight of at least about 150, or wherein the silane compound has the general chemical formula (I):
(R 1 O) m —Si—X 4-m   (I),

wherein R 1 O is the alkoxy group, X is the organofunctional group, and m ranges from 1 to 3.

8. The hydrophobic finish composition of claim 1 , wherein the carboxylic acids or salts of carboxylic acids are selected from the group consisting of dicarboxylic acids, tricarboxylic acids, salts of dicarboxylic acids, and salts of tricarboxylic acids.

9. The hydrophobic finish composition of claim 1 , wherein
the hydraulic component is about 55% to about 75% by weight of the hydrophobic finish composition based on the weight of the finish composition including water;
the film-forming polymer is about 7.5% to about 22.5% by weight of the hydrophobic finish composition based on the weight of the hydrophobic finish composition including water;
the silane compound is 0.1% to 3% by weight of the hydrophobic finish composition based on the weight of the hydrophobic finish composition including water; and
the extended flow time retention agent is 0.075% to 0.75% by weight of the hydraulic component on a dry basis.

10. The hydrophobic finish composition of claim 1 , wherein the carboxylic acids and/or salts of carboxylic acids used as extended flow time retention agents are other than copolymerizable unsaturated carboxylic acids and/or salts of copolymerizable unsaturated carboxylic acids of structural formula (V):

wherein R 6 , R 7 , and R 8 are H or substituted or unsubstituted functional groups, and R 9 is a functional group containing a carboxyl group (C(O)OH), or polymerized versions thereof.

11. The hydrophobic finish composition of claim 1 comprising:
(i) the hydraulic component comprising fly ash in an amount from about 50% to about 85% by weight of the hydrophobic finish composition on a water inclusive basis;
(ii) the film-forming polymer;
(iii) 5% by weight or less, based on the weight of the finish composition on a wet basis, the at least one silane compound selected from the group consisting of:
(a) silane compounds having a molecular weight of at least about 150,
(b) silane compounds having a general chemical formula (I):
(R 1 O) m —Si—X 4-m   (I)

wherein R 1 O is an alkoxy group, X is an organofunctional group, and m ranges from 1 to 3, and
(c) mixtures of silane compounds (a) and (b); and

(iv) the extended flow time retention agent comprising at least one member selected from the group consisting of carboxylic acids, salts of carboxylic acids, and mixtures thereof;
wherein said carboxylic acids have the chemical formula (II):

wherein R is an organofunctional group;
wherein the salts of carboxylic acid have the chemical formula (III)

wherein R is as defined in formula (II) and X + is a cation,
wherein there is the absence of calcium sulfate.

12. The hydrophobic finish composition of claim 11 , wherein the extended flow time retention agent is at least one member selected from the group consisting of tricarboxylic acids, dicarboxylic acids, sugar acids, aldonic acids, aldaric acids, uronic acids, aromatic carboxylic acids, amino carboxylic acids, alpha hydroxy acids, beta hydroxy acids, sodium salts of said acids, and potassium salts of said acids.

13. The hydrophobic finish composition of claim 11 , wherein the film-forming polymer comprises at least one member selected from the group consisting of acrylic polymers and copolymers, rubber-based polymers and copolymers, styrene-butadiene rubber, copolymers of styrene and acrylic, copolymers of vinyl acetate and ethylene, copolymers of vinyl chloride and ethylene, copolymers of vinyl acetate and vinyl ester of versatic acid, copolymers of vinyl laurate and ethylene, terpolymers of vinyl acetate, ethylene and methylmethacrylate, terpolymers of vinyl acetate, ethylene and vinyl laurate, terpolymers of vinyl acetate, ethylene and vinyl ester of versatic acid, and any combination thereof.

14. The hydrophobic finish composition of claim 11 , wherein the carboxylic acids or salts of carboxylic acids are selected from the group consisting of dicarboxylic acids, tricarboxylic acids, salts of dicarboxylic acids, and salts of tricarboxylic acids.

15. The hydrophobic

Assignees

• United States Gypsum Co

Inventors

• Dubey Ashish
• Peng Yanfei

Classifications

• C09D5/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C04B41/483

  Polyacrylates · CPC title

• B32B5/26

  another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} · CPC title

• C04B41/009

  characterised by the material treated · CPC title