Process for managing sulfur on catalyst in a light paraffin dehydrogenation process

Patent metadata

Field	Value
Publication number	US-10807075-B2
Application number	US-201715848000-A
Country	US
Kind code	B2
Filing date	Dec 20, 2017
Priority date	Dec 20, 2016
Publication date	Oct 20, 2020
Grant date	Oct 20, 2020

Abstract

A process is presented for the management of sulfur on a catalyst. The catalyst is a dehydrogenation catalyst, and sulfur accumulates during the dehydrogenation process. Sulfur compounds are stripped from the spent catalyst and the catalyst is cooled before the regeneration process. The process includes controlling the amount of sulfur that needs to be removed from the catalyst before regeneration.

First claim

The invention claimed is:

1. A process for regenerating a spent catalyst from a reactor comprising:
a. passing a first feed stream to a first reactor to produce a first effluent stream;
b. passing the first effluent stream to a second reactor to produce a second effluent stream;
c. passing the second effluent stream to a third reactor to produce a third effluent stream;
d. passing the third effluent stream to a fourth reactor to product a product stream, wherein the spent catalyst is collected from the fourth reactor;
e. passing the spent catalyst from the fourth reactor having sulfur on the catalyst, to a sulfur stripping vessel;
f. injecting a water stream into the first, second, third, and fourth reactors;
g. injecting water into a hydrogen gas stream to generate a hydrogen water gas stream consisting essentially of hydrogen and water and passing the hydrogen water gas stream to the sulfur stripping vessel at an elevated temperature, thereby generating a stripped spent catalyst stream;
h. passing the stripped spent catalyst stream to a regenerator wherein the stripped spent catalyst stream is contacted with chlorine-containing gas, thereby generating a regenerated catalyst stream; and
i. returning the regenerated catalyst stream to at least one reactor via a reduction zone.

2. The process of claim 1 wherein the water stream is injected into an inlet of each of the four reactors.

3. The process of claim 2 wherein the water stream comprises steam.

4. The process of claim 2 wherein the water stream comprises condensate.

5. The process of claim 2 wherein the water stream comprises demineralized steam or water.

6. The process of claim 1 further comprising passing the stripped spent catalyst stream to a catalyst cooler prior to passing the catalyst to the regenerator.

7. The process of claim 1 wherein at least 50% of the sulfur on the spent catalyst is removed in the sulfur stripping vessel.

8. The process of claim 1 wherein the sulfur stripping vessel temperature is at least 150° C.

9. The process of claim 1 wherein the sulfur stripping vessel temperature is at least 250° C.

10. The process of claim 1 wherein the reduction zone removes halogen compounds from the spent catalyst.

11. The process of claim 10 wherein the halogen removed is chloride.

12. A process for regenerating a spent catalyst from a reactor comprising:
a. passing a first feed stream and a first water stream to a first reactor to produce a first effluent stream;
b. passing the first effluent stream and a second water stream to a second reactor to produce a second effluent stream;
c. passing the second effluent stream and a third water stream to a third reactor to produce a third effluent stream;
d. passing the third effluent stream and a fourth water stream to a fourth reactor to product a product stream, wherein the spent catalyst is collected from the fourth reactor;
e. passing the spent catalyst from the fourth reactor having sulfur on the catalyst, to a sulfur stripping vessel;
f. injecting another water stream into a hydrogen gas stream to generate a hydrogen water gas stream consisting essentially of water and hydrogen;
g. passing the hydrogen water gas stream to the sulfur stripping vessel at an elevated temperature, thereby generating a stripped spent catalyst stream;
h. passing the stripped spent catalyst stream to a regenerator wherein the stripped spent catalyst stream is contacted with chlorine-containing gas, thereby generating a regenerated catalyst stream; and
i. returning the regenerated catalyst stream to at least one reactor via a reduction zone.

13. The process of claim 12 wherein any of the first, second, third, fourth, or another water streams comprise steam.

14. The process of claim 12 wherein any of the first, second, third, fourth, or another water streams comprise condensate.

15. The process of claim 12 wherein any of the first, second, third, fourth, or another water streams comprise demineralized steam or water.

16. The process of claim 12 further comprising:
passing the stripped spent catalyst to a cooling zone before passing to the regenerator.

17. A process for regenerating a spent catalyst from a reactor comprising:
a. passing a first feed stream to a first reactor to produce a first effluent stream;
b. passing the first effluent stream to a second reactor to produce a second effluent stream;
c. passing the second effluent stream to a third reactor to produce a third effluent stream; injecting a water stream consisting essentially of water to the first, second, and third reactors, wherein the spent catalyst is collected from the third reactor;
d. passing the spent catalyst from the third reactor having sulfur on the catalyst, to a sulfur stripping vessel;
e. passing a hydrogen gas stream consisting essentially of hydrogen and water to the sulfur stripping vessel at an elevated temperature, thereby generating a stripped spent catalyst stream;
f. passing the stripped spent catalyst stream to a regenerator wherein the stripped spent catalyst stream is contacted with chlorine-containing gas, thereby generating a regenerated catalyst stream; and
g. returning the regenerated catalyst stream to at least one reactor via a reduction zone.

18. The process of claim 17 wherein the water stream comprises steam.

19. The process of claim 17 wherein the water stream comprises condensate.

20. The process of claim 17 wherein the water stream comprises demineralized steam or water.

Assignees

• Uop Llc

Inventors

• Spieker Wolfgang A
• Ballard Adam D
• Gajda Gregory J
• Sachtler J W Adriaan

Classifications

• Y02P20/584

  Recycling of catalysts · CPC title

• B01J23/96 Primary

  of catalysts comprising metals, oxides or hydroxides of the noble metals · CPC title

• C10G2300/701

  Use of spent catalysts · CPC title

• C10G2300/4093

  Catalyst stripping · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title