Sulfide-Based Solid Electrolyte for Lithium Ion Cell, and Solid Electrolyte Compound
US-2017352916-A1 · Dec 7, 2017 · US
US10777841B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10777841-B2 |
| Application number | US-201816014273-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 21, 2018 |
| Priority date | Jul 6, 2017 |
| Publication date | Sep 15, 2020 |
| Grant date | Sep 15, 2020 |
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Disclosed is an all-solid-state lithium ion secondary battery excellent in cycle characteristics. The battery may be an all-solid-state lithium ion secondary battery, wherein an anode comprises anode active material particles, an electroconductive material and a solid electrolyte; wherein the anode active material particles comprise at least one active material selected from the group consisting of elemental silicon and SiO; and wherein, for the anode active material particles, a value A obtained by the following formula (1) is 6.1 or more and 54.8 or less: A=S BET ×d med ×D Formula (1) where S BET is a BET specific surface area (m 2 /g) of the anode active material particles; d med is a median diameter D50 (μm) of the anode active material particles; and D is a density (g/cm 3 ) of the anode active material particles.
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The invention claimed is: 1. An all-solid-state lithium ion secondary battery, wherein an anode comprises anode active material particles, an electroconductive material and a solid electrolyte; wherein the anode active material particles comprise at least one active material selected from the group consisting of elemental silicon and SiO; and wherein, for the anode active material particles, a value A obtained by the following formula (1) is 6.1 or more and 54.8 or less: A=S BET ×d med ×D Formula (1) where S BET is a BET specific surface area (m 2 /g) of the anode active material particles; d med is a median diameter D50 (μm) of the anode active material particles; and D is a density (g/cm 3 ) of the anode active material particles. 2. The all-solid-state lithium ion secondary battery according to claim 1 , wherein a value obtained by dividing, by the value A, a volume percentage (%) of the electroconductive material when a volume of the anode is determined as 100 volume %, is 0.05 or more and 0.50 or less. 3. An all-solid-state lithium ion secondary battery, wherein an anode is formed by using an anode mixture comprising anode active material particles, an electroconductive material and a solid electrolyte; wherein the anode active material particles comprise at least one active material selected from the group consisting of elemental silicon and SiO; and wherein, for the anode active material particles, a value A obtained by the following formula (1) is 6.1 or more and 54.8 or less: A=S BET ×d med ×D Formula (1) where S BET is a BET specific surface area (m 2 /g) of the anode active material particles; d med is a median diameter D50 (μm) of the anode active material particles; and D is a density (g/cm 3 ) of the anode active material particles. 4. The all-solid-state lithium ion secondary battery according to claim 3 , wherein a value obtained by dividing, by the value A, a volume percentage (%) of the electroconductive material when a volume of the anode mixture is determined as 100 volume %, is 0.05 or more and 0.50 or less. 5. The all-solid-state lithium ion secondary battery according to claim 1 , wherein the solid electrolyte is a sulfide-based solid electrolyte. 6. The all-solid-state lithium ion secondary battery according to claim 3 , wherein the solid electrolyte is a sulfide-based solid electrolyte. 7. The all-solid-state lithium ion secondary battery according to claim 1 , wherein the electroconductive material is at least one carbonaceous material selected from the group consisting of carbon black, carbon nanotube and carbon nanofiber. 8. The all-solid-state lithium ion secondary battery according to claim 3 , wherein the electroconductive material is at least one carbonaceous material selected from the group consisting of carbon black, carbon nanotube and carbon nanofiber.
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
Electrodes based on metals, Si or alloys · CPC title
Silicon or alloys based on silicon · CPC title
inorganic · CPC title
Solid materials · CPC title
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