Low transition temperature mixtures and lubricating oils containing the same

Patent metadata

Field	Value
Publication number	US-10793801-B2
Application number	US-201815879911-A
Country	US
Kind code	B2
Filing date	Jan 25, 2018
Priority date	Feb 6, 2017
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

Low transition temperature mixtures (LTTMs) comprising a eutectic mixture of a quaternary amine and a polyol such as glycol are provided. The LTTMs can provide various beneficial properties, such as highly desirable viscosity index, low glass transition temperatures, and/or high kinematic viscosities relative to the molecular weight of the mixture components. The mixtures can be advantageously used as co-base stocks in lubricating oil compositions.

First claim

What is claimed is:

1. A composition comprising a eutectic mixture of:
a first component comprising a quaternary amine having at most 6 carbon atoms per molecule; and
a second component comprising an ethylene glycol;
wherein a molar ratio of the first component to the second component in the mixture is in a range from 1:1 to 1:4, and the composition exhibits a glass transition temperature of no higher than −70° C., a viscosity index of at least 120, and a kinematic viscosity at 100° C. in a range from 2.0 to 10 cSt.

2. The composition of claim 1 , wherein the molar ratio of the first component to the second component is in a range from 1:2 to 1:4.

3. The composition of claim 1 , wherein the first component comprises choline chloride, betaine, or a combination thereof.

4. The composition of claim 1 , wherein the mixture exhibits a viscosity index of at least 80 and a glass transition temperature of no higher than −90° C.

5. The composition of claim 1 , wherein the first component has at most 5 carbon atoms per molecule.

6. The composition of claim 1 , wherein the composition further comprises 0.1 to 5.0 wt % water, based on the total weight of the composition.

7. The composition of claim 1 wherein the composition exhibits a glass transition temperature of no higher than −110° C. and a kinematic viscosity at 100° C. in a range from 2.0 to 6.0 cSt.

8. The composition of claim 1 , exhibiting a viscosity index of at least 140 and/or a kinematic viscosity at 100° C. of at least 3.5 cSt.

9. The composition of claim 1 , wherein the composition exhibits a traction coefficient of no higher than 0.01 at temperatures in a range from 40° C. to 100° C. as determined using a mini traction machine at a speed of 2 m/s and a pressure of 0.75 GPa.

10. A lubricating oil comprising a primary lubricating oil base stock and a secondary lubricant component having a composition capable of forming a eutectic mixture, wherein the eutectic mixture comprises a first component comprising a quaternary amine having at most 6 carbon atoms per molecule and a second component comprising an ethylene glycol wherein:
the eutectic mixture comprises an equilibrium phase between the first component and the second component;
a molar ratio of the first component to the second component in the eutectic mixture ranges from 1:1 to 1:4; and
the eutectic mixture exhibits a glass transition temperature of no higher than −70° C., a viscosity index of at least 120, and a kinematic viscosity at 100° C. in a range from 2.0 to 10 cSt.

11. The lubricating oil of claim 10 , wherein the molar ratio of the first component to the second component in the eutectic mixture ranges from 1:2 to 1:4.

12. The lubricating oil of claim 10 , further comprising one or more of an antiwear additive, a viscosity modifier, an antioxidant, a detergent, a dispersant, a pour point depressant, a corrosion inhibitor, a metal deactivator, a seal compatibility additive, an antifoaming agent, and an anti-rust additive.

13. The lubricating oil of claim 10 , wherein, based on the total weight of the lubricating oil:
the primary lubricating oil base stock is present at a concentration in a range from 50 to 95 wt %; and/or
the secondary lubricant component stock is present at a concentration in a range from 1.0 to 20 wt %.

14. A composition comprising a eutectic mixture of:
a first component comprising a quaternary amine having at most 6 carbon atoms per molecule; and
a second component comprising an ethylene glycol;
wherein a molar ratio of the first component to the second component in the mixture is in a range from 1:2 to 1:4, and the composition exhibits a glass transition temperature of no higher than −70° C., a viscosity index of at least 140, and a kinematic viscosity at 100° C. in a range from 3.0 to 6 cSt.

15. A composition comprising a eutectic mixture of:
a first component comprising a quaternary amine having at most 6 carbon atoms per molecule; and
a second component comprising an ethylene glycol;
wherein a molar ratio of the first component to the second component in the mixture is in a range from 1:1 to 1:4, and the composition exhibits a glass transition temperature of no higher than −70° C., a viscosity index of at least 120, and a kinematic viscosity at 100° C. in a range from 2.0 to 10 cSt
wherein the mixture is formed in the absence of any additional solvent that dissolves both compounds.

16. The composition of claim 15 wherein the first and second components are compatible.

17. The lubricating oil of claim 10 , wherein the eutectic mixture is used to deliver additives that have limited solubility in lubricants.

18. The lubricating oil of claim 17 , wherein the delivery can be triggered by either heat, moisture, or other solvent.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Patil Abhimanyu O
• Bodige Satish
• Gunasekara Thilina N

Classifications

• C10M111/02 Primary

  at least one of them being a non-macromolecular organic compound · CPC title

• C10M105/58

  Amines, e.g. polyalkylene polyamines, quaternary amines (polyalkylene polyamines with eleven or more monomer units C10M107/44) · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10M2207/024

  having at least two phenol groups but no condensed ring · CPC title

• C10M2207/0225

  used as base material · CPC title