Slurry for positive electrode of lithium-ion secondary battery, positive electrode for lithium-ion secondary battery obtained using slurry for positive electrode of lithium-ion secondary battery and production method therefor, and lithium-ion secondary battery provided with positive electrode for lithium-ion secondary battery and production method therefor

Patent metadata

Field	Value
Publication number	US-10811686-B2
Application number	US-201615750860-A
Country	US
Kind code	B2
Filing date	Aug 3, 2016
Priority date	Aug 11, 2015
Publication date	Oct 20, 2020
Grant date	Oct 20, 2020

Abstract

A slurry for a positive electrode of a lithium-ion secondary battery. Also disclosed is a positive electrode for a lithium-ion secondary battery obtained using the slurry for a positive electrode of a lithium-ion secondary battery, and a production method for the electrode; and a lithium-ion secondary battery provided with the positive electrode for a lithium-ion secondary battery, and a production method for the battery. The slurry for a positive electrode of a lithium-ion secondary battery includes a positive electrode active material (A), a conductive auxiliary agent (B), a resin binder (C), a thickening dispersant (D), and water (E), wherein the thickening dispersant (D) includes a polyalkylene oxide having a phenyl group in a side chain thereof.

First claim

The invention claimed is:

1. A slurry for a positive electrode of a lithium-ion secondary battery, comprising a positive electrode active material (A), a conductive auxiliary agent (B), a resin binder (C), a thickening dispersant (D), and water (E),
wherein the resin binder (C) is a copolymer of monomers which comprise
an aromatic vinyl compound and
at least one of an ethylenically unsaturated carboxylic acid ester and an ethylenically unsaturated carboxylic acid,
wherein the thickening dispersant (D) comprises a polyalkylene oxide having a phenyl group in the side chain, and
the polyalkylene oxide having a phenyl group in the side chain is a compound represented by the following formula (1),

wherein, n, m and l represent molar ratios of monomers, n, m and l represent integers and n+m+1=100, n+m≤98, l≥2.

2. The slurry for a positive electrode of a lithium-ion secondary battery according to claim 1 , wherein a content of the resin binder (C) with respect to 100 parts by mass of the positive electrode active material (A) is 0.2 parts by mass or more and 5.0 parts by mass or less.

3. The slurry for a positive electrode of a lithium-ion secondary battery according to claim 1 ,
wherein a content of the thickening dispersant (D) with respect to 100 parts by mass of the positive electrode active material (A) is 0.2 to 5.0 parts by mass.

4. A positive electrode for a lithium-ion secondary battery, which comprises a positive electrode current collector and a positive electrode active material layer formed on the positive electrode current collector, wherein the positive electrode active material layer comprises a positive electrode active material,
wherein the positive electrode active material layer is formed from the slurry for a positive electrode of a lithium-ion secondary battery according to claim 1 .

5. A lithium-ion secondary battery comprising the positive electrode for a lithium-ion secondary battery according to claim 4 .

6. A method of producing a positive electrode for a lithium-ion secondary battery, wherein the positive electrode comprises a positive electrode current collector and a positive electrode active material layer formed on the positive electrode current collector, wherein the positive electrode active material layer comprises a positive electrode active material,
wherein the method comprises a step of
applying the slurry for a positive electrode of a lithium-ion secondary battery according to claim 1 to the positive electrode current collector to form the positive electrode active material layer.

7. A method of producing a positive electrode for a lithium-ion secondary battery, comprising steps of
preparing a slurry for a positive electrode of a lithium-ion secondary battery according to claim 1 ;
preparing a positive electrode for a lithium-ion secondary battery by applying the slurry for a positive electrode of a lithium-ion secondary battery on a positive electrode current collector to form a positive electrode active material layer; and
assembling a lithium-ion secondary battery comprising the positive electrode for a lithium-ion secondary battery.

Assignees

• Showa Denko Kk

Inventors

• Aoki Yusuke
• Hanasaki Mitsuru

Classifications

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• C09D171/02

  Polyalkylene oxides · CPC title

• C09D101/10

  Esters of organic acids (of both organic acids and inorganic acids C09D101/20) · CPC title