Perovskite compound, thin layer comprising the perovskite compound, and optoelectronic device comprising the perovskite compound

Patent metadata

Field	Value
Publication number	US-10784449-B2
Application number	US-201715485080-A
Country	US
Kind code	B2
Filing date	Apr 11, 2017
Priority date	Apr 11, 2016
Publication date	Sep 22, 2020
Grant date	Sep 22, 2020

Abstract

A perovskite compound represented by Formula 1, a thin layer including the perovskite compound, and an optoelectronic device including the perovskite compound:

[A][B 1 n B 2 (1-n) ][X] 3 .  Formula 1

In Formula 1, A may be at least one selected from a monovalent organic cation, monovalent inorganic cation, and combinations thereof; B 1 may be a thulium (II) (Tm 2+ ) ion; B 2 may be at least one divalent inorganic cation, where B 2 is free of (e.g., does not include) Tm 2+ ; n may be a real number that satisfies 0<n≤1; and X may be at least one monovalent anion.

First claim

What is claimed is:

1. A perovskite compound represented by Formula 1:
[A][B 1 n B 2 (1-n) ][X] 3 ,  Formula 1

wherein the perovskite compound is an ABX 3 perovskite, and in Formula 1,
A is at least one selected from a monovalent organic cation, a monovalent inorganic cation, and combinations thereof;
B 1 is a Tm 2+ ion;
B 2 is at least one selected from a divalent inorganic cation, where B 2 is free of Tm 2+ ion;
n is a real number that satisfies 0<n≤1; and
X is at least one monovalent anion.

2. The perovskite compound of claim 1 , wherein A is (R 1 R 2 R 3 R 4 N) + , (R 1 R 2 R 3 R 4 P) + , (R 1 R 2 R 3 R 4 As) + , (R 1 R 2 R 3 R 4 Sb) + , (R 1 R 2 N═C(R 3 )—NR 4 R 5 ) + , a monovalent cation of a substituted or unsubstituted nitrogen-containing 5-membered ring, a monovalent cation of a substituted or unsubstituted nitrogen-containing 6-membered ring, Li + , Na + , K + , Rb + , Cs + , Fr + , or a combination thereof,
wherein R 1 to R 5 , a substituent of the monovalent cation of the substituted nitrogen-containing 5-membered ring, and a substituent of the monovalent cation of the substituted nitrogen-containing 6-membered ring are each independently selected from a hydrogen atom, a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a substituted or unsubstituted C 1 -C 60 alkyl group, a substituted or unsubstituted C 2 -C 60 alkenyl group, a substituted or unsubstituted C 2 -C 60 alkynyl group, a substituted or unsubstituted C 1 -C 60 alkoxy group, a substituted or unsubstituted C 6 -C 60 aryl group, and —N(Q 1 )(Q 2 )(Q 3 ), and
wherein Q 1 to Q 3 are each independently selected from a hydrogen atom, a deuterium atom, a hydroxyl group, a C 1 -C 60 alkyl group, a C 2 -C 60 alkenyl group, a C 2 -C 60 alkynyl group, a C 1 -C 60 alkoxy group, and a C 6 -C 60 aryl group.

3. The perovskite compound of claim 1 , wherein A is (R 1 R 2 R 3 R 4 N) + , (R 1 R 2 R 3 R 4 P) + , (R 1 R 2 R 3 R 4 As) + , (R 1 R 2 R 3 R 4 Sb) + , or a combination thereof,
wherein R 1 to R 4 are each independently selected from a hydrogen atom, a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a C 1 -C 20 alkyl group, a C 1 -C 20 alkoxy group, and —N(Q 1 )(Q 2 )(Q 3 ), and
wherein Q 1 to Q 3 are each independently selected from a hydrogen atom, a deuterium atom, a hydroxyl group, a C 1 -C 20 alkyl group, and a C 1 -C 20 alkoxy group.

4. The perovskite compound of claim 1 , wherein A is (CH 3 NH 3 ) + , (C 2 H 6 PH 2 ) + , (CH 3 AsH 3 ) + , (NH 4 ) + , (CH 3 SbH 3 ) + , (PH 4 ) + , (PF 4 ) + , (CH 3 PH 3 ) + , (SbH 4 ) + , (AsH 4 ) + , (NCl 4 ) + , (NH 3 OH) + , (NH 3 NH 2 ) + , (CH(NH 2 ) 2 ) + , (C 3 N 2 H 5 ) + , ((CH 3 ) 2 NH 2 ) + , (NC 4 H 8 ) + , ((CH 3 CH 2 )NH 3 ) + , ((NH 2 ) 3 C) + , or a combination thereof.

5. The perovskite compound of claim 1 , wherein B 2 is a divalent cation of a rare earth metal, a divalent cation of an alkaline earth metal, or a combination thereof.

6. The perovskite compound of claim 1 , wherein B 2 is La 2+ , Ce 2+ , Pr 2+ , Nd 2+ , Pm 2+ , Eu 2+ , Gd 2+ , Tb 2+ , Ho 2+ , Er 2+ , Yb 2+ , Lu 2+ , Be 2+ , Mg 2+ , Ca 2+ , Sr 2+ , Ba 2+ , Ra 2+ , or a combination thereof.

7. The perovskite compound of claim 1 , wherein B 2 is Eu 2+ .

8. The perovskite compound of claim 1 , wherein n is a real number that satisfies 0.05≤n≤0.4.

9. The perovskite compound of claim 1 , wherein:
n is a real number that satisfies 0.01≤n≤0.14, and the perovskite compound emits blue light;
n is a real number that satisfies 0.15≤n≤0.34, and the perovskite compound emits green light; or
n is a real number that satisfies 0.35≤n≤0.5, and the perovskite compound emits red light.

10. The perovskite compound of claim 1 , wherein X is at least one halide anion.

11. The perovskite compound of claim 1 , wherein X is —I.

12. A thin layer comprising the perovskite compound of claim 1 .

13. An optoelectronic device comprising the perovskite compound of claim 1 .

14. The optoelectronic device of claim 13 , wherein the optoelectronic device is a photovoltaic device, a photodiode, a phototransistor, a photomultiplier, a photo-resistor, a photo-detector, a light sensitive detector, a solid-state triode, a battery electrode, a light-emitting device, a light-emitting diode, a transistor, a solar battery, a laser, or a diode injection laser.

15. The optoelectronic device of claim 13 , wherein the optoelectronic device is a light-emitting diode, and the light-emitting diode comprises:
a first electrode;
a second electrode facing the first electrode; and
an emission layer between the first electrode and the second electrode,
wherein the emission layer comprises the perovskite compound.

16. The optoelectronic device of claim 15 , further comprising at least one selected from a hole transport region between the first electrode and the emission layer and an electron transport region between the emission layer and the second electrode, wherein the at least one selected from the hole transport region and the electron transport region comprises a metal halide, a metal oxide, a metal chalcogenide, a metal selenide, or a combination thereof.

17. The optoelectronic device of claim 15 , further comprising at least one selected from a hole transport region between the first electrode and the emission layer and an electron transport region between the emission layer and the second electrode, wherein the at least one selected from the hole transport region and electron transport region comprises a group IV compound semiconductor, a group III-V semiconductor, a group II-VI semiconductor, a group I-VII semiconductor, a group IV-VI semiconductor, a group V-VI semiconductor, a group II-V semiconductor, a ternary or quaternary semiconductor, or a combination thereof.

18. The optoelectronic device of claim 15 , further comprising at least one selected from a hole transport region between the first electrode and the emission layer and an electron transport region between the emission layer and the second electrode,
wherein the hole transport region comprises an amine-based compound; or
the electron transport region comprises a metal-free compound that comprises at least one π electron deficient nitrogen-containing ring.

19. The optoelectronic device of claim 15 , further comprising an electron transport region between the emission layer and the second electrode, wherein the electron transport region comprises an electron injection layer, wherein the electron injection layer comprises an alkali metal, an alkaline earth metal, a rare earth metal, an alkali metal compound, an alkaline earth metal compound, a rare earth metal compound, an alkali metal complex, an alkaline earth metal complex, a rare earth metal complex, or a combination thereof.

20. The optoelectronic device of claim 13 , wherein the optoelectronic device is a light-emitting diode, and the light-emitting diode comprises:
a first electrode;
a second electrode facing the first electrode;
an emission layer between the first electrode and the second electrode; and
at least one selected from a hole transport region between the first electrode and the emission layer, and an electron transport region between the emission layer and the second electrode,
wherein at least one selected from the hole transport region and the electron transport region comprises the perovskite compound.

Assignees

• Samsung Display Co Ltd

Inventors

• Kim Dongchan
• Cho Yoonhyeung
• Kim Wonjong
• Kim Eungdo
• Seo Dongkyu
• Lee Jonghyuk
• Lee Jihye
• Yim Sanghoon
• Han Wonsuk

Classifications

• Y02E10/549

  Organic PV cells · CPC title

• H10H20/822

  Materials of the light-emitting regions · CPC title

• C09K2211/18

  Metal complexes · CPC title

• C09K11/06 Primary

  containing organic luminescent materials · CPC title

• C07F5/00

  Compounds containing elements of Groups 3 or 13 of the Periodic Table · CPC title