Method of acid saccharification of biomass

Patent metadata

Field	Value
Publication number	US-10793537-B1
Application number	US-201916683260-A
Country	US
Kind code	B1
Filing date	Nov 14, 2019
Priority date	Oct 1, 2019
Publication date	Oct 6, 2020
Grant date	Oct 6, 2020

Abstract

Disclosed herein are a method of acid saccharification of biomass and a method of polymerization of furan compounds. The method of acid saccharification of biomass comprises recovering pentose-derived furan compounds produced during the acid saccharification process of biomass. The method of acid saccharification of biomass comprises introducing furan compounds into the acid saccharification process of biomass, to produce and recover furan polymers.

First claim

What is claimed is:

1. A method of acid saccharification of biomass, comprising:
preparing a mixture of two immiscible phases; and
carrying out acid saccharification of the biomass in the mixture of two immiscible phases,
wherein the first phase is an extraction solution for furan compounds and the second phase is an acidic aqueous solution comprising the biomass, and the first phase is immiscible in the second phase, and
wherein the extraction solution for furan compounds comprises a hydrophobic ether compound, an alcohol compound, a ketone compound, or a combination thereof.

2. The method of acid saccharification of biomass according to claim 1 ,
wherein the extraction solution for furan compounds comprises cyclopentylmethylether.

3. The method of acid saccharification of biomass according to claim 1 ,
wherein the furan compounds are furfural.

4. The method of acid saccharification of biomass according to claim 1 ,
wherein the preparing comprises adding the extraction solution for furan compounds to the acidic aqueous solution containing biomass.

5. The method of acid saccharification of biomass according to claim 4 ,
wherein the acidic aqueous solution containing biomass is a suspension obtained by mixing biomass and an acidic aqueous solution and then stirring the resultant at 30 to 50° C.

6. The method of acid saccharification of biomass according to claim 1 ,
wherein the method comprises a step of recovering furan compounds from the extraction solution.

7. The method of acid saccharification of biomass according to claim 4 ,
wherein the method comprises a step of further adding a furan compound to the acidic aqueous solution containing biomass.

8. The method of acid saccharification of biomass according to claim 7 ,
wherein the furan compound added to the acidic aqueous solution is one or more of furan, 2-methylfuran, and gamma-valerolactone.

9. The method of acid saccharification of biomass according to claim 7 ,
wherein, in the method, the acid saccharification of biomass and the polymerization of furan compounds are carried out as a one-pot reaction.

10. The method of acid saccharification of biomass according to claim 9 ,
wherein, in the method, one or more of 5,5′-(furan-2-ylmethylene)bis(2-methylfuran) and 5,5-bis(5-methylfuran-2-yl)pentan-2-one are produced through polymerization.

11. The method of acid saccharification of biomass according to claim 4 ,
wherein the extraction solution is added in a volume ratio of 0.5 or more relative to the acidic aqueous solution.

12. The method of acid saccharification of biomass according to claim 4 ,
wherein the acid saccharification is carried out at 80 to 150° C.

13. The method of acid saccharification of biomass according to claim 1 , wherein a volume ratio of the extraction solution to the acidic aqueous solution in the mixture of two immiscible phases is 0.5:1 to 2:1.

Assignees

• Korea Inst Sci & Tech

Inventors

• Ha Jeong-Myeong
• Yang Hyemin
• Jeong Ye Seul
• Choi Jae Wook
• Suh Dong Jin
• Yoon Young Hyun
• Yang Gi Seok
• Lee Ung

Classifications

• C07H3/02

  Monosaccharides · CPC title

• C07H1/00

  Processes for the preparation of sugar derivatives · CPC title

• C07D307/46

  Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom · CPC title

• C07D307/36 Primary

  with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms · CPC title

• C13K13/00

  Sugars not otherwise provided for in this class · CPC title