Hot-dip galvanized cold-rolled steel sheet and process for producing same

Patent metadata

Field	Value
Publication number	US-10774412-B2
Application number	US-201214130530-A
Country	US
Kind code	B2
Filing date	Jun 29, 2012
Priority date	Jul 6, 2011
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

A hot-dip galvanized cold-rolled steel sheet has a tensile strength of 750 MPa or higher, a composition consisting, in mass percent, C: more than 0.10% and less than 0.25%, Si: more than 0.50% and less than 2.0%, Mn: more than 1.50% and 3.0% or less, and optionally containing one or more types of Ti, Nb, V, Cr, Mo, B, Ca, Mg, REM, and Bi, P: less than 0.050%, S: 0.010% or less, sol. Al: 0.50% or less, and N: 0.010% or less, and a main phase as a low-temperature transformation product and a second phase as retained austenite. The retained austenite volume fraction is more than 4.0% and less than 25.0% of the whole structure, and has an average grain size of less than 0.80 μm. A number density of retained austenite grains having a grain size of 1.2 μm or more is 3.0×10−2/μm2 or less.

First claim

The invention claimed is:

1. A hot-dip galvanized cold-rolled steel sheet having a hot-dip galvanized layer on a surface of a cold-rolled steel sheet, the cold-rolled steel sheet comprising:
a chemical composition consisting of, in mass percent, C: more than 0.10% and less than 0.25%, Si: more than 0.70% and less than 2.0%, Mn: more than 1.50% and at most 3.0%, P: less than 0.050%, S: at most 0.010%, sol. Al: at least 0% and less than 0.10%, N: at most 0.010%, Ti: at least 0% and less than 0.040%, Nb: at least 0% and less than 0.030%, V: at least 0% and at most 0.50%, Cr: at least 0% and at most 1.0%, Mo: at least 0% and less than 0.20%, B: at least 0% and at most 0.010%, Ca: at least 0% and at most 0.010%, Mg: at least 0% and at most 0.010%, REM: at least 0% and at most 0.050%, Bi: at least 0% and at most 0.050%, and the remainder being Fe and impurities; and
a metallurgical structure in which a main phase is a low-temperature transformation product and a second phase contains retained austenite, wherein
the retained austenite has a volume fraction of more than 4.0% to less than 25.0% with respect to a whole structure, and an average grain size of less than 0.80 μm, and in the retained austenite, a number density of retained austenite grains having a grain size of 1.2 μm or more is 3.0×10 −2 /μm 2 or less.

2. The hot-dip galvanized cold-rolled steel sheet as set forth in claim 1 , wherein the chemical composition contains, in mass percent, one kind or two or more kinds selected from a group consisting of Ti: at least 0.005% and less than 0.040%, Nb: at least 0.005% and less than 0.030%, and V: at least 0.010% and at most 0.50%.

3. The hot-dip galvanized cold-rolled steel sheet as set forth in claim 1 , wherein the chemical composition contains, in mass percent, one kind or two or more kinds selected from a group consisting of Cr: at least 0.20% and at most 1.0%, Mo: at least 0.05% and less than 0.20%, and B: at least 0.0010% and at most 0.010%.

4. The hot-dip galvanized cold-rolled steel sheet as set forth in claim 1 , wherein the chemical composition contains, in mass percent, one kind or two or more kinds selected from a group consisting of Ca: at least 0.0005% and at most 0.010%, Mg: at least 0.0005% and at most 0.010%, REM: at least 0.0005% and at most 0.050%, and Bi: at least 0.0010% and at most 0.050%.

5. The hot-dip galvanized cold-rolled steel sheet as set forth in claim 1 , wherein the chemical composition contains, in mass percent, C: more than 0.12% and less than 0.25%.

