Techniques and materials for calibrating optical sensors

Patent metadata

Field	Value
Publication number	US-10794826-B2
Application number	US-201815927335-A
Country	US
Kind code	B2
Filing date	Mar 21, 2018
Priority date	Mar 27, 2017
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

A calibration material may be used to calibrate an optical sensor to help ensure that the optical sensor produces accurate measurements. In some examples, the calibration material may be used to calibrate both turbidity measurements made by an optical sensor and fluorometric measurements made by the same optical sensor. The calibration material may be an aqueous mixture that includes water in an amount greater than 70 percent by weight of the composition, inorganic, water-insoluble, light-scattering particles, and a viscosity modifier in an amount effective to maintain the inorganic, water-insoluble, light-scattering particles in suspension in the composition. The composition can be non-fluorescing when exposed to ultraviolet light. In addition, in some applications, the composition is formulated of food safe ingredients, allowing the composition to be used in facilities that process consumable foods and beverages.

First claim

The invention claimed is:

1. A method of calibrating a turbidity and fluorometric optical sensor comprising:
selecting a calibration composition formulated of food safe ingredients;
emitting light at a first wavelength by an optical emitter of an optical sensor into the calibration composition;
detecting light scattered by the calibration composition in response to light emitted at the first wavelength by an optical detector of the optical sensor and determining therefrom a turbidity of the calibration composition;
comparing the turbidity of the calibration composition determined via the optical sensor to a known turbidity of the calibration composition and storing turbidity calibration data in a memory associated with the optical sensor based on the comparison;
emitting light at a second wavelength different than the first wavelength by the optical emitter of the optical sensor into the calibration composition;
detecting an optical response corresponding to fluorescent emissions emitted by the calibration composition; and
comparing the fluorescent emissions of the calibration composition detected via the optical sensor to a known fluorescent emissions level of the calibration composition and storing fluorescence calibration data in a memory associated with the optical sensor based on the comparison.

2. The method of claim 1 , wherein the known fluorescent emissions level of the calibration composition is a zero fluorescent emissions level.

3. The method of claim 1 , wherein the optical sensor houses the optical emitter and the optical detector and contains only a single optical window through which the optical emitter emits light into the calibration composition and through which the optical detector receives light from the calibration composition.

4. The method of claim 1 , wherein emitting light at the first wavelength by the optical emitter of the optical sensor into the calibration composition, detecting light scattered by the calibration composition, emitting light at the second wavelength different than the first wavelength by the optical emitter of the optical sensor into the calibration composition, and detecting the optical response corresponding to fluorescent emissions emitted by the calibration composition are each performed in a production area where at least one of a food and a beverage material is being handled.

5. The method of claim 1 , further comprising obtaining the optical sensor from a food or beverage production facility where the optical sensor is utilized during normal operation.

6. The method of claim 1 , wherein the first wavelength of light is within a range from 400 nanometers to 700 nanometers, and the second wavelength of light is within a range from 200 nanometers to 400 nanometers.

7. The method of claim 6 , wherein the optical emitter comprises a first optical emitter housed within the optical sensor that emit light at the first wavelength and a second optical emitter housed within the optical sensor that emits light at the second wavelength.

8. The method of claim 1 , wherein the calibration composition comprises:
water in an amount greater than 70 percent by weight of the calibration composition;
inorganic, water-insoluble, light-scattering particles; and
a viscosity modifier in an amount effective to maintain the inorganic, water-insoluble, light-scattering particles in suspension in the calibration composition, and
the calibration composition is non-fluorescing when exposed to light emitted at the second wavelength.

9. The method of claim 8 , wherein:
the amount of water ranges from 90 percent by weight to 98 percent by weight of the calibration composition;
the inorganic, water-insoluble, light-scattering particles consist essentially of titanium dioxide, and
the inorganic, water-insoluble, light-scattering particles are present in the calibration composition in an amount effective to provide a turbidity ranging from 1 NTU to 10,000 NTU.

10. The method of claim 8 , further comprising, prior to emitting light into the calibration composition, agitating the calibration composition to distribute the inorganic, water-insoluble, light-scattering particles substantially uniformly in the calibration composition.

11. The method of claim 8 , wherein the calibration composition further comprises a buffering agent that buffers the calibration composition to an acidic pH level.

12. The method of claim 11 , wherein the acidic pH level is a pH less than 5.0.

13. The method of claim 11 , wherein the buffering agent comprises phosphoric acid and a phosphate salt.

Assignees

• Ecolab Usa Inc

Inventors

• Walsh Richard Joseph
• Hendrickson Evan
• Power Caleb
• Banks Rodney

Classifications

• G01N21/4785 Primary

  Standardising light scatter apparatus; Standards therefor · CPC title

• G01N21/274

  Calibration, base line adjustment, drift correction · CPC title

• G01N21/278

  Constitution of standards · CPC title

• G01N2021/6491

  Measuring fluorescence and transmission; Correcting inner filter effect · CPC title

• G01N21/85

  Investigating moving fluids or granular solids · CPC title