Method for startup of a gas phase polymerization reactor

Patent metadata

Field	Value
Publication number	US-10787526-B2
Application number	US-201815946870-A
Country	US
Kind code	B2
Filing date	Apr 6, 2018
Priority date	Apr 6, 2018
Publication date	Sep 29, 2020
Grant date	Sep 29, 2020

Abstract

A gas phase polymerization process is described that includes contacting a polymer seed bed with a desiccant. The gas phase polymerization process further includes introducing a polymer seed bed into a gas phase polymerization reactor, contacting the polymer seed bed with a desiccant, and introducing a polymerization catalyst into the gas phase polymerization reactor. Also described is a gas phase polymerization process in accordance with the present disclosure that includes subjecting a polymer seed bed to startup conditions in a gas phase polymerization reactor, monitoring a moisture content of a vapor in contact with the polymer seed bed, and introducing a desiccant into the gas phase polymerization reactor to maintain the moisture content below a desired moisture content, to reduce a moisture content that is above a desired moisture content, or both.

First claim

What is claimed is:

1. A gas phase polymerization process comprising:
contacting a polymer seed bed with a desiccant, wherein the desiccant comprises silica gel, alumina, solid super acid, molecular sieve, or a combination thereof, and wherein the desiccant has a particle size distribution (PSD), an average particle size, a porosity, a sphericity, or a combination thereof that is substantially equal to that of a polymerization catalyst used in the gas phase polymerization process.

2. The gas phase polymerization process of claim 1 , further comprising purging the polymer seed bed, contacting the polymer seed bed with a chemical scavenger, or both.

3. The gas phase polymerization process of claim 2 , wherein the purging of the polymer seed bed, the contacting of the polymer seed bed with the chemical scavenger, or both are performed prior to the contacting of the polymer seed bed with the desiccant, concurrently with the contacting of the polymer seed bed with the desiccant, subsequent to the contacting of the polymer seed bed with the desiccant, or a combination thereof.

4. The gas phase polymerization process of claim 3 further comprising monitoring a moisture content of a vapor in contact with the polymer seed bed, and contacting the polymer seed bed with the desiccant when the moisture content is greater than or equal to a desired moisture content.

5. The gas phase polymerization process of claim 2 , wherein the purging of the polymer seed bed, the contacting of the polymer seed bed with the chemical scavenger, or both are performed prior to introducing the polymer seed bed into a gas phase polymerization reactor, concurrently with introducing the polymer seed bed into a gas phase polymerization reactor, subsequent to introducing the polymer seed bed into a gas phase polymerization reactor, or a combination thereof.

6. The gas phase polymerization process of claim 1 , wherein the polymer seed bed is contacted with the desiccant prior to introducing the polymer seed bed into a gas phase polymerization reactor, concurrently with introducing the polymer seed bed into a gas phase polymerization reactor, subsequent to introducing the polymer seed bed into a gas phase polymerization reactor, or a combination thereof.

7. The gas phase polymerization process of claim 6 further comprising introducing a polymerization catalyst into the gas phase polymerization reactor, wherein the polymerization catalyst is introduced into the gas phase polymerization reactor prior to introducing the desiccant into the gas phase polymerization reactor, concurrently with introducing the desiccant into the gas phase polymerization reactor, subsequent to introducing the desiccant into the gas phase polymerization reactor, or a combination thereof.

8. The gas phase polymerization process of claim 7 further comprising, after a startup time has elapsed, continuously introducing reactants into the gas phase polymerization reactor under polymerization conditions to produce a polymer product, wherein the startup time is indicated as the time between introducing the polymerization catalyst into the gas phase polymerization reactor and a time at which a temperature of a fluidizing gas at an inlet of the gas phase polymerization reactor is less than a temperature of the polymer seed bed.

9. The gas phase polymerization process of claim 1 , wherein the desiccant has an average particle size in the range of from about 30 μm to about 300 μm, a porosity in the range of from about 20% to about 95%, a sphericity in the range of from about 0.5 to about 1.0, or a combination thereof.

10. A gas phase polymerization process comprising:
introducing a polymer seed bed into a gas phase polymerization reactor;
contacting the polymer seed bed with a desiccant, wherein the desiccant comprises silica gel, alumina, solid super acid, molecular sieve, or a combination thereof, and wherein the desiccant has a particle size distribution (PSD), an average particle size, a porosity, a sphericity, or a combination thereof that is substantially equal to that of the polymerization catalyst; and
introducing a polymerization catalyst into the gas phase polymerization reactor.

11. The gas phase polymerization process of claim 10 further comprising monitoring a moisture content within the gas phase polymerization reactor and introducing the polymerization catalyst into the gas phase polymerization reactor when the moisture content is at or below a desired moisture content.

12. The gas phase polymerization process of claim 10 further comprising purging the polymer seed bed with an inert gas prior to introducing the polymer seed bed into the gas phase polymerization reactor, concurrently with introducing the polymer seed bed into the gas phase polymerization reactor, subsequent to introducing the polymer seed bed into the gas phase polymerization reactor, or a combination thereof.

13. The gas phase polymerization process of claim 10 further comprising introducing a chemical scavenger into the gas phase polymerization reactor.

14. The gas phase polymerization process of claim 13 further comprising monitoring a moisture content of the gas phase polymerization reactor, and introducing the polymerization catalyst into the gas phase polymerization reactor subsequent to the introduction of the chemical scavenger thereto and when the moisture content is less than or equal to a desired moisture content.

15. The gas phase polymerization process of claim 10 ,
wherein the polymer seed bed is contacted with the desiccant prior to introduction of the polymer seed bed into the gas phase polymerization reactor, concurrently with the introduction of the polymer seed bed into the gas phase polymerization reactor, subsequent to the introduction of the polymer seed bed into the gas phase polymerization reactor, or a combination thereof;
wherein the polymerization catalyst is introduced into the gas phase polymerization reactor prior to introducing the desiccant into the gas phase polymerization reactor, concurrently with introducing the desiccant into the gas phase polymerization reactor, subsequent to introducing the desiccant into the gas phase polymerization reactor, or a combination thereof;
or a combination thereof.

16. The gas phase polymerization process of claim 10 further comprising continuously introducing reactants into the gas phase polymerization reactor under polymerization conditions to produce a polymer product, wherein the reactants comprise ethylene and optionally other olefins and wherein the polymer product comprises polyethylene (PE).

17. A gas phase polymerization process comprising:
subjecting a polymer seed bed to startup conditions in a gas phase polymerization reactor;
monitoring a moisture content of a vapor in contact with the polymer seed bed; and
introducing a desiccant into the gas phase polymerization reactor to maintain the moisture content below a desired moisture content, to reduce a moisture content that is above a desired moisture content, or both,
wherein the desiccant comprises silica gel, alumina, solid super acid, molecular sieve, or a combination thereof, and wherein the desiccant has a particle size distribution (PSD), an average particle size, a porosity, a sphericity, or a combination thereof that is substantially equal to that of a polymerization catalyst used in the gas phase polymerization process.

18. The gas phase polymerization process of claim 10 , wherein the desiccant has an average particle size in the range of from about 30 μm to about 300 μm.

19. The gas phase pol

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Hendrickson Greg G
• Lowell Jeff S
• Schwerdtfeger Eric D

Classifications

• B01J19/002 Primary

  Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions · CPC title

• C08F10/06

  Propene · CPC title

• C08F2/34 Primary

  Polymerisation in gaseous state · CPC title

• C08F10/02

  Ethene · CPC title

• B01J8/008

  Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction (B01J8/0285, B01J8/067, B01J8/087, B01J8/1836 take precedence) · CPC title