Process for preparing a molding comprising zinc and a titanium-containing zeolite

Patent metadata

Field	Value
Publication number	US-10780432-B2
Application number	US-201816470834-A
Country	US
Kind code	B2
Filing date	Jan 18, 2018
Priority date	Jan 18, 2017
Publication date	Sep 22, 2020
Grant date	Sep 22, 2020

Abstract

A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).

First claim

The invention claimed is:

1. A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, the process comprising:
(i) preparing a molding comprising a titanium-containing zeolitic material having framework type MWW;
(ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i);
(iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension of from 100 to 200° C., thereby obtaining an aqueous suspension comprising a molding comprising zinc and the titanium-containing zeolitic material having framework type MWW; and
(iv) separating the molding comprising zinc and the titanium-containing zeolitic material having framework type MWW from the liquid phase of the aqueous suspension obtained in (iii).

2. The process of claim 1 , wherein the molding prepared in (i) comprises the titanium-containing zeolitic material having framework type MWW and a binder, wherein in the molding prepared in (i), a weight ratio of the titanium-containing zeolitic material having framework type MWW relative to the binder is from 1:1 to 9:1.

3. The process of claim 1 , wherein the molding prepared in (i) has at least one of the following characteristics (1) to (3):
(1) a BET specific surface area of at least 300 m 2 /g;
(2) a pore volume of at least 0.9 mL/g; and
(3) a mechanical strength of from 5 to 10 N.

4. The process of claim 1 , wherein at least 99 weight % of the titanium-containing zeolitic material having framework type MWW comprised in the molding prepared in (i) consists of Ti, Si, O, and H.

5. The process of claim 4 , wherein the titanium-containing zeolitic material having framework type MWW has a titanium content, calculated as elemental titanium, of from 0.1 to 5 weight %, based on a total weight of the titanium-containing zeolitic material having framework type MWW.

6. The process of claim 1 , wherein the titanium-containing zeolitic material having framework type MWW comprised in the molding prepared in (i) is in the form of a powder having a particle size distribution Dv10 value of from 1 to 10 micrometer and a Dv90 value of from 12 to 200 micrometer.

7. The process of claim 6 , wherein the Dv10 value is from 1.5 to 10 micrometer, a Dv50 value is from 5 to 50 micrometer, and the Dv90 value is from 12 to 90 micrometer.

8. The process of claim 1 , wherein in the aqueous suspension prepared in (ii), a weight ratio of zinc comprised in the zinc source relative to the titanium-containing zeolitic material having framework type MWW comprised in the molding is from 0.005:1 to 0.1:1.

9. The process of claim 1 , wherein in the aqueous suspension prepared in (ii), a weight ratio of the titanium-containing zeolitic material having framework type MWW comprised in the molding relative to water is from 0.01:1 to 0.1:1.

10. The process of claim 1 , wherein in (iii), the suspension prepared in (ii) is heated to and kept at a temperature of the liquid phase of the aqueous suspension of from 110 to 175° C.

11. The process of claim 1 , further comprising
(v) drying the separated molding comprising zinc and the titanium-containing zeolitic material having framework type MWW obtained from (iv); and
(vi) calcining the dried molding comprising zinc and the titanium-containing zeolitic material having framework type MWW obtained from (v).

Assignees

• Basf Se

Inventors

• Parvulescu Andrei-Nicolae
• Mueller Ulrich
• Luetzel Hans-Juergen
• Teles Joaquim Henrique
• Riedel Dominic
• Urbanczyk Daniel
• Wegerle Ulrike
• Weber Markus
• Woerz Nicolai Tonio
• Mueller Christian

Classifications

• B01J35/30

  characterised by their physical properties · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/77

  Compounds characterised by their crystallite size · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J35/36

  Mechanical strength · CPC title