Perovskite nanocrystalline particles and optoelectronic device using same
US-2017358757-A1 · Dec 14, 2017 · US
US10796901B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10796901-B2 |
| Application number | US-201715714519-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 25, 2017 |
| Priority date | Sep 29, 2016 |
| Publication date | Oct 6, 2020 |
| Grant date | Oct 6, 2020 |
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A core/shell semiconductor nanoparticle structure comprises a core comprising a halide perovskite semiconductor and a shell comprising a semiconductor material that is not a halide perovskite (and that is substantially free of halide perovskites). The halide perovskite semiconductor core may be of the form AMX3, wherein: A is an organic ammonium such as CH3NH3+, (C8H17)2(CH3NH3)+, PhC2H4NH3+, C6H11CH2NH3+ or 1-adamantyl methyl ammonium, an amidinium such as CH(NH2)2+, or an alkali metal cation such as Li+, Na+, K+, Rb+ or Cs+; M is a divalent metal cation such as Mg2+, Mn2+, Ni2+, Co2+, Pb2+, Sn2+, Zn2+, Ge2+, Eu2+, Cu2+ or Cd2+; and X is a halide anion (F−, Cl−, Br−, I−) or a combination of halide anions.
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What is claimed is: 1. A photoluminescent core/shell semiconductor nanoparticle comprising: a core comprising a halide perovskite semiconductor of the form ABX 3 ; and a shell substantially surrounding the core and comprising BaTiO 3 , SrTiO 3 , BiFeO 3 , LaNiO 3 , CaTiO 3 , PbTiO 3 or LaYbO 3 , wherein the shell is substantially free of halide perovskites, A is selected from the group consisting of Li + , Na + , K + , Rb + and Cs + , M is a divalent metal cation selected from the group consisting of Mg 2+ , Mn 2+ , Pb 2+ , Sn 2+ and Zn 2+ , and X is selected from the group consisting of F − , Cl − , Br − and I − . 2. A composition comprising: a population of core/shell semiconductor nanoparticles according to claim 1 ; and a matrix. 3. The composition of claim 2 , wherein the matrix comprises a resin. 4. A solution comprising: a population of core/shell semiconductor nanoparticles according to claim 1 ; and a solvent. 5. A light-emitting device comprising the photoluminescent core/shell nanoparticle of claim 1 .
the material having a perovskite structure, e.g. BaTiO3 · CPC title
Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title
Wavelength conversion materials · CPC title
containing organic luminescent materials · CPC title
within the light-emitting regions · CPC title
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