Resin mixture based on epoxy(meth)acrylate resin, and the use thereof
US-9994655-B2 · Jun 12, 2018 · US
US10787395B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10787395-B2 |
| Application number | US-201716330121-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 20, 2017 |
| Priority date | Sep 26, 2016 |
| Publication date | Sep 29, 2020 |
| Grant date | Sep 29, 2020 |
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A two-component mortar mass includes a resin component (A), which contains as curable constituent at least one radically curable resin, and a curing component (B) which contains a curing agent for the radically curable resin of the resin component (A), wherein the resin component (A) and/or the curing component (B) contain(s) as further constituent at least one inorganic additive. The inorganic additive contains a transition aluminum oxide having an average particle size d50 of at least 7.0 μm and a pore diameter of 4.0 nm to 30.0 nm.
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The invention claimed is: 1. A two-component mortar compound, comprising: a resin component (A), which, as the curable ingredient, contains at least a free-radical-curing resin, and a hardener component (B), which contains a hardening agent for the free-radical-curing resin of the resin component (A), wherein the resin component (A) and/or the hardener component (B) contains at least one inorganic additive as a further ingredient, wherein the at least one inorganic additive comprises a transition alumina having a mean particle size d50 of at least 7.0 μm and a pore diameter of 4 nm to 30 nm. 2. The two-component mortar compound according to claim 1 , wherein the at least one inorganic additive comprises at least the transition alumina as well as one or more further substances, which are selected from the group consisting of inorganic fillers, hydraulically binding compounds, polycondensable inorganic compounds, modifiers and mixtures thereof. 3. The two-component mortar compound according to claim 1 , wherein the at least one inorganic additive comprises a filler. 4. The two-component mortar compound according to claim 1 , wherein the at least one inorganic additive comprises a hydraulically binding or polycondensable inorganic compound. 5. The two-component mortar compound according to claim 1 , wherein the at least one inorganic additive further comprises an inorganic modifier. 6. The two-component mortar compound according to claim 1 , wherein the transition alumina is present in the mortar compound in a proportion of 0.5 to 10 percent by volume. 7. The two-component mortar compound according to claim 1 , wherein the mean particle size d50 of the transition alumina is at least 12.0 μm. 8. The two-component mortar compound according to claim 1 , wherein the polymerization shrinkage of the mortar compound is less than 3.1%. 9. The two-component mortar compound according to claim 1 , wherein the transition alumina has a mean particle size d50 of up to 120 μm. 10. The two-component mortar compound according to claim 1 , wherein the transition alumina has a pore diameter in a range of 4.5 nm to 20 nm. 11. The two-component mortar compound according to claim 1 , wherein the at least one inorganic additive, including the transition alumina, are present in the mortar compound in a proportion of 50 to 80 percent by weight relative to the total weight of the compound. 12. The two-component mortar compound according to claim 1 , wherein the free-radical-curing resin comprises a urethane (meth)acrylate resin and/or a (meth)acrylate-modified epoxy resin. 13. The two-component mortar compound according to claim 1 , wherein the resin component (A), comprises at least one polymerization inhibitor which is a phenolic compound, and optionally, a non-phenolic compound selected from the group consisting of stable free radicals, phenothiazines and mixtures thereof. 14. The mortar compound according to claim 13 , wherein the at least one polymerization inhibitor comprises a phenolic compound, which is able to bind to the transition alumina. 15. The two-component mortar compound according to claim 1 , wherein the hardener component (B) is anhydrous. 16. The two-component mortar compound according to claim 1 , wherein the resin component (A) comprises: a free-radical-curing resin in a proportion of 5 to 45 wt %; a reactive diluent in a proportion of 0 to 25 wt %; an accelerator in a proportion of 0 to 3 wt %; a polymerization inhibitor in a proportion of 0 to 5 wt %; and at least one inorganic additive in a proportion of 50 to 80 wt %; wherein the sum of all proportions adds up to 100 percent by weight, and wherein the inorganic additive comprises at least one transition alumina having a mean particle size d50 of at least 7 μm and a pore diameter of 4 nm to 30 nm. 17. The two-component mortar compound according to claim 1 , wherein the mortar compound obtained by mixing the resin component (A) and the hardener component (B) comprises: a free-radical-curing resin in a proportion of 5 to 50 wt %; a reactive diluent in a proportion of 0 to 25 wt %; an organic peroxide in a proportion of 0.5 to 5 wt %, a polymerization accelerator in a proportion of 0 to 0.5 wt %; at least one transition alumina in a proportion of 2 to 20 percent by weight; further inorganic additives in a proportion of 10 to 78 wt %; and water in a proportion of 0 to 10 wt %; wherein the sum of all proportions of the compound adds up to 100 percent by weight. 18. The two-component mortar compound according to claim 3 , wherein the tiller is selected from the group consisting of quartz, glass, corundum, porcelain, stoneware, heavy spar, light spar, gypsum, talc, chalk and mixtures thereof. 19. A method for chemical fastening of a structural part, comprising: contacting said structural part with the two-component mortar compound according to claim 1 , wherein said structural part is a threaded anchor rod, a rebar, a threaded sleeve or a screw in a drilled hole which is present in a mineral substrate.
Two or more component mortars · CPC title
Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title
Mineral polymers other than those of the Davidovits type, e.g. from a reaction mixture containing waterglass · CPC title
Acrylates · CPC title
Polyacrylates; Polymethacrylates · CPC title
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