Method of manufacturing an electrochemical cell

Patent metadata

Field	Value
Publication number	US-10797353-B2
Application number	US-201815862187-A
Country	US
Kind code	B2
Filing date	Jan 4, 2018
Priority date	Jan 4, 2018
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

A method of manufacturing an electrochemical cell may comprise exposing a surface of a metal substrate to a chalcogen in gas phase such that a metal chalcogenide layer forms on the surface of the metal substrate. A lithium metal foil may be laminated onto the metal chalcogenide layer on the surface of the metal substrate such that a surface of the lithium metal foil physically and chemically bonds to the metal chalcogenide layer on the surface of the metal substrate.

First claim

What is claimed is:

1. A method of manufacturing an electrochemical cell, the method comprising:
providing a porous or non-porous metal substrate;
exposing a surface of the metal substrate to a chalcogen in gas phase such that a conformal metal chalcogenide layer forms on the surface of the metal substrate;
providing a lithium metal foil having a first surface and an opposite second surface; and
laminating the lithium metal foil onto the metal chalcogenide layer on the surface of the metal substrate such that the first surface of the lithium metal foil physically and chemically bonds to the metal chalcogenide layer on the surface of the metal substrate.

2. The method of claim 1 wherein the surface of the metal substrate and the metal chalcogenide layer are heated to a temperature above a melting point of lithium such that, when the lithium metal foil is laminated onto the metal chalcogenide layer on the surface of the metal substrate, the first surface of the lithium metal foil locally melts and actively wets the metal chalcogenide layer on the surface of the metal substrate without melting the second surface of the lithium metal foil.

3. The method of claim 2 wherein the surface of the metal substrate and the metal chalcogenide layer are heated to a temperature in the range of 250° C. to 450° C. prior to laminating the lithium metal foil onto the metal chalcogenide layer on the surface of the metal substrate.

4. The method of claim 2 wherein the second surface of the lithium metal foil is maintained at a temperature below 180° C. while the lithium metal foil is laminated onto the metal chalcogenide layer on the surface of the metal substrate.

5. The method of claim 1 wherein the lithium metal foil is laminated onto the metal chalcogenide layer on the surface of the metal substrate by positioning the lithium metal foil adjacent the metal substrate such that the first surface of the lithium metal foil confronts the surface of the metal substrate, and then passing the metal substrate and the lithium metal foil between a pair of metal rollers.

6. The method of claim 1 wherein the metal substrate comprises a non-porous metal foil, a perforated metal sheet, or a porous metal mesh.

7. The method of claim 1 wherein the metal substrate comprises copper, and wherein the metal chalcogenide layer comprises copper oxide, copper sulfide, copper selenide, or a combination thereof.

8. The method of claim 1 wherein the chalcogen comprises oxygen, sulfur, selenium, or a combination thereof, and wherein the metal chalcogenide layer comprises a metal oxide, a metal sulfide, a metal selenide, or a combination thereof.

9. The method of claim 1 wherein the chalcogen comprises oxygen, and wherein the surface of the metal substrate is exposed to gaseous oxygen by heating the metal substrate in air such that the gaseous oxygen chemically reacts with and bonds to the surface of the metal substrate.

10. The method of claim 1 wherein the chalcogen comprises sulfur or selenium, and wherein the surface of the metal substrate is exposed to gaseous sulfur or selenium by heating a volume of solid phase sulfur or selenium to release a volume of gaseous sulfur or selenium therefrom, and then exposing the surface of the metal substrate to the volume of gaseous sulfur or selenium such that the gaseous sulfur or selenium chemically reacts with and bonds to the surface of the metal substrate.

11. The method of claim 1 wherein the metal substrate is non-porous and includes a first major surface and an opposite second major surface, and wherein the metal chalcogenide layer is formed on at least one of the first or second major surfaces of the metal substrate.

12. The method of claim 1 wherein the metal substrate has a thickness in the range of 8-20 μm.

13. The method of claim 1 wherein the metal chalcogenide layer has a thickness in the range of 1-500 nm.

14. The method of claim 1 wherein the lithium metal foil has a thickness in the range of 5-100 μm.

15. The method of claim 1 including forming the metal substrate into a negative electrode current collector exhibiting a desired size and shape and having at least one lithium metal negative electrode layer physically and chemically bonded thereto.

16. A method of manufacturing an electrochemical cell, the method comprising:
providing a porous or non-porous metal substrate having a first surface and an opposite second surface;
exposing the first and second surfaces of the metal substrate to a chalcogen in gas phase such that a first metal chalcogenide layer forms on the first surface of the metal substrate and a second metal chalcogenide layer forms on the second surface of the metal substrate;
providing a first lithium metal foil and a second lithium metal foil, each of the first and second lithium metal foils having a first surface and an opposite second surface; and
laminating the first and second lithium metal foils respectively onto the first and second metal chalcogenide layers on the first and second surfaces of the metal substrate such that the first surface of the first lithium metal foil physically and chemically bonds to the first metal chalcogenide layer on the first surface of the metal substrate and the first surface of the second lithium metal foil physically and chemically bonds to the second metal chalcogenide layer on the second surface of the metal substrate.

17. The method of claim 16 wherein the metal substrate and the first and second metal chalcogenide layers are heated to a temperature above a melting point of lithium such that, when the first and second lithium metal foils are respectively laminated onto the first and second metal chalcogenide layers on the first and second surfaces of the metal substrate, the first surface of the first lithium metal foil locally melts and actively wets the first metal chalcogenide layer on the first surface of the metal substrate without melting the second surface of the first lithium metal foil, and first surface of the second lithium metal foil locally melts and actively wets the second metal chalcogenide layer on the second surface of the metal substrate without melting the second surface of the second lithium metal foil.

18. The method of claim 16 wherein the first and second lithium metal foils are respectively laminated onto the first and second metal chalcogenide layers on the first and second surfaces of the metal substrate by positioning the first and second lithium metal foils adjacent the metal substrate such that the first surface of the first lithium metal foil confronts the first surface of the metal substrate and the first surface of the second lithium metal foil confronts the second surface of the metal substrate, and then passing the metal substrate and the first and second lithium metal foils between a pair of metal rollers.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Adair Keegan
• Dai Fang
• Cai Mei

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/058 Primary

  Construction or manufacture · CPC title

• H01M4/742

  perforated material · CPC title

• H01M4/0435

  Rolling or calendering · CPC title

• H01M4/58

  of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates · CPC title