Low pressure carbon dioxide removal from the anode exhaust of a fuel cell

Patent metadata

Field	Value
Publication number	US-10797332-B2
Application number	US-201816119389-A
Country	US
Kind code	B2
Filing date	Aug 31, 2018
Priority date	Aug 31, 2018
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

A fuel cell system for removing CO2 from anode exhaust gas includes a fuel cell having an anode that outputs anode exhaust including H2, CO, CO2, and water; a shift reactor that receives a first portion of the anode exhaust and performs a water-gas shift reaction to produce an output stream primarily including H2 and CO2; an anode gas oxidizer (AGO); and an absorption system including an absorber column that absorbs the CO2 from the output stream in a solvent and outputs a resultant gas including H2 and a hydrocarbon that is at least partially recycled to the anode, and a stripper column that regenerates the solvent and outputs a CO2-rich stream. The AGO is configured to oxidize at least a portion of the CO2-rich stream and an AGO input stream that includes one of a second portion of the anode exhaust or a portion of the output stream.

First claim

What is claimed:

1. A fuel cell system for removing carbon dioxide from anode exhaust gas, the fuel cell system comprising:
a fuel cell having an anode configured to output an anode exhaust gas comprising hydrogen, carbon monoxide, carbon dioxide, and water;
a shift reactor configured to receive a first portion of the anode exhaust gas and to perform a water-gas shift reaction to produce an output stream primarily comprising hydrogen and carbon dioxide;
an anode gas oxidizer; and
an absorption system configured to receive the output stream from the shift reactor, the absorption system comprising:
an absorber column configured to absorb the carbon dioxide from the output stream in a solvent and to output a resultant gas comprising hydrogen and a hydrocarbon that is at least partially recycled to the anode; and
a stripper column configured to regenerate the solvent and to output a carbon dioxide-rich stream, wherein:

the anode gas oxidizer is configured to receive and oxidize an anode gas oxidizer input stream and at least a portion of the carbon dioxide-rich stream; and
the anode gas oxidizer input stream comprises one of a second portion of the anode exhaust gas or a portion of the output stream from the shift reactor.

2. The fuel cell system of claim 1 , wherein another portion of the carbon dioxide-rich stream output by the stripper column is captured.

3. The fuel cell system of claim 1 , wherein the solvent comprises an amine solution.

4. The fuel cell system of claim 1 , wherein the solvent comprises mixtures of dimethyl ethers of polyethylene glycol.

5. The fuel cell system of claim 1 , further comprising:
a first heat exchanger located upstream of the shift reactor, the first heat exchanger configured to cool the first portion of the anode exhaust gas; and
a second heat exchanger located downstream of the shift reactor, the second heat exchanger configured to cool the output stream.

6. The fuel cell system of claim 5 , further comprising:
a water recovery system downstream of the second heat exchanger, the water recovery system configured to recover water from the cooled output stream and to recycle the recovered water to the anode.

7. The fuel cell system of claim 6 , wherein the anode is configured to receive a fuel gas comprising the resultant gas from the absorber column, the recovered water from the water recovery system, and a hydrocarbon stream comprising at least one of methane, natural gas, propane or other hydrocarbon.

8. The fuel cell system of claim 1 , further comprising a pressure swing adsorption system configured to receive at least a portion of the resultant gas from the absorber column and to separate hydrogen from the resultant gas.

9. The fuel cell system of claim 8 , wherein:
the pressure swing adsorption system is configured to output a first stream comprising the hydrogen and a second stream comprising carbon dioxide and the hydrocarbon; and
the second stream is recycled to the anode.

10. The fuel cell system of claim 1 , wherein the anode gas oxidizer is further configured to receive a pre-heated air stream.

11. The fuel cell system of claim 10 , further comprising a cathode configured to output a cathode gas, wherein:
the cathode exhaust gas is configured to heat an air stream to produce the pre-heated air stream; and
the cathode exhaust gas is configured to heat the stripper bottom to produce a lean solvent.

12. The fuel cell system of claim 1 , further comprising a cathode configured to output a cathode gas,
wherein the cathode exhaust gas is configured to heat fuel gas upstream of the anode.

13. A method of removing carbon dioxide from fuel cell anode exhaust gas, the method comprising:
outputting anode exhaust gas comprising hydrogen, carbon monoxide, carbon dioxide, and water from the anode;
receiving a first portion of the anode exhaust gas in a shift reactor;
receiving an anode gas oxidizer input stream in an anode gas oxidizer;
performing a water-gas shift reaction in the shift reactor to produce an output stream primarily comprising hydrogen and carbon dioxide;
receiving the output stream from the shift reactor in an absorption system comprising an absorber column having a solvent therein and a stripper column;
absorbing the carbon dioxide from the output stream in the solvent and outputting, from the absorber column, a resultant gas comprising hydrogen and a hydrocarbon that is at least partially recycled to the anode;
regenerating the solvent and outputting, from the stripper column, a carbon dioxide-rich stream; and
oxidizing the anode gas oxidizer input stream and at least a portion of the carbon dioxide-rich stream to produce an oxidant gas,
wherein the anode gas oxidizer input stream comprises one of a second portion of the anode exhaust gas or a portion of the output stream from the shift reactor.

14. The method of claim 13 , further comprising capturing another portion of the carbon dioxide-rich stream.

15. The method of claim 13 , wherein the solvent comprises an amine solution.

16. The method of claim 13 , wherein the solvent comprises mixtures of dimethyl ethers of polyethylene glycol.

17. The method of claim 13 , further comprising:
cooling the first portion of the anode exhaust gas prior to entering the shift reactor; and
cooling the output stream of the shift reactor.

18. The method of claim 17 , further comprising:
recovering water from the cooled output stream; and
recycling the recovered water to the anode.

19. The method of claim 18 , further comprising receiving a fuel gas at the anode that comprises the resultant gas from the absorber column, the recovered water from the water recovery system, and a gas stream comprising at least one of methane or natural gas.

20. The method of claim 19 , further comprising heating the fuel gas, upstream of the anode, using cathode exhaust gas.

21. The method of claim 13 , further comprising:
separating hydrogen from the resultant gas using a pressure swing adsorption system.

22. The method of claim 21 , further comprising:
outputting, from the pressure swing adsorption system, a first stream comprising hydrogen;
outputting, from the pressure swing adsorption system, a second stream comprising carbon dioxide and the hydrocarbon; and
recycling the second stream to the anode.

23. The method of claim 13 , further comprising:
heating an air stream using cathode exhaust gas to form a pre-heated air stream; and
providing the pre-heated air stream to the anode gas oxidizer.

Assignees

• Fuelcell Energy Inc

Inventors

• Jahnke Fred C
• Lambrech Matthew A

Classifications

• H01M8/0612

  from carbon-containing material · CPC title

• H01M8/0668 Primary

  Removal of carbon monoxide or carbon dioxide · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/0637

  Direct internal reforming at the anode of the fuel cell · CPC title

• C01B3/56

  by contacting with solids; Regeneration of used solids · CPC title