Methods and apparatuses for forming large-area carbon coatings

Patent metadata

Field	Value
Publication number	US-10801104-B2
Application number	US-201715644884-A
Country	US
Kind code	B2
Filing date	Jul 10, 2017
Priority date	Jul 12, 2013
Publication date	Oct 13, 2020
Grant date	Oct 13, 2020

Abstract

In one aspect, methods of making a carbon coating are described herein. In some implementations, a method of making a carbon coating comprises applying a first adhesive material to a substrate surface to provide an adhesive surface; rolling a carbon source over the adhesive surface to provide a carbon layer on the adhesive surface; and rolling an adhesive roller over the carbon layer to remove some but not all of the carbon of the carbon layer to provide the carbon coating.

First claim

That which is claimed is:

1. A carbon-coated substrate comprising:
a substrate surface;
a carbon coating disposed on the substrate surface, the carbon coating comprising a continuous layer of graphene or graphite covering an area of the substrate of more than 0.25 m 2 ; and
an adhesive layer disposed between and immediately adjacent to the substrate surface and the carbon coating, the adhesive layer having an outermost surface adjacent to the carbon coating, the continuous layer of graphene or graphite being disposed on the outermost surface and covering at least 90% of the outermost surface,
wherein the carbon coating has a thickness of up to 5 mm,
wherein the substrate surface is a surface of a window or windshield.

2. The carbon-coated substrate of claim 1 , wherein the carbon coating comprises graphene.

3. The carbon-coated substrate of claim 1 , wherein the carbon coating covers an area of more than 100 m 2 .

4. The carbon-coated substrate of claim 1 , wherein the thickness of the carbon coating is 100 nm or less.

5. The carbon-coated substrate of claim 1 , wherein the carbon coating is a graphene layer comprising a plurality of graphene sheets.

6. The carbon-coated substrate of claim 1 , wherein the adhesive layer comprises an animal protein-based adhesive material including at least one of collagen glue, albumin glue, casein glue, meat glue, bone glue, fish glue, hide glue, hoof glue, or rabbit skin glue.

7. The carbon-coated substrate of claim 1 , wherein the adhesive layer comprises a plant-based adhesive material including at least one of a resin, a starch, a Canada balsam resin, coccoina, gum arabic resin, latex, methyl cellulose, mucilage, resorcinol resin, or urea-formaldehyde resin.

8. The carbon-coated substrate of claim 1 , wherein the adhesive layer comprises at least one of a synthetic monomer glue, a synthetic polymer glue, an acrylonitrile, a cyanoacrylate, an acrylic glue, an epoxy resin, an epoxy putty, an ethylene-vinyl acetate, a phenol formaldehyde resin, a polyamide, a polyester resin, a polyethylene hot-melt glue, a polypropylene glue, a polysulfide, a polyurethane, a polyvinyl acetate, a polyvinyl alcohol, a polyvinyl chloride, a polyvinylpyrrolidone, a rubber cement, a silicone, or a styrene acrylate copolymer.

9. The carbon-coated substrate of claim 1 , wherein the adhesive layer comprises at least one of a paint or a primer.

10. The carbon-coated substrate of claim 1 , wherein the adhesive layer comprises:
a first adhesive material having a first adhesion strength; and
a second adhesive material having a second adhesion strength that is less than the first adhesion strength.

11. The carbon-coated substrate of claim 1 , wherein the carbon coating comprises at least 95 atom percent graphene carbon.

12. The carbon-coated substrate of claim 1 , wherein the carbon coating exhibits an optical transparency of at least 90 percent to incident radiation having a wavelength of between 350 nm and 750 nm.

13. The carbon-coated substrate of claim 1 , wherein the thickness of the carbon coating varies by 20 percent or less across the substrate surface based on an average thickness of the layer.

14. The carbon-coated substrate of claim 13 , wherein:
the carbon coating covers between 0.25 m 2 and about 100 m 2 of the substrate surface.

15. The carbon-coated substrate of claim 1 , wherein the carbon coating covers about 10 m 2 to about 100 m 2 of the substrate surface.

16. The carbon-coated substrate of claim 1 , wherein the carbon coating covers about 5 m 2 to about 100 m 2 of the substrate surface.

17. The carbon-coated substrate of claim 16 , wherein the carbon coating comprises graphene.

18. The carbon-coated substrate of claim 17 , wherein the carbon coating comprises at least 95 atom percent graphene carbon.

Assignees

• Boeing Co

Inventors

• Li Angela W
• Hunt Jeffrey H
• Howe Wayne R

Classifications

• B05C1/027 Primary

  only at particular parts of the articles (at particular parts of work of indefinite length B05C1/16) · CPC title

• B05D1/28

  performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers · CPC title

• Y10T428/26

  Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension · CPC title

• H01B1/04

  mainly consisting of carbon-silicon compounds, carbon or silicon · CPC title

• B05C1/08

  using a roller {or other rotating member which contacts the work along a generating line} · CPC title