Dyeable polyolefin fiber and fibrous structure comprising same

Patent metadata

Field	Value
Publication number	US-10793976-B2
Application number	US-201716084199-A
Country	US
Kind code	B2
Filing date	Feb 28, 2017
Priority date	Mar 11, 2016
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

A dyeable polyolefin fiber includes a sea-island structure in which a polyolefin (A) is the sea component and a copolyester (B) obtained by copolymerizing cyclohexanedicarboxylic acid is the island component, the polyolefin fiber characterized in that the dispersion diameter of the island component in a lateral cross section of the fiber is 30 to 1000 nm. The dyeable polyolefin fiber is bright, deep coloring is imparted to the lightweight polyolefin fiber, oxidative decomposition during tumbler drying and yellowing during long-term storage are minimized, and the polyolefin fiber can be suitably used as a fibrous structure.

First claim

The invention claimed is:

1. A dyeable polypropylene fiber comprising a polymer alloy fiber having an islands-in-a-sea structure comprising a polypropylene (A) as a sea component and a copolymerized polyester (B) with cyclohexanedicarboxylic acid copolymerized as an island component, wherein a dispersion diameter of the island component in a lateral fiber cross section of the fiber is 30 to 1000 nm, and
cyclohexanedicarboxylic acid is copolymerized at a ratio of 10 to 100 mol % relative to all dicarboxylic acid components in the copolymerized polyester (B).

2. The dyeable polypropylene fiber according to claim 1 , further comprising a compatibilizer (C).

3. The dyeable polypropylene fiber according to claim 2 , wherein the compatibilizer (C) is one or more compounds selected from the group consisting of a polyolefin-based resin, an acrylic resin, a styrene-based resin, and a conjugated diene-based resin each containing at least one functional group selected from the group consisting of an acid anhydride group, a carboxyl group, a hydroxyl group, an epoxy group, an amino group, and an imino group.

4. The dyeable polypropylene fiber according to claim 2 , wherein the compatibilizer (C) is a styrene-ethylene-butylene-styrene copolymer containing at least one functional group selected from an amino group and an imino group.

5. The dyeable polypropylene fiber according to claim 2 , wherein the fiber contains the copolymerized polyester (B) in an amount of 3.0 to 20.0 parts by weight per 100 parts by weight in total of the polypropylene (A), the copolymerized polyester (B) and the compatibilizer (C).

6. The dyeable polypropylene fiber according to claim 2 , wherein the fiber contains the compatibilizer (C) in an amount of 0.1 to 10.0 parts by weight per 100 parts by weight in total of the polypropylene (A), the copolymerized polyester (B) and the compatibilizer (C).

7. The dyeable polypropylene fiber according to claim 1 , wherein the maximum temperature of a sample of the fiber is 155° C. or less during isothermal holding of the sample at 150° C. for 100 hours in a test according to the oxidative exotherm test method (acceleration method) of a polypropylene fiber specified by Japan Chemical Fibers Association.

8. The dyeable polypropylene fiber according to claim 1 , wherein the color fastness to nitrogen oxides measured according to JIS L0855 is class 4 or higher.

9. The dyeable polypropylene fiber according to claim 1 , wherein the phenolic yellowing measured according to ISO 105-X18 is class 3 or higher.

10. The dyeable polypropylene fiber according to claim 1 , further comprising an antioxidant.

11. The dyeable polypropylene fiber according to claim 10 , wherein the antioxidant is at least one species selected from the group consisting of a phenol-based compound, a phosphorus-based compound, and a hindered amine-based compound.

12. The dyeable polypropylene fiber according to claim 11 , wherein the hindered amine-based compound is an aminoether type hindered amine-based compound.

13. A fibrous structure at least partly comprising the dyeable polypropylene fiber according to claim 1 .

Assignees

• Toray Industries

Inventors

• Kano Hidekazu
• Hamanaka Shogo
• Mochizuki Katsuhiko

Classifications

• C08G63/18

  the acids or hydroxy compounds containing carbocyclic rings · CPC title

• D01D5/36

  Matrix structure; Spinnerette packs therefor · CPC title

• C08G63/199

  Acids or hydroxy compounds containing cycloaliphatic rings · CPC title

• D01F6/46

  of polyolefins · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title