Photovoltaic device comprising a metal halide perovskite and a passivating agent

Patent metadata

Field	Value
Publication number	US-10777693-B2
Application number	US-201415104103-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Dec 17, 2013
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

The present invention relates to devices comprising metal halide perovskites and organic passivating agents. In particular, the invention relates to photovoltaic and optoelectronic devices comprising passivated metal halide perovskites. The device according to the invention comprises: (a) a metal halide perovskite; and (b) a passivating agent which is an organic compound; wherein molecules of the passivating agent are chemically bonded to anions or cations in the metal halide perovskite. The invention also provides a process for producing a photovoltaic device, which photovoltaic device comprises: (a) a metal halide perovskite; and (b) a passivating agent which is an organic compound; wherein molecules of the passivating agent are chemically bonded to anions or cations in the metal halide perovskite, wherein the process comprises treating a metal halide perovskite with a passivating agent, which passivating agent is an organic compound and is suitable for chemically bonding to anions or cations in the metal halide perovskite.

First claim

The invention claimed is:

1. A photovoltaic device comprising a semiconductor, which semiconductor comprises:
(a) a metal halide perovskite; and
(b) a passivating agent which is an organic compound;

wherein:
molecules of the passivating agent are chemically bonded to anions or cations in the metal halide perovskite; and
the passivating agent is an organic compound having a molecular weight of less than 1000 g mol −1 .

2. A photovoltaic device according to claim 1 , wherein the chemical bonds between molecules of the passivating agent and anions or cations in the metal halide perovskite are selected from halogen bonds and chalcogen-metal bonds.

3. A photovoltaic device according to claim 1 , wherein cations or anions in the metal halide perovskite to which molecules of the passivating agent are bonded are under-coordinated.

4. A photovoltaic device according to claim 1 , wherein at least some of the anions or cations in the metal halide perovskite to which molecules of the passivating agent are bonded are at the surface of the metal halide perovskite.

5. A photovoltaic device according to claim 1 , wherein molecules of the passivating agent form a self-assembled layer on a surface of the metal halide perovskite.

6. A photovoltaic device according to claim 1 , wherein at least some of the anions or cations in the metal halide perovskite to which molecules of the passivating agent are bonded are at defect sites in bulk of the crystal structure of the metal halide perovskite.

7. A photovoltaic device according to claim 1 , wherein molecules of the passivating agent are bonded to under-coordinated cations or under-coordinated anions in the bulk of the crystal structure of the metal halide perovskite.

8. A photovoltaic device according to claim 6 , wherein at least some of the anions or cations in the metal halide perovskite to which molecules of the passivating agent are bonded are at grain boundaries in bulk of the crystal structure of the metal halide perovskite.

9. A photovoltaic device according to claim 1 , wherein the passivating agent is iodopentafluorobenzene.

10. A photovoltaic device according to claim 1 , and further comprising:
a further passivating agent which is a further organic compound;
wherein molecules of the further passivating agent are disposed at grain boundaries within the metal halide perovskite and are not chemically bonded to anions or cations in the metal halide perovskite.

11. A photovoltaic device according to claim 10 , wherein the molecules of the further passivating agent block interaction between anions and cations in the metal halide perovskite at the grain boundaries.

12. A photovoltaic device according to claim 1 wherein the metal halide perovskite is a perovskite of the formula (I):
[A][B][X] 3   (I)

wherein:
[A] is at least one organic cation;
[B] is at least one metal cation, wherein [B] comprises at least one of Ca 2+ , Sr 2+ , Cd 2+ , Cu 2+ , Ni 2+ , Mn 2+ , Fe 2+ , Co 2+ , Pd 2+ , Ge 2+ , Sn 2+ , Pb 2+ , Yb 2+ and Eu 2+ ; and
[X] is at least one halide anion.

13. A photovoltaic device according to claim 1 , wherein the photovoltaic device comprises a layer of said semiconductor.

14. A photovoltaic device according to claim 13 , wherein the layer of the semiconductor is without open porosity.

Assignees

• Isis Innovation
• Univ Oxford Innovation Ltd

Inventors

• Snaith Henry J
• Abate Antonio
• Noel Nakita K

Classifications

• H10K30/40

  comprising a p-i-n structure, e.g. having a perovskite absorber between p-type and n-type charge transport layers · CPC title

• H10K30/50 Primary

  Photovoltaic [PV] devices · CPC title

• H10F77/311

  for photovoltaic cells · CPC title

• H10K85/50 Primary

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• H10F77/12

  Active materials · CPC title