Molecular sieve catalyst compositions, catalyst composites, systems, and methods

Patent metadata

Field	Value
Publication number	US-10786808-B2
Application number	US-201715683905-A
Country	US
Kind code	B2
Filing date	Aug 23, 2017
Priority date	Jun 18, 2014
Publication date	Sep 29, 2020
Grant date	Sep 29, 2020

Abstract

Described is a selective catalytic reduction material comprising a spherical particle including an agglomeration of crystals of a molecular sieve. The catalyst is a crystalline material that is effective to catalyze the selective catalytic reduction of nitrogen oxides in the presence of a reductant at temperatures between 200° C. and 600° C. A method for selectively reducing nitrogen oxides and an exhaust gas treatment system are also described.

First claim

What is claimed is:

1. A system for treating exhaust gas from a lean burn engine containing NO x , the system comprising:
a selective catalytic reduction (SCR) material comprising a spherical particle having a median particle size of about 0.5 to about 5 microns, comprising an agglomeration of crystals of a metal-promoted molecular sieve,
wherein the crystals have approximately the same crystal size, wherein the same crystal size is selected from the range of about 1 to about 250 nm, and
wherein the metal-promoted molecular sieve has a structure type selected from the group consisting of AEI, AFT, AFX, CHA, EAB, EMT, ERI, FAU, GME, JSR, KFI, LEV, LTL, LTN, MOZ, MSO, MWW, OFF, SAS, SAT, SAV, SBS, SBT, SFW, SSF, SZR, TSC, WEN, and combinations thereof; and
at least one other exhaust gas treatment component.

2. The system of claim 1 , wherein the least one other exhaust gas treatment component is selected from a soot filter, a diesel oxidation catalyst, an ammonia oxidation catalyst, and combinations thereof.

3. The system of claim 2 , wherein the system comprises a soot filter, and wherein the soot filter is a wall-flow filter substrate upon which the SCR material is disposed.

4. The system of claim 2 , wherein the system comprises a diesel oxidation catalyst located upstream of the SCR material.

5. The system of claim 2 , wherein the system comprises an ammonia oxidation catalyst located downstream of the SCR material.

6. The system of claim 5 , wherein the ammonia oxidation catalyst comprises a platinum group metal selected from platinum, palladium, rhodium, and combinations thereof.

7. The system of claim 2 , wherein the system comprises a soot filter and a diesel oxidation catalyst located upstream of the SCR material.

8. The system of claim 1 , wherein the metal-promoted molecular sieve has a structure type selected from AEI, AFT, AFX, CHA, EAB, ERI, KFI, LEV, SAS, SAT, and SAV.

9. The system of claim 1 , wherein the metal-promoted molecular sieve has a structure type selected from AEI, CHA, and AFX.

10. The system of claim 9 , wherein the metal-promoted molecular sieve has the CHA structure type.

11. The system of claim 10 , wherein the metal-promoted molecular sieve having the CHA structure type has a silica to alumina ratio in the range of 10 to 100.

12. The system of claim 10 , wherein the metal-promoted molecular sieve having the CHA structure type is selected from an aluminosilicate zeolite, a borosilicate, a gallosilicate, a SAPO, an AlPO, a MeAPSO, and a MeAPO.

13. The system of claim 10 , wherein the metal-promoted molecular sieve having the CHA structure type is selected from the group consisting of SSZ-13, SSZ-62, natural chabazite, zeolite K-G, Linde D, Linde R, LZ-218, LZ-235, LZ-236, ZK-14, SAPO-34, SAPO-44, SAPO-47, and ZYT-6.

14. The system of claim 13 , wherein the metal-promoted molecular sieve having the CHA structure type is selected from SSZ-13 and SSZ-62.

15. The system of claim 1 , wherein the metal-promoted molecular sieve is promoted with a metal selected from Cu, Fe, Co, Ni, La, Ce, Mn, V, Ag, and combinations thereof.

16. The system of claim 15 , wherein the metal-promoted molecular sieve is promoted with a metal selected from Cu, Fe, and combinations thereof.

17. The system of claim 1 , wherein the SCR material is effective to catalyze the selective catalytic reduction of nitrogen oxides in the presence of a reductant at temperatures between 200° C. and 600° C.

18. The system of claim 1 , wherein the metal-promoted molecular sieve comprises metal in an amount in a range of about 0.1 to about 10 wt. % on an oxide basis.

19. The system of claim 1 , wherein the spherical particle has a median particle size in the range of about 1.2 to about 3.5 microns.

20. The system of claim 1 , wherein the crystals have a crystal size in the range of about 100 to about 250 nm.

21. The system of claim 1 , wherein the SCR material is in the form of a washcoat layer deposited on a substrate.

22. The system of claim 1 , wherein the metal-promoted molecular sieve comprises a zeolitic framework material of silicon and aluminum atoms, wherein a fraction of the silicon atoms are isomorphously substituted with a tetravalent metal.

23. The system of claim 22 , wherein the tetravalent metal is selected from the group consisting of Ti, Zr, Hf, Ge, and combinations thereof.

24. The system of claim 23 , wherein the tetravalent metal comprises Ti.

Assignees

• Basf Corp

Inventors

• Trukhan Natalia
• Müller Ulrich
• Breen Michael
• Slawski Barbara
• Fu Qi
• Mohanan Jaya L
• Kraus Martin W
• Moini Ahmad
• Yang Xiaofan
• Hochmuth John K

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/10

  Infrared [IR] · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/45

  Nanoparticles · CPC title