Method and device for separating air by cryogenic distillation

Patent metadata

Field	Value
Publication number	US-10794630-B2
Application number	US-201816054223-A
Country	US
Kind code	B2
Filing date	Aug 3, 2018
Priority date	Aug 3, 2017
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

Method for separating air by cryogenic distillation, wherein air is compressed in a compressor and is subsequently sent to a heat exchanger, with the air cooled in the exchanger being sent to a check valve downstream of the heat exchanger and subsequently to a turbine, the valve being positioned so that air from a short-circuiting duct cannot return to the exchanger from the compressor.

First claim

The invention claimed is:

1. A method for separating air by cryogenic distillation, the method comprising a normal mode and a start-up operation, wherein the normal operation comprises the steps of:
i) cooling compressed and purified air in a heat exchanger, compressing a first part of the air in a cold compressor at an intermediate temperature of the heat exchanger and returning the first part of the air to the heat exchanger for further cooling and liquefaction within the heat exchanger to form liquid air, wherein the liquid air is sent from the heat exchanger to at least a first column of a double column, the double column comprising the first column and a second column, the second column operating at a lower pressure than the first column;
ii) sending oxygen and nitrogen enriched liquids from the first column to the second column, extracting an oxygen enriched fluid from the bottom of the second column, and extracting a nitrogen enriched fluid from the top of the second column and then heating the nitrogen enriched fluid in the heat exchanger; and
iii) withdrawing a second part of the air from the heat exchanger at an intermediate temperature thereof, expanding the second part of the air in a first turbine before sending to the first column;
wherein the start-up operation comprises the step of:
iv) sending the first part of the air from the cold compressor to a short-circuiting duct and then expanding the first part of the air to form an expanded fraction of boosted air;
v) sending the expanded fraction of boosted air to the system of columns for separation within,
wherein steps iv) and v) are conducted without the first part of the air or the expanded fraction of boosted air having been cooled in the main heat exchanger,
wherein there is a check valve disposed downstream of the heat exchanger, the check valve being in fluid communication with the heat exchanger, the short-circuiting duct, and the inlet of the first turbine, the check valve being configured to prevent the first part of the air from moving in the opposite direction to that of normal operation and from being introduced into the heat exchanger from the short-circuiting duct.

2. The method according to claim 1 , wherein in step iv) the first part of the air is sent from the cold compressor to the first turbine and/or to a second turbine by passing through the short-circuiting duct and an arrival point, thereby allowing the first part of the air to be sent from the cold compressor to the first turbine and/or to the second turbine without passing through the heat exchanger therebetween.

3. The method according to claim 1 , further comprising the step of providing a second turbine, wherein the second part of the air is divided into a first fraction and a second fraction, wherein the first fraction expands in the first turbine and at least a first portion of the second fraction expands in the second turbine, wherein the first fraction and the second faction, after expanding in the first and second turbines, are mixed at a mixing point and are subsequently sent to the first column as a single flow.

4. The method according to claim 3 , wherein a second portion of the second fraction is expanded in an expansion valve and then mixed with the first portion of the second fraction at a location downstream the mixing point and upstream the first column.

5. The method according to claim 1 , wherein the cold compressor is driven by the first or the second turbine.

6. The method according to claim 1 , wherein the inlet temperature of the cold compressor during the normal operation is below 0° C.

7. The method according to claim 1 , wherein the inlet temperature of the cold compressor during the normal operation is below −50° C.

8. The method according to claim 1 , wherein the method further comprises the steps of measuring an outlet temperature of the cold booster, and then in response to the measured outlet temperature of the cold booster, switching between the normal operation and the start-up operation.

9. A device for separating air by cryogenic distillation comprising:
a heat exchanger having a warm end, a cold end, and an intermediate section disposed between the warm end and the cold end;
a double separation column comprising a first column and a second column, the second column operating at a lower pressure than the first column, wherein the double separation column is in fluid communication with the cold end of the heat exchanger thereby allowing for the double separation column to receive a liquefied air from the cold end of the heat exchanger; wherein the double separation column is configured to send an oxygen-enriched liquid and a nitrogen-enriched liquid from the first column to the second column, wherein the double separation column is further configured to send an oxygen-enriched fluid from the bottom of the second column and a nitrogen-enriched fluid from the top of the second column to the cold end of the heat exchanger for warming therein;
an air feed conduit configured to send compressed and purified air to the warm end of the heat exchanger;
a cold compressor in fluid communication with the intermediate section of the heat exchanger, such that the cold compressor is configured to receive a first part of air from the intermediate section of the heat exchanger,
a first conduit in fluid communication with an outlet of the cold compressor and the heat exchanger, such that the first conduit is configured to transfer compressed air from the cold compressor to the heat exchanger;
an extraction duct in fluid communication with the intermediate section of the heat exchanger, the extraction duct being configured to extract a second part of the air from the heat exchanger at an intermediate temperature;
a first turbine in fluid communication with the extraction duct, such that the first turbine is configured to receive at least a first fraction of the second part of the air from the extraction duct, wherein an outlet of the first turbine is in fluid communication with the first column;
a short-circuit conduit in fluid communication with a discharge of the cold compressor and the extraction duct, wherein the short-circuit conduit connects to the extraction duct at an arrival point, wherein the short-circuit conduit does not traverse through the heat exchanger, the short-circuit conduit having a control valve configured to allow or restrict flow of compressed air received from the cold compressor through the short-circuit conduit;
a check valve disposed on the extraction duct downstream of the heat exchanger, the check valve being disposed on the extraction duct between the arrival point and the heat exchanger and being configured to prevent air from moving from the arrival point and into the heat exchanger.

10. The device according to claim 9 , further comprising a division point downstream the check valve, wherein the division point is disposed between the check valve and the arrival point.

11. The device according to claim 10 , further comprising a second turbine in fluid communication with the division point, wherein the division point is configured to split the second part of the air from the heat exchanger into a first fraction and a second fraction, wherein the first turbine is configured to receive the first fraction, wherein the second turbine is configured to receive the second fraction.

12. The device according to claim 11 , wherein the first fraction and the second fraction are mixed together at a mixing point following expansion in the first turbine and second turbine, respectively.

13. The device according to claim 10 , further comprising an expansion bypass-valve disposed downst

Assignees

• Air Liquide

Inventors

• Cavagne Patrice
• Dos Santos Benedicte
• Lemaire Yann-Pierrick

Classifications

• F25J3/04563

  Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating · CPC title

• F25J2240/42

  the fluid being air · CPC title

• F25J2240/10

  the fluid being air · CPC title

• F25J2230/40

  the fluid being air · CPC title

• F25J3/04781

  Pressure changing devices, e.g. for compression, expansion, liquid pumping · CPC title