Supported catalyst material for a fuel cell

Patent metadata

Field	Value
Publication number	US-10790515-B2
Application number	US-201715456389-A
Country	US
Kind code	B2
Filing date	Mar 10, 2017
Priority date	Mar 10, 2016
Publication date	Sep 29, 2020
Grant date	Sep 29, 2020

Abstract

The disclosure relates to a supported catalyst material for a fuel cell. This comprises an electrically conductive, carbon-based carrier material and catalytic structures deposited or grown on the carrier material with a multilayer structure. The core layer comprises an electrically conductive bulk material, with the bulk material in direct contact with the carbon-based carrier material. The thin surface layer has a catalytically active noble metal or an alloy thereof. The preparation is carried out directly onto the carrier material with the deposition of the corresponding starting materials from the gas phase.

First claim

The invention claimed is:

1. A supported catalyst material for a fuel cell, comprising:
a porous, electrically conductive carbon-based carrier material; and
catalytic structures including a first catalytic structure and a second catalytic structure on the carbon-based carrier material, the first catalytic structure and the second catalytic structure each including:
a center region including: an anchor covalently bonded to a portion of the carbon-based carrier material, and a core layer of an electrically conductive bulk material on and around the anchor, the core layer in direct contact with the carbon-based carrier material, the center region of the first catalytic structure spatially separated from the center region of the second catalytic structure, and
a surface layer of a catalytically active noble metal or an alloy thereof on the core layer, the surface layer comprising crystal edges and crystal corners, wherein a local protective layer selectively covers the crystal edges or the crystal edges and the crystal corners.

2. The catalyst material according to claim 1 wherein the bulk material of the core layer of the first catalytic structure and the second catalytic structure is selected from the group consisting of nitrides, carbides, borides, oxides of metals, and combinations thereof.

3. The catalyst material according to claim 1 , wherein the first catalytic structure and the second catalytic structure each include a bonding agent layer comprising tungsten, arranged between the core layer and the surface layer.

4. The catalyst material according to claim 1 , wherein an intermediate layer comprising a noble metal alloy is arranged between the core layer and the surface layer of each of the first catalytic structure and the second catalytic structure.

5. The catalyst material according to claim 1 , wherein an intermediate layer comprising a noble metal alloy is arranged between an adhesion-promoting layer and the surface layer of each of the first catalytic structure and the second catalytic structure.

6. The catalyst material according to claim 1 , wherein the carbon-based carrier material of each of the first catalytic structure and the second catalytic structure has a porous particulate structure.

7. The catalyst material according to claim 6 , wherein the carbon-based carrier material of each of the first catalytic structure and the second catalytic structure includes graphite, volcanic graphite carbon, graphene, ketjenblack, acetylene black, furnace black, carbon black, activated carbon and meso phase carbon.

8. An electrode structure for a fuel cell, comprising:
a flat carrier, selected from a polymer electrolyte membrane and a gas-permeable electrically conductive substrate; and
a catalytic converter arranged on at least one side of the flat carrier; and
a coating that includes:
a supported catalyst material that includes:
a porous, electrically conductive carbon-based carrier material; and
catalytic structures including a first catalytic structure and a second catalytic structure on the carbon-based carrier material, the first catalytic structure and the second catalytic structure each having a multilayer structure that includes:
a center region including an anchor covalently bonded to a portion of the carbon-based carrier material, and a core layer of an electrically conductive bulk material on and around the anchor, the core layer in direct contact with the carbon-based carrier material, the center region of the first catalytic structure being spatially separated from center region of the second catalytic structure, and
a surface layer of a catalytically active noble metal or an alloy thereof on the core layer, the surface layer comprising crystal edges and crystal corners, wherein a local protective layer selectively covers the crystal edges or the crystal edges and the crystal corners.

9. The electrode structure of claim 8 , wherein a bonding agent layer comprising tungsten, is arranged between the core layer and the surface layer of each of the first catalytic structure and the second catalytic structure.

10. The catalyst material of claim 6 , wherein the porous particulate structure includes spheroids or fibers.

11. The catalyst material of claim 1 , wherein the protective layer of each of the first catalytic structure and the second catalytic structure comprises at least one oxide, carbide, nitride, or gold.

12. The catalyst material of claim 11 , wherein the protective layer of each of the first catalytic structure and the second catalytic structure comprises alumina, boron oxide, silicon oxide, boron carbide, silicon carbide, tungsten carbide, boron nitride, aluminum nitride, silicon nitride, titanium nitride, or gold.

13. The catalyst material of claim 6 , wherein the porous particulate structure of each of the first catalytic structure and the second catalytic structure includes nanostructures selected from the group consisting of carbon nanotubes, carbon nanorods, carbon nanofibers, and carbon nanobands.

14. The catalyst material of claim 1 , wherein the catalytically active noble metal or alloy comprises ruthenium, rhodium, palladium, osmium, iridium, platinum, or combinations thereof.

15. The catalyst material of claim 14 , wherein the catalytically active noble metal or alloy comprises platinum.

16. The catalyst material of claim 1 , wherein the local protective layer covers only the crystal edges.

17. The catalyst material of claim 1 , wherein the local protective layer covers only the crystal edges and the crystal corners.

18. The electrode structure of claim 8 , wherein the local protective layer covers only the crystal edges.

19. The electrode structure of claim 8 , wherein the local protective layer covers only the crystal edges and the crystal corners.

Assignees

• Volkswagen Ag
• Audi Ag

Inventors

• Schladt Thomas
• Graf Tanja

Classifications

• H01M4/9058

  of noble metals or noble-metal based alloys · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M4/8867

  Vapour deposition · CPC title

• H01M4/8668

  Binders · CPC title

• H01M4/8605

  Porous electrodes · CPC title