Process for the production of olefins and of middle distillates from a hydrocarbon effluent resulting from the fischer-tropsch synthesis

Patent metadata

Field	Value
Publication number	US-10793787-B2
Application number	US-201916513106-A
Country	US
Kind code	B2
Filing date	Jul 16, 2019
Priority date	Jul 18, 2018
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

Process for the production of olefins and of middle distillates from a paraffinic feedstock, in which:
a) a paraffinic feedstock resulting from a Fischer-Tropsch unit is recovered, the said feedstock containing a light fraction and a heavy fraction; b) the light fraction is sent to a catalytic cracking unit; c) the effluent resulting from the catalytic cracking unit is separated in a fractionation unit in order to obtain a fraction of light hydrocarbons, an olefinic fraction and a residual liquid fraction; d) the heavy fraction is sent to a hydrocracking/hydroisomerization unit; e) the effluent resulting from the hydrocracking/hydroisomerization unit is separated in a fractionation unit in order to obtain a middle distillates fraction, a naphtha cut having a maximum boiling point of less than 180° C. and an unconverted heavy fraction; f) a part of the naphtha cut resulting from the fractionation unit is sent to the catalytic cracking unit.

First claim

The invention claimed is:

1. Process for the production of olefins and of middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis comprising at least the following stages:
a) the said paraffinic feedstock resulting from a Fischer-Tropsch unit (A) is recovered, the said paraffinic feedstock comprising at least a light fraction, known as condensate, and a heavy fraction, known as waxes;
b) at least a part of the said light fraction is sent to a catalytic cracking unit (C);
c) the effluent resulting from the catalytic cracking unit is separated in a fractionation unit (D) in order to obtain at least a fraction comprising light hydrocarbons, at least an olefinic fraction and at least a residual liquid fraction;
d) at least a part of the said heavy fraction is sent to a hydrocracking/hydroisomerization unit (F) in the presence of hydrogen and of a hydrocracking/hydroisomerization catalyst;
e) the effluent resulting from the hydrocracking/hydroisomerization unit is separated in a fractionation unit (G) in order to obtain a middle distillates fraction, a naphtha cut having a maximum boiling point of less than 180° C. and an unconverted heavy fraction;
f) at least a part of the said naphtha cut resulting from the fractionation unit is sent to the catalytic cracking unit.

2. Process according to claim 1 , in which:
an additional stage a′) is carried out in which the said light fraction obtained in stage a) is fractionated in a fractionation unit (H) in order to obtain a light cut of the said light fraction, the final boiling point of which is less than 180° C., and a heavy cut of the said light fraction, the initial boiling point of which is greater than 120° C.;
a stage b) is carried out in which the said light cut of the said light fraction resulting from stage a′) is sent to the said catalytic cracking unit (C).

3. Process according to claim 2 , in which an additional stage a″) is carried out in which the said heavy cut of the said light fraction obtained on conclusion of stage a′) is sent to the said hydrocracking/hydroisomerization unit (F), as a mixture with the said heavy fraction resulting from stage a).

4. Process according to claim 2 , in which a stage g) is carried out in which the said heavy cut of the said light fraction obtained on conclusion of stage a′) is sent to a hydrotreating unit (I) in order to obtain a hydrotreated heavy cut of the said light fraction.

5. Process according to claim 4 , in which a stage h) is carried out in which the said hydrotreated heavy cut of the said light fraction obtained on conclusion of stage g) is sent to the isomerization unit (J).

6. Process according to claim 5 , in which a stage i) is carried out in which the effluent resulting from the isomerization unit (J) of stage h) is sent to the fractionation unit (G), as a mixture with the effluent resulting from the hydrocracking/hydroisomerization unit (F).

7. Process according to claim 6 , in which the catalyst of the isomerization unit (J) comprises at least one noble metal from Group VIII and a support comprising at least one IZM-2 zeolite and at least one binder.

8. Process according to claim 1 , in which the said light fraction and/or the said heavy fraction obtained on conclusion of stage a) is/are sent, before stage b), to a hydrotreating unit.

9. Process according to claim 1 , in which the said residual liquid fraction obtained on conclusion of stage c) is recycled, at least in part, in stage b).

10. Process according to claim 1 , in which the said unconverted heavy fraction obtained on conclusion of stage e) is recycled, at least in part, in stage d).

11. Process according to claim 1 , in which all of the said naphtha cut resulting from the fractionation unit is sent to the catalytic cracking unit.

12. Process according to claim 1 , in which the catalytic cracking unit comprises a catalyst comprising a ZSM-5 zeolite.

13. Process according to claim 1 , in which the catalyst of the hydrocracking/hydroisomerization unit (C) comprises at least one hydro/dehydrogenating metal chosen from the group formed by the metals of Group Vlb and of Group VIII and at least one Bronsted acid solid.

Assignees

• Ifp Energies Now

Inventors

• Heraud Jean-Philippe
• Etienne Pascal

Classifications

• C10G47/16

  Crystalline alumino-silicate carriers · CPC title

• C10G2300/1022

  Fischer-Tropsch products · CPC title

• C10G11/18 Primary

  according to the "fluidised-bed" technique · CPC title

• C10G69/10

  hydrocracking of higher boiling fractions into naphtha and reforming the naphtha obtained · CPC title

• C10G47/00

  Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title