Osmotic power generator

Patent metadata

Field	Value
Publication number	US-10801478-B2
Application number	US-201716313200-A
Country	US
Kind code	B2
Filing date	Jun 27, 2017
Priority date	Jun 28, 2016
Publication date	Oct 13, 2020
Grant date	Oct 13, 2020

Abstract

An osmotic power generator comprising an active membrane supported in a housing, at least a first chamber portion disposed on a first side of the active membrane for receiving a first electrolyte liquid and a second chamber portion disposed on a second side of the active membrane for receiving a second electrolyte liquid, a generator circuit comprising at least a first electrode electrically coupled to said first chamber, and at least a second electrode electrically coupled to said second chamber, the first and second electrodes configured to be connected together through a generator load receiving electrical power generated by a difference in potential and an ionic current between the first and second electrodes. The active membrane includes at least one pore allowing ions to pass between the first and second sides of the membrane under osmosis due to an osmotic gradient between the first and second electrolyte liquids to generate said difference in potential and ionic current between the first and second electrodes.

First claim

The invention claimed is:

1. An osmotic power generator comprising:
a housing,
an active membrane mounted in the housing,
at least a first chamber disposed on a first side of the active membrane for receiving a first electrolyte liquid and a second chamber disposed on a second side of the active membrane for receiving a second electrolyte liquid,
a generator circuit comprising at least a first electrode electrically coupled to said first chamber, and at least a second electrode electrically coupled to said second chamber, the first and second electrodes configured to be connected together through a generator load receiving electrical power generated by a difference in potential and an ionic current between the first and second electrodes,
the active membrane comprising at least one pore allowing ions to pass between the first and second sides of the active membrane under osmosis due to an osmotic gradient between the first and second electrolyte liquids to generate said difference in potential and ionic current between the first and second electrodes, wherein the active membrane comprises a thin layer of 2D material having a thickness (Hm) from 0.3 nm to 5 nm, and the at least one pore has an average diameter (Dp) from 2 nm to 25 nm.

2. The osmotic power generator according to claim 1 , wherein said active membrane comprises an electrochemically etchable 2D material comprising any one or combination of transition metal dichalcogenide (TMDC) crystals, hBn silicene, transition metal trichalcogenides, metal halides, transition metal oxides, graphene, and graphene oxide.

3. The osmotic power generator according to claim 2 wherein the TMDC is selected from MoS 2 , SnSe 2 , WS 2 , TaS 2 , MoSe 2 , WSe 2 , TaSe 2 , NbS 2 , NbSe 2 , TiS 2 , TiSe 2 , ReS 2 and ReSe 2 .

4. The osmotic power generator according to claim 1 , wherein the active membrane thin layer comprises MoS 2 thin layers or is a MoS 2 monolayer.

5. The osmotic power generator according to claim 1 , wherein the active membrane comprises an electrochemically etchable 2D material.

6. The osmotic power generator according to claim 5 , wherein the active membrane comprises any one or combination of silicene, germanene and stanene.

7. The osmotic power generator according to claim 5 , wherein the electrochemically etchable 2D material is a monoelemental two-dimensional (2D) crystal or a combination of said monoelemental two-dimensional crystals.

8. The osmotic power generator according to claim 7 , wherein the monoelemental two-dimensional (2D) crystal is a 2D-Xene.

9. The osmotic power generator according to claim 1 , wherein said active membrane thin layer is in a single, double or multilayer form.

10. The osmotic power generator according to claim 1 , wherein said active membrane comprises a plurality of pores.

11. The osmotic power generator according to claim 10 , wherein a total pore surface area of said plurality of pores constitutes up to 50% of a surface area of the active membrane.

12. The osmotic power generator according to claim 1 , wherein said active membrane comprises a plurality of pores, with a pore density up to 90% of a surface area of the active membrane.

13. The osmotic power generator according to claim 1 , wherein the active membrane thin layer is supported by a support structure provided on at least one side of the thin layer, the support structure comprising a plurality of pillar portions spaced apart between suspended portions of the thin layer comprising a plurality of said pores.

14. The osmotic power generator according to claim 1 , wherein the first and/or second electrolyte liquid is an aqueous ionic solution or a room temperature ionic liquid (RTIL).

15. The osmotic power generator according to claim 1 , wherein the concentration of the electrolyte in the first electrolyte liquid varies from 4 M to 0.4 M.

16. The osmotic power generator according to claim 1 , wherein the first electrolyte liquid is seawater.

17. The osmotic power generator according to claim 1 , wherein the osmotic power generator comprises a pressure source or pressure generator configured to increase the pressure of the first electrolyte liquid in the first chamber.

18. The osmotic power generator according to claim 17 , wherein the pressure source is gravity on a column of liquid on said first side of the active membrane.

19. The osmotic power generator according to claim 1 , wherein the osmotic power generator further comprises a pressure source or pressure generator to increase the pressure of the first electrolyte liquid to 100 bars.

20. The osmotic power generator according to claim 1 , wherein the osmotic power generator further comprises a temperature regulation system comprising a temperature sensing element and a heat source, to heat the first electrolyte liquid.

21. The osmotic power generator according to claim 20 , wherein the heat source is a waste heat source or a renewable energy heat source.

22. The osmotic power generator according to claim 1 , wherein the osmotic power generator further comprises a temperature regulation system for maintaining the temperature of the first electrolyte liquid at 4° C. to 50° C.

23. The osmotic power generator according to claim 1 , wherein the generator load includes an energy storage device.

24. A method of generating osmotic power in an osmotic membrane chamber, said method comprising:
providing the osmotic power generator according to claim 1 ,
supplying the first electrolyte liquid on said first side of the active membrane,
supplying the second electrolyte liquid on the second side of the active membrane, whereby the first electrolyte liquid has greater ionic strength than the second electrolyte liquid, and
connecting the first and second electrodes to the generator load.

25. An osmotic power generator comprising:
a housing,
two or more active membranes separated by intermediate chambers in a stacked arrangement mounted in the housing,
at least a first chamber disposed on a first side of the stacked arrangement for receiving a first electrolyte liquid and a second chamber disposed on a second side of the stacked arrangement for receiving a second electrolyte liquid,
a generator circuit comprising at least a first electrode electrically coupled to said first chamber, and at least a second electrode electrically coupled to said second chamber, the first and second electrodes configured to be connected together through a generator load receiving electrical power generated by a difference in potential and an ionic current between the first and second electrodes,
each of the two or more active membranes comprising at least one pore allowing ions to pass between the first and second sides of the stacked arrangement under osmosis due to an osmotic gradient between the first and second electrolyte liquids to generate said difference in potential and ionic current between the first and second electrodes, wherein each active membrane comprises a thin layer of 2D material having a thickness (Hm) from 0.3 nm to 5 nm, and the at least one pore has an average diameter (Dp) from 2 nm to 25 nm.

Assignees

• Ecole Polytechnique Fed Lausanne Epfl

Inventors

• Feng Jiandong
• Radenovic Aleksandra

Classifications

• F03G7/015

  Actuators using the difference in osmotic pressure between fluids · CPC title

• B01D61/002 Primary

  Forward osmosis or direct osmosis · CPC title

• B01D71/02231

  Palladium · CPC title

• B01D2325/0283

  Pore size · CPC title

• B01D69/1071

  Woven, non-woven or net mesh · CPC title