6. A method for manufacturing a hot-dip galvanized cold-rolled steel sheet according to claim 1 , comprising the following steps (A)-(D):
(A) a hot-rolling step in which a slab having the chemical composition consisting of, in mass percent, C: more than 0.10% and less than 0.25%, Si: more than 0.70% and less than 2.0%, Mn: more than 1.50% and at most 3.0%, P: less than 0.050%, SL at most 0.010%, sol. Al: at least 0% and less than 0.10%, N: at most 0.010%, Ti: at least 0% and less than 0.040%, Nb: at least 0% and less than 0.030%, V: at least 0% and at most 0.50%, Cr: at least 0% and at most 1.0%, Mo: at least 0% and less than 0.20%, B: at least 0% and at most 0.010%, Mg: at least 0% and at most 0.010%, REM: at least 0% and at most 0.050%, Bi: at least 0% and at most 0.050%, and the remainder being Fe and impurities is subjected to hot rolling in which a final pass reduction is more than 15% and rolling is completed in a temperature condition meeting both of (Ar 3 point+30° C.) or higher and higher than 880° C. to form a hot-rolled steel sheet, and the hot-rolled steel sheet is cooled to a temperature range of 720° C. or lower within 0.40 seconds after the completion of the rolling, and is coiled in a temperature range of higher than 400° C.;
(B) a cold-rolled step in which the coiled hot-rolled steel sheet is uncoiled and subjected to a cold rolling to form a cold-rolled steel sheet;
(C) an annealing step in which the cold-rolled steel sheet is subjected to soaking treatment in a temperature range of higher than Ac 3 point, thereafter is cooled to a temperature range of 340° C. to 450° C., and is held for 15 seconds or more in the same temperature range to form an annealed cold-rolled sheet; and
(D) a hot-dip galvanizing step in which the annealed cold-rolled steel sheet is subjected to hot-dip galvanizing.

7. A method for producing a hot-dip galvanized cold-rolled steel sheet according to claim 1 , comprising the following steps (a) to (e):
(a) a hot-rolling step in which a slab having the chemical composition consisting of, in mass percent, C: more than 0.10% and less than 0.25%, Si: more than 0.70% and less than 2.0%, Mn: more than 1.50% and at most 3.0%, P: less than 0.050%, S: at most 0.010%, sol. Al: at least 0% and less than 0.10%, N: at most 0.010%, Ti: at least 0% and less than 0.040%, Nb: at least 0% and less than 0.030%, V: at least 0% and at most 0.50%, Cr: at least 0% and at most 1.0%, Mo: at least 0% and less than 0.20%, B: at least 0% and at most 0.010%, Ca: at least 0% and at most 0.010%, Mg: at least 0% and at most 0.010%, REM: at least 0% and at most 0.050%, Bi: at least 0% and at most 0.050%, and the remainder being Fe and impurities is subjected to hot rolling in which a final pass reduction is more than 15% and rolling is completed in a temperature condition meeting both of (Ar3 point+30° C.) or higher, and higher than 880° C. to form a hot-rolled steel sheet, and the hot-rolled steel sheet is cooled to a temperature range of 720° C. or lower within 0.40 seconds after the completion of the rolling, and is coiled in a temperature range of lower than 200° C.;
(b) a hot-rolled sheet annealing step in which the coiled hot-rolled steel sheet is uncoiled and subjected to annealing in a temperature range of 500° C. or higher, and lower than Ac 1 point to form an annealed hot-rolled steel sheet;
(c) a cold-rolling step in which the annealed hot-rolled steel sheet is subjected to cold rolling to form a cold-rolled steel sheet;
(d) an annealing step in which the cold-rolled steel sheet is subjected to soaking treatment in a temperature range of higher than Ac 3 point, thereafter is cooled to a temperature range of 340° C. to 450° C., and is held for 15 seconds or more in the temperature range to form an annealed cold-rolled steel sheet; and
(e) a hot-dip galvanizing step in which the annealed cold-rolled steel sheet is subjected to hot-dip galvanizing.

Assignees

• Imai Norio
• Wakita Masayuki
• Nishio Takuya
• Haga Jun
• Hata Kengo
• Tanaka Yasuaki
• Yoshida Mitsuru
• Takebayashi Hiroshi
• Fukushima Suguhiro
• Tomida Toshiro
• Nippon Steel Corp

Inventors

• Imai Norio
• Wakita Masayuki
• Nishio Takuya
• Haga Jun
• Hata Kengo
• Tanaka Yasuaki
• Yoshida Mitsuru
• Takebayashi Hiroshi
• Fukushima Suguhiro
• Tomida Toshiro

Classifications

• C23C2/024

  by cleaning or etching · CPC title

• C23C2/0224

  Two or more thermal pretreatments · CPC title

• C23C2/02 Primary

  Pretreatment of the material to be coated, e.g. for coating on selected surface areas (C23C2/30 takes precedence) · CPC title

• C21D8/0236 Primary

  Cold rolling · CPC title

• C23C2/04

  characterised by the coating material · CPC title