Cement solidification device for waste and method therefor, and zero-liquid discharge air pollution control system and method therefor

Patent metadata

Field	Value
Publication number	US-10780473-B2
Application number	US-201615552688-A
Country	US
Kind code	B2
Filing date	Feb 25, 2016
Priority date	Feb 27, 2015
Publication date	Sep 22, 2020
Grant date	Sep 22, 2020

Abstract

A cement solidification device for waste includes a slurrying vessel 14 that dissolves and slurries waste 11 containing harmful substances and deliquescent compounds in solvent water 12 to obtain slurried material 13; an iron-based additive supply unit 16 that adds an iron-based additive 15 to the slurrying vessel 14; a cement kneading vessel 20 that adds a cement solidifying agent 17 from a cement-solidifying agent supply unit 18 to the slurried material 13 in which the iron-based additive 15 is mixed to obtain a cement kneaded product 19; and a cement solidification unit 22 that cures the cement kneaded product 19 to form a cement solidified product 21.

First claim

The invention claimed is:

1. A zero-liquid discharge air pollution control system, comprising:
a boiler that combusts fuel;
a heat recovery device that is provided on a main flue gas duct discharging a boiler flue gas from the boiler and is configured to recover heat of the boiler flue gas;
a precipitator that is configured to remove soot dust in the boiler flue gas after the heat recovery device;
a desulfurization device that is configured to remove sulfur oxides contained in the boiler flue gas after the precipitator with a desulfurization absorbent;
a solid-liquid separator that is configured to remove solid material from desulfurized effluent discharged from the desulfurization device;
a spray drying device that is configured to spray separated water from the solid-liquid separator;
a gas introduction line that is configured to introduce into the spray drying device a drying gas for evaporating and drying the separated water;
a discharged-gas supply line that is configured to return to the main flue gas duct a discharged gas after evaporating and drying the separated water by the spray drying device;
an evaporated salt separator that is provided on the discharged-gas supply line and is configured to separate an evaporated salt containing harmful substances and deliquescent compounds in the discharged gas;
a slurrying vessel that is configured to dissolve and slurry the evaporated salt in solvent water to obtain slurried material;
an evaporated salt discharge line that is configured to supply the evaporated salt from the evaporated salt separator to the slurrying vessel;
a cement kneading vessel that is provided on a downstream side of the slurrying vessel and is configured to add a cement solidifying agent to the slurried material introduced from the slurrying vessel and to knead the resulted material to obtain a cement kneaded product;
an iron-based additive supply unit that is connected to either or both of the slurrying vessel and the cement kneading vessel and is configured to add an iron-based additive to either one or both of the slurried material in the slurrying vessel and the cement kneaded product in the cement kneading vessel; and
a cement solidification unit that is provided on a downstream side of the cement kneading vessel and is configured to cure the cement kneaded product introduced from the cement kneading vessel to form a cement solidified product having a compressive strength of 200 kg/cm 2 or greater.

2. The cement solidification device for waste according to claim 1 , wherein the iron-based additive is an inorganic ferrous salt.

3. The zero-liquid discharge air pollution control system according to claim 1 , wherein the solvent water is a part of the separated water that has been separated by the solid-liquid separator.

4. The zero-liquid discharge air pollution control system according to claim 1 , wherein fly ash is added to the cement kneading vessel together with the cement solidifying agent.

5. The zero-liquid discharge air pollution control system according to claim 1 , wherein a dry additive is added to a branched gas.

6. The zero-liquid discharge air pollution control system according to claim 5 , wherein after an evaporated salt to which the dry additive is added is separated by the evaporated salt separator, a part of the evaporated salt is added to the branched gas.

7. The zero-liquid discharge air pollution control system according to claim 1 , further comprising:
a dissolved-component measuring device that measures dissolved components in the separated water that has been separated by the solid-liquid separator, wherein
an addition amount of either one or both of the iron-based additive and the cement solidifying agent is adjusted, depending on a value of the measured dissolved components.

8. The zero-liquid discharge air pollution control system according to claim 7 , further comprising:
an elution-component measuring device that measures elution components in the cement solidified product, wherein
an addition amount of either one or both of the iron-based additive and the cement solidifying agent is adjusted depending on a value of the measured elution components.

9. The zero-liquid discharge air pollution control system according to claim 1 , further comprising:
an oxidation-reduction potential meter that measures an oxidation-reduction potential value of the desulfurization absorbent in the desulfurization device, wherein
an oxidation-reduction potential is adjusted to a range of 100 to 200 mV.

10. A zero-liquid discharge air pollution control method including recovering heat of a boiler flue gas from a boiler, removing sulfur oxides contained in the boiler flue gas with a desulfurization absorbent, removing solid material from desulfurized effluent discharged at the removing of sulfur oxides, and spraying separated water that has been separated at the removing of the solid material and evaporating and drying the separated water with a drying gas, the zero-liquid discharge air pollution control method comprising:
separating, into solid and gas, an evaporated salt containing harmful substances and deliquescent compounds in discharged gas after the spraying and the drying;
dissolving and slurrying waste that contains heavy metals and deliquescent compounds in solvent water, optionally with an iron-based additive, to obtain slurried material;
adding a cement solidifying agent to the slurried material, optionally with an iron-based additive, followed by kneading to obtain a cement kneaded product containing iron-based material; and
curing the cement kneaded product to form a cement solidified product having a compressive strength of 200 kg/cm 2 or greater,
wherein the waste is evaporated waste.

11. The zero-liquid discharge air pollution control method according to claim 10 , wherein the solvent water is a part of the separated water that has been separated from the desulfurized effluent.

12. The zero-liquid discharge air pollution control method according to claim 10 , wherein fly ash is added together with the cement solidifying agent to obtain the cement kneaded product.

13. The zero-liquid discharge air pollution control method according to claim 10 , wherein a dry additive is added to a branched gas.

14. The zero-liquid discharge air pollution control method according to claim 13 , wherein after an evaporated salt to which the dry additive is added is separated by the evaporated salt separator, a part of the evaporated salt is added to the branched gas.

15. The zero-liquid discharge air pollution control method according to claim 10 , wherein dissolved components in the separated water that has been separated by the solid-liquid separator are measured, and an addition amount of either one or both of the iron-based additive and the cement solidifying agent is adjusted depending on a value of the measured dissolved components.

16. The zero-liquid discharge air pollution control method according to claim 15 , wherein elution components in the cement solidified product are measured, and an addition amount of either one or both of the iron-based additive and the cement solidifying agent is adjusted depending on a value of the measured elution components.

17. The zero-liquid discharge air pollution control method according to claim 10 , wherein an oxidation-reduction potential value of the desulfurization absorbent in the desulfurization device is measured, and the oxidation-reduction potential is adjusted to a range of 100 to 200 mV.

Assignees

• Mitsubishi Hitachi Power Sys

Inventors

• Kamiyama Naoyuki
• Kagawa Seiji
• Ushiku Tetsu
• Sugita Satoru
• Fukuda Toshihiro

Classifications

• B09B3/27 Primary

  Binding by sodium silicate, e.g. cement or water glass · CPC title

• B09B3/70

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title

• B01D53/50

  Sulfur oxides (B01D53/60 takes precedence) · CPC title

• C02F1/12 Primary

  Spray evaporation · CPC title

• B09B2101/30

  Incineration ashes · CPC title