Process and system for recycling alkaline and carbon zinc batteries

Patent metadata

Field	Value
Publication number	US-10811695-B2
Application number	US-201615563007-A
Country	US
Kind code	B2
Filing date	Apr 8, 2016
Priority date	Apr 8, 2015
Publication date	Oct 20, 2020
Grant date	Oct 20, 2020

Abstract

The present technology relates to processes for recycling alkaline and/or carbon zinc batteries. In particular, the present technology relates to a process for recycling alkaline and/or carbon zinc batteries that provides a consistent and measurable amount of material (e.g., discarded batteries) to be recycled and may enhance the recovery of certain materials during the recycling process.

First claim

What is claimed is:

1. A method for recovering metals from a feedstock comprising discharged batteries, the method comprising:
pre-sorting the feedstock to select batteries having defined characteristics and collecting information about the defined characteristics;
conveying the selected batteries to a comminution process at a first rate;
comminuting the selected batteries using a comminutor operating at a second rate to produce dust and particulates and processing at least one of the dust and particulates to produce a refined feedstock by removing unwanted materials;
causing a temperature-controlled fluid source to provide fluid of a selected temperature to create a slurry comprising the refined feedstock, the fluid of the selected temperature provided to at least one of (a) the comminutor or (b) a storage tank located downstream of the comminutor and upstream of a digester, wherein the temperature-controlled fluid source comprises a cooling feedback loop in fluid communication with (i) the at least one of (a) the comminutor or (b) the storage tank and (ii) the digester;
conveying the slurry comprising the refined feedstock to a digestion process within the digester at a third rate;
digesting selected metals from the refined feedstock in a selected amount of digestion reagent to create a soluble recoverable material and an insoluble recoverable material while at least periodically monitoring pH of the digestion process via one or more pH sensors located at one or more points within the digester within which the selected metals are being digested in the selected amount of digestion reagent, wherein the selected amount of digestion reagent is selected based upon a measurement by the one or more pH sensors;
causing the temperature-controlled fluid source to provide fluid of the selected temperature to at least one of (a) the digester or (b) a precipitate stream produced by the digester;
separating the soluble recoverable material from the insoluble recoverable material;
rinsing the insoluble recoverable material with a selected amount of rinsing reagent, wherein the selected amount of rinsing reagent is selected based at least in part on the information about the defined characteristics;
collecting additional information about at least one of: the first rate, the second rate, the third rate, and the pH of the digestion process via the one or more pH sensors; and
processing at least a portion of the information and the additional information to maximize recovery of insoluble recoverable material by making ongoing adjustments to at least one of: the first rate, the second rate, the third rate, the pH of the digestion process, the selected amount of digestion reagent, and the selected amount of rinsing reagent.

2. The method according to claim 1 , wherein pre-sorting includes a time-of-flight method to determine at least one of the defined characteristics.

3. The method according to claim 1 , wherein the defined characteristics are selected from: battery size, battery chemistry, and battery weight.

4. The method according to claim 1 , further comprising drying the insoluble recoverable material at a temperature sufficient to drive off impurities.

5. The method according to claim 1 , wherein separating the soluble and insoluble recoverable materials comprises filtering.

6. The method according to claim 1 , wherein the rinsing reagent is heated.

7. The method according to claim 1 , wherein the processing includes at least one of: a demagnetization process and a screening process.

8. The method according to claim 1 , further comprising collecting the dust prior to digestion via a process that does not involve wetting the dust.

9. The method according to claim 1 , wherein unwanted materials are removed from the refined feedstock by creating the slurry to dissolve at least a portion of the unwanted materials.

10. The method according to claim 1 , wherein at least one of the digester or the comminutor is cooled via the cooling feedback loop associated with the temperature-controlled fluid source.

11. The method according to claim 10 wherein the fluid comprises water.

12. The method according to claim 10 , wherein the fluid comprises alkali hydroxide.

13. The method according to claim 1 , further comprising, based on the processing of the at least a portion of the information and the additional information, making ongoing adjustments to at least one of the selected temperature of the or a pH of the fluid.

14. The method according to claim 13 , wherein the additional information comprises at least one of a measurement of a temperature of the fluid or the pH of the fluid.

15. The method according to claim 1 , further comprising heating the rinsed insoluble recoverable material to at least 500° C. to remove water and drive off any mercury present in the rinsed insoluble recoverable material.

16. The method according to claim 1 , wherein the slurry is not produced within the comminutor.

Assignees

• Energizer Brands Llc

Inventors

• Muska David
• Goedde Donald
• Resnick Richard

Classifications

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title

• H01M6/52 Primary

  Reclaiming serviceable parts of waste cells or batteries {, e.g. recycling} · CPC title

• C22B47/00

  Obtaining manganese · CPC title

• H01M10/54

  Reclaiming serviceable parts of waste accumulators · CPC